(a) Interpretation: The products formed by the reaction of t r a n s -2- butene with Hg ( OAc ) 2 and H 2 O including their stereochemistry are to be stated. Concept introduction: In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The OH group is connected to the most substituted carbon atom and the H atom is connected to the least substituted carbon atom.

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Answer 1

Question

Chapter 7, Problem 7.32P

Interpretation Introduction

(a)

Interpretation:

The products formed by the reaction of $trans-2-$ butene with $Hg(OAc)2$ and $H2O$ including their stereochemistry are to be stated.

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

Interpretation Introduction

(b)

Interpretation:

The compounds obtained after the reaction of the products of part (a) with $NaBD4$ in aqueous $NaOH$ are to be stated. Also, these products are to be compared with the products of Eq. $7.45$ .

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

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Answer 2

Question

Chapter 7, Problem 7.32P

Interpretation Introduction

(a)

Interpretation:

The products formed by the reaction of $trans-2-$ butene with $Hg(OAc)2$ and $H2O$ including their stereochemistry are to be stated.

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

Interpretation Introduction

(b)

Interpretation:

The compounds obtained after the reaction of the products of part (a) with $NaBD4$ in aqueous $NaOH$ are to be stated. Also, these products are to be compared with the products of Eq. $7.45$ .

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

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Answer 3

Question

Chapter 7, Problem 7.32P

Interpretation Introduction

(a)

Interpretation:

The products formed by the reaction of $trans-2-$ butene with $Hg(OAc)2$ and $H2O$ including their stereochemistry are to be stated.

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

Interpretation Introduction

(b)

Interpretation:

The compounds obtained after the reaction of the products of part (a) with $NaBD4$ in aqueous $NaOH$ are to be stated. Also, these products are to be compared with the products of Eq. $7.45$ .

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

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Answer 4

Question

Chapter 7, Problem 7.32P

Interpretation Introduction

(a)

Interpretation:

The products formed by the reaction of $trans-2-$ butene with $Hg(OAc)2$ and $H2O$ including their stereochemistry are to be stated.

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

Interpretation Introduction

(b)

Interpretation:

The compounds obtained after the reaction of the products of part (a) with $NaBD4$ in aqueous $NaOH$ are to be stated. Also, these products are to be compared with the products of Eq. $7.45$ .

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

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Answer 5

Chapter 7, Problem 7.32P

Interpretation Introduction

(a)

Interpretation:

The products formed by the reaction of $trans-2-$ butene with $Hg(OAc)2$ and $H2O$ including their stereochemistry are to be stated.

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

Interpretation Introduction

(b)

Interpretation:

The compounds obtained after the reaction of the products of part (a) with $NaBD4$ in aqueous $NaOH$ are to be stated. Also, these products are to be compared with the products of Eq. $7.45$ .

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

Answer 6

Chapter 7, Problem 7.32P

Interpretation Introduction

(a)

Interpretation:

The products formed by the reaction of $trans-2-$ butene with $Hg(OAc)2$ and $H2O$ including their stereochemistry are to be stated.

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

Answer 7

Chapter 7, Problem 7.32P

Interpretation Introduction

(a)

Interpretation:

The products formed by the reaction of $trans-2-$ butene with $Hg(OAc)2$ and $H2O$ including their stereochemistry are to be stated.

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The compounds obtained after the reaction of the products of part (a) with $NaBD4$ in aqueous $NaOH$ are to be stated. Also, these products are to be compared with the products of Eq. $7.45$ .

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The compounds obtained after the reaction of the products of part (a) with $NaBD4$ in aqueous $NaOH$ are to be stated. Also, these products are to be compared with the products of Eq. $7.45$ .

Concept introduction:

In oxymercuration-reduction reaction, the addition of water molecule to alkene takes place to form anti-addition products. The oxymercuration-reduction reaction follows the Markovnikov’s regioselectivity. The $OH$ group is connected to the most substituted carbon atom and the $H$ atom is connected to the least substituted carbon atom.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 7 - Prob. 7.1P Ch. 7 - Prob. 7.2P Ch. 7 - Prob. 7.3P Ch. 7 - Prob. 7.4P Ch. 7 - Prob. 7.5P Ch. 7 - Prob. 7.6P Ch. 7 - Prob. 7.7P Ch. 7 - Prob. 7.8P Ch. 7 - Prob. 7.9P Ch. 7 - Prob. 7.10P

Solution Summary: The author explains the oxymercuration-reduction reaction of trans-2- butene, which involves the addition of water molecule to alkene to form anti-addition products.

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