Organic Chemistry: Principles And Mechanisms
Organic Chemistry: Principles And Mechanisms
2nd Edition
ISBN: 9780393630756
Author: KARTY, Joel
Publisher: W.w. Norton & Company,
bartleby

Concept explainers

Question
Book Icon
Chapter 7, Problem 7.15P
Interpretation Introduction

(a)

Interpretation:

The product for the given E2 step with appropriate curved arrows is to be drawn.

Concept introduction:

E2 is the bimolecular elimination step. The step is bimolecular because it involves two reactants – a strong base and the substrate. The strong base reacts with the substrate having the leaving group, and the hydrogen atoms are on adjacent carbons like HCCL or HC=CL. The first curved arrow is drawn from the negatively charged atom of a strong base to the hydrogen adjacent to the leaving group in the substrate. The second curved arrow is drawn from the C-H bond to the region between the adjacent carbon atoms bearing hydrogen and the leaving group. The third curved arrow is drawn representing the detachment of the leaving group to avoid exceeding octet of carbon atom. The main product formed in such a step is alkene (C = C) or alkyne (CC), double bond between two carbon atoms.

Interpretation Introduction

(b)

Interpretation:

The product for the given E2 step with appropriate curved arrows is to be drawn.

Concept introduction:

E2 is the bimolecular elimination step. The step is bimolecular because it involves two reactants – a strong base and the substrate. The strong base reacts with the substrate having the leaving group, and the hydrogen atoms are on adjacent carbons like HCCL or HC=CL. The first curved arrow is drawn from the negatively charged atom of a strong base to the hydrogen adjacent to the leaving group in the substrate. The second curved arrow is drawn from the C-H bond to the region between the adjacent carbon atoms bearing hydrogen and the leaving group. The third curved arrow is drawn representing the detachment of the leaving group to avoid exceeding octet of carbon atom. The main product formed in such a step is alkene (C = C) or alkyne (CC), double bond between two carbon atoms.

Blurred answer
Students have asked these similar questions
Provide an IUPAC name for each of the compounds shown. (Specify (E)/(Z) stereochemistry, if relevant, for straight chain alkenes only. Pay attention to commas, dashes, etc.) H₁₂C C(CH3)3 C=C H3C CH3 CH3CH2CH CI CH3 Submit Answer Retry Entire Group 2 more group attempts remaining Previous Next
Arrange the following compounds / ions in increasing nucleophilicity (least to most nucleophilic) CH3NH2 CH3C=C: CH3COO 1 2 3 5 Multiple Choice 1 point 1, 2, 3 2, 1, 3 3, 1, 2 2, 3, 1 The other answers are not correct 0000
curved arrows are used to illustrate the flow of electrons. using the provided starting and product structures, draw the cured electron-pushing arrows for thw following reaction or mechanistic steps. be sure to account for all bond-breaking and bond making steps

Chapter 7 Solutions

Organic Chemistry: Principles And Mechanisms

Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning