Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 7, Problem 7.17NP
Interpretation Introduction

Interpretation : The van der Waals parameters of carbon dioxide should be calculated from the values of the critical constants.

Concept Introduction :

The correction for intermolecular forces is represented as follows:

  b=RTc8Pc

Here,

b − correction for volume

R − universal gas constant

Tc − critical temperature

Pc − critical pressure

The correction for intermolecular forces is represented as follows:

  a=27R2Tc264Pc

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