MOLECULAR NATURE OF MATTER ALEKS ACCESS
9th Edition
ISBN: 9781266207631
Author: SILBERBERG
Publisher: MCG
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Chapter 7, Problem 7.37P
Interpretation Introduction
Interpretation:
The reason the wavelike motion of macroscopic objects cannot be observed is to be determined.
Concept introduction:
According to de-Broglie, just like light, matter also has a dual character as a wave and as a particle. The term wavicle was proposed for such a particle. However, matter waves are different from
Expert Solution & Answer
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Students have asked these similar questions
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of ZybanⓇ:
1. Write a mechanism for the bromination of m-chloropropiophenone.
Br₂
CH2Cl2
Cl
Br
2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks).
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Synthesis of Ibuprofen-Part 2:
1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure
of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how
to make naproxen from the compound below. Show all intermediates and reagents in your synthesis.
Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction
steps would need to change/add?
3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 7 Solutions
MOLECULAR NATURE OF MATTER ALEKS ACCESS
Ch. 7.1 - Some diamonds appear yellow because they contain...Ch. 7.1 - Prob. 7.1BFPCh. 7.1 - Prob. 7.2AFPCh. 7.1 - Prob. 7.2BFPCh. 7.2 - Prob. 7.3AFPCh. 7.2 - Prob. 7.3BFPCh. 7.3 - Prob. 7.4AFPCh. 7.3 - Prob. 7.4BFPCh. 7.3 - Prob. 7.5AFPCh. 7.3 - Prob. 7.5BFP
Ch. 7.4 - Prob. 7.6AFPCh. 7.4 - Prob. 7.6BFPCh. 7.4 - Prob. 7.7AFPCh. 7.4 - Prob. 7.7BFPCh. 7.4 - Prob. 7.8AFPCh. 7.4 - Prob. 7.8BFPCh. 7 - Prob. 7.1PCh. 7 - Consider the following types of electromagnetic...Ch. 7 - Prob. 7.3PCh. 7 - In the 17th century, Isaac Newton proposed that...Ch. 7 - Prob. 7.5PCh. 7 - What new idea about light did Einstein use to...Ch. 7 - An AM station broadcasts rock music at “950 on...Ch. 7 - An FM station broadcasts music at 93.5 MHz...Ch. 7 - Prob. 7.9PCh. 7 - An x-ray has a wavelength of 1.3 Å. Calculate the...Ch. 7 - Prob. 7.11PCh. 7 - Prob. 7.12PCh. 7 - Police often monitor traffic with “K-band” radar...Ch. 7 - Covalent bonds in a molecule absorb radiation in...Ch. 7 - Prob. 7.15PCh. 7 - Prob. 7.16PCh. 7 - How is n1 in the Rydberg equation (Equation 7.4)...Ch. 7 - What key assumption of Bohr’s model would a “Solar...Ch. 7 - Prob. 7.19PCh. 7 - Which of these electron transitions correspond to...Ch. 7 - Why couldn’t the Bohr model predict spectra for...Ch. 7 - Prob. 7.22PCh. 7 - Use the Rydberg equation to find the wavelength...Ch. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - Prob. 7.26PCh. 7 - Prob. 7.27PCh. 7 - Prob. 7.28PCh. 7 - Prob. 7.29PCh. 7 - Prob. 7.30PCh. 7 - Prob. 7.31PCh. 7 - Prob. 7.32PCh. 7 - In addition to continuous radiation, fluorescent...Ch. 7 - Prob. 7.34PCh. 7 - Prob. 7.35PCh. 7 - Prob. 7.36PCh. 7 - Prob. 7.37PCh. 7 - Prob. 7.38PCh. 7 - A 232-lb fullback runs 40 yd at 19.8 ± 0.1...Ch. 7 - Prob. 7.40PCh. 7 - Prob. 7.41PCh. 7 - Prob. 7.42PCh. 7 - Prob. 7.43PCh. 7 - Prob. 7.44PCh. 7 - What physical meaning is attributed to ψ2?
Ch. 7 - What does “electron density in a tiny volume of...Ch. 7 - Prob. 7.47PCh. 7 - Prob. 7.48PCh. 7 - How many orbitals in an atom can have each of the...Ch. 7 - Prob. 7.50PCh. 7 - Give all possible ml values for orbitals that have...Ch. 7 - Prob. 7.52PCh. 7 - Prob. 7.53PCh. 7 - Prob. 7.54PCh. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - Prob. 7.57PCh. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Prob. 7.60PCh. 7 - Prob. 7.61PCh. 7 - The quantum-mechanical treatment of the H atom...Ch. 7 - The photoelectric effect is illustrated in a plot...Ch. 7 - Prob. 7.64PCh. 7 - Prob. 7.65PCh. 7 - Prob. 7.66PCh. 7 - Prob. 7.67PCh. 7 - Prob. 7.68PCh. 7 - Prob. 7.69PCh. 7 - Prob. 7.70PCh. 7 - Prob. 7.71PCh. 7 - Prob. 7.72PCh. 7 - Prob. 7.73PCh. 7 - Prob. 7.74PCh. 7 - Use the relative size of the 3s orbital below to...Ch. 7 - Prob. 7.76PCh. 7 - Prob. 7.77PCh. 7 - Enormous numbers of microwave photons are needed...Ch. 7 - Prob. 7.79PCh. 7 - Prob. 7.80PCh. 7 - Prob. 7.81PCh. 7 - Prob. 7.82PCh. 7 - Prob. 7.83PCh. 7 - Prob. 7.84PCh. 7 - For any microscope, the size of the smallest...Ch. 7 - In fireworks, the heat of the reaction of an...Ch. 7 - Prob. 7.87PCh. 7 - Fish-liver oil is a good source of vitamin A,...Ch. 7 - Many calculators use photocells as their energy...Ch. 7 - Prob. 7.90PCh. 7 - Prob. 7.91PCh. 7 - Prob. 7.92PCh. 7 - The flame tests for sodium and potassium are based...Ch. 7 - Prob. 7.94PCh. 7 - Prob. 7.95PCh. 7 - The discharge of phosphate in detergents to the...
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- Acid Catalyzed Aromatization of Carvone: 1. Starting with the ketone, below, draw a mechanism for the reaction to give the phenol as shown. H2SO4 HO- H₂O 2. Why do we use CDCl instead of CHCl, for acquiring our NMR spectra? 3. Why does it not matter which enantiomer of carvone is used for this reaction? What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardAssign this H NMRarrow_forwardPlease complete these blanks need that asaparrow_forward
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