Chemistry: Structure and Properties, Books a la Carte PACKAGE W/MasteringChemistry, 2nd Edition
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ISBN: 9780134777559
Author: Tro, Nivaldo J.
Publisher: PEARSON
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Relative Transmittance
0.995
0.99
0.985
0.98
Please draw the structure that is consistent with all the spectral data below in the box and
alphabetically label the equivalent protons in the structure (Ha, Hb, Hc ....) in order to assign all the
proton NMR peaks. Label the absorption bands in the IR spectrum indicated by the arrows.
INFRARED SPECTRUM
1
0.975
3000
2000
Wavenumber (cm-1)
1000
Structure with assigned H peaks
1
3
180 160 140 120
100
f1 (ppm)
80 60
40
20
0
C-13 NMR
note that there are 4
peaks between 120-140ppm
Integral values equal
the number of
equivalent protons
10.0
9.0
8.0
7.0
6.0
5.0
4.0
3.0
2.0
1.0
0.0
fl (ppm)
Calculate the pH of 0.0025 M phenol.
In the following reaction, the OH- acts as which of these?
NO2-(aq) + H2O(l) ⇌ OH-(aq) + HNO2(aq)
Chapter 7 Solutions
Chemistry: Structure and Properties, Books a la Carte PACKAGE W/MasteringChemistry, 2nd Edition
Ch. 7 - Prob. 1ECh. 7 - Prob. 2ECh. 7 - What is the difference between a physical change...Ch. 7 - What is the difference between a physical property...Ch. 7 - What is a balanced chemical equation?Ch. 7 - Why must chemical equations be balanced?Ch. 7 - What is reaction stoichiometry? What is the...Ch. 7 - In a chemical reaction, what is the limiting...Ch. 7 - In a chemical reaction, what is the theoretical...Ch. 7 - We typically calculate the percent yield using the...
Ch. 7 - Prob. 11ECh. 7 - Prob. 12ECh. 7 - Write a general equation for the reaction of an...Ch. 7 - Prob. 14ECh. 7 - Classify each change as physical or chemical....Ch. 7 - Prob. 16ECh. 7 - Prob. 17ECh. 7 - Prob. 18ECh. 7 - Classify each of the listed properties of...Ch. 7 - Prob. 20ECh. 7 - Classify each property as physical or chemical the...Ch. 7 - Prob. 22ECh. 7 - Sulfuric acid (H2SO4) is a component of acid rain...Ch. 7 - Nitric acid (HNO3) is a component of acid rain...Ch. 7 - Prob. 25ECh. 7 - Prob. 26ECh. 7 - Write a balanced chemical equation for the...Ch. 7 - Write a balanced equation for the photosynthesis...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for each...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - Write a balanced chemical equation for the...Ch. 7 - Balance each chemical equation. CO2(g) + CaSiO3(s)...Ch. 7 - Balance each chemical equation. Na2S(aq) +...Ch. 7 - Prob. 35ECh. 7 - Consider the unbalanced equation for the...Ch. 7 - Calculate how many moles of NO2 form when each...Ch. 7 - Calculate how many moles of NH3 form when each...Ch. 7 - Consider the balanced equation: SiO2(s) + 3 C(s)...Ch. 7 - Consider the balanced equation: 2 N2H4(s) +...Ch. 7 - Hydrobromic acid (HBr) dissolves solid iron...Ch. 7 - Sulfuric acid (H2SO4) dissolves aluminum metal...Ch. 7 - For each of the reactions, calculate the mass (in...Ch. 7 - For each of the reactions, calculate the mass (in...Ch. 7 - For the following reaction, determine the limiting...Ch. 7 - Find the limiting reactant for each initial amount...Ch. 7 - Consider the reaction: HCl(g) + O2(g) 2 H2O(g) +...Ch. 7 - Consider the reaction: 2 CH 3 OH(g)+3 O 2 (g)2 CO...Ch. 7 - Calculate the theoretical yield of the product (in...Ch. 7 - Calculate the theoretical yield of product (in...Ch. 7 - Zinc sulfide reacts with oxygen according to the...Ch. 7 - Iron(ll) sulfide reacts with hydrochloric acid...Ch. 7 - For the reaction shown, calculate the theoretical...Ch. 7 - For the reaction shown, calculate the theoretical...Ch. 7 - Iron(lll) oxide reacts with carbon monoxide...Ch. 7 - Elemental phosphorus reacts with chlorine gas...Ch. 7 - Lead(ll) ions can be removed from solution with...Ch. 7 - Prob. 58ECh. 7 - Urea (CH4N2O) is a common fertilizer that is...Ch. 7 - Prob. 60ECh. 7 - Prob. 61ECh. 7 - Complete and balance each combustion reaction...Ch. 7 - Prob. 63ECh. 7 - Prob. 64ECh. 7 - Prob. 65ECh. 7 - Prob. 66ECh. 7 - Prob. 67ECh. 7 - Prob. 68ECh. 7 - Prob. 69ECh. 7 - Prob. 70ECh. 7 - Aspirin can be made in the laboratory by reacting...Ch. 7 - The combustion of liquid ethanol (C2H5OH) produces...Ch. 7 - Prob. 73ECh. 7 - Prob. 74ECh. 7 - Prob. 75ECh. 7 - An important reaction that takes place in a blast...Ch. 7 - A liquid fuel mixture contains 30.35% hexane...Ch. 7 - Titanium occurs in the magnetic mineral ilmenite...Ch. 7 - A mixture of C3H8 and C2H2 has a mass of 2.0 g. It...Ch. 7 - Prob. 80ECh. 7 - Lead poisoning is a serious condition resulting...Ch. 7 - Prob. 82ECh. 7 - Metallic aluminum reacts with MnO2 at elevated...Ch. 7 - Prob. 84ECh. 7 - Consider the reaction: 4K(s)+O2(g)2K2O(s) The...Ch. 7 - Prob. 86ECh. 7 - Consider the reaction:...Ch. 7 - Prob. 88ECh. 7 - Prob. 89ECh. 7 - Prob. 90ECh. 7 - What are the correct coefficients (reading from...Ch. 7 - Prob. 2SAQCh. 7 - Prob. 3SAQCh. 7 - For the reaction shown here, 3.5 mol A is mixed...Ch. 7 - Manganese(IV) oxide reacts with aluminum to form...Ch. 7 - Sodium and chlorine react to form sodium chloride....Ch. 7 - Sulfur and fluorine react to form sulfur...Ch. 7 - A reaction has a theoretical yield of 45.8 g. When...Ch. 7 - Prob. 9SAQCh. 7 - Solid potassium chlorate (KCIO3) decomposes into...
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- Using spectra attached, can the unknown be predicted? Draw the predicition. Please explain and provide steps. Molecular focrmula:C16H13ClOarrow_forwardCalculate the percent ionization for 0.0025 M phenol. Use the assumption to find [H3O+] first. K = 1.0 x 10-10arrow_forwardThe Ka for sodium dihydrogen phosphate is 6.32 x 10-8. Find the pH of a buffer made from 0.15 M H2PO4- and 0.25 M HPO42- .arrow_forward
- The Ka for lactic acid is 1.4 x 10-4. Find the pH of a buffer made from 0.066 M lactic acid and 0.088 M sodium lactate.arrow_forwardZaitsev's Rule 3) (a) Rank the following alkenes in order of decreasing stability. most stable A B C D > > > (b) Rank the following carbocations in order of decreasing stability least stable B C Darrow_forwardCalculate the pH of 0.25 M acetic acid.arrow_forward
- For each of the following reactions: Fill in the missing reactant, reagent, or product (s), indicating stereochemistry where appropriate using dashed and wedged bonds. If the reaction forms a racemic mixture, draw both structures in the box and write the word “racemic”.arrow_forward5) Using the carbon-containing starting material(s), propose a synthesis based on the following retrosynthetic analysis. Provide structures for all intermediates. The carbon atoms in the product must originate from the starting material(s), but you may use as many equivalents of each starting material as you would like, and any reagent/reaction you know (note: no mechanisms are required). H H =arrow_forwardCalculate the percent ionization for 0.0025 M phenol. Use the assumption to find [H3O+] first. K = 1.0 x 10-10arrow_forward
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