Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 7, Problem 67P

(a)

Interpretation Introduction

Interpretation: For the given reaction, change in equilibrium needs to be explained, if pressure is doubled.

Concept Introduction: The given equilibrium reaction is as follows:

CS2(g)+3Cl2(g)CCl4(g)+S2Cl2(g)+238kJ

According to Le Chatelier's principle, if any change in the equilibrium reaction takes place, the equilibrium gets reestablished by shifting in the reaction to oppose that change.

For example, if number of moles increases, the equilibrium shifts in the reaction to decrease the number of moles.

(b)

Interpretation Introduction

Interpretation: For the given reaction, change in equilibrium needs to be explained, if CCl4 is removed.

Concept Introduction: The given equilibrium reaction is as follows:

CS2(g)+3Cl2(g)CCl4(g)+S2Cl2(g)+238kJ

According to Le Chatelier's principle, if any change in the equilibrium reaction takes place, the equilibrium gets reestablished by shifting in the reaction to oppose that change.

For example, if number of moles increases, the equilibrium shifts in the reaction to decrease the number of moles.

(c)

Interpretation Introduction

Interpretation: For the given reaction, change in equilibrium needs to be explained, if heat is added.

Concept Introduction: The given equilibrium reaction is as follows:

CS2(g)+3Cl2(g)CCl4(g)+S2Cl2(g)+238kJ

According to Le Chatelier's principle, if any change in the equilibrium reaction takes place, the equilibrium gets reestablished by shifting in the reaction to oppose that change.

For example, if number of moles increases, the equilibrium shifts in the reaction to decrease the number of moles.

(d)

Interpretation Introduction

Interpretation: For the given reaction, change in equilibrium needs to be explained, if catalyst is added.

Concept Introduction: The given equilibrium reaction is as follows:

CS2(g)+3Cl2(g)CCl4(g)+S2Cl2(g)+238kJ

According to Le Chatelier's principle, if any change in the equilibrium reaction takes place, the equilibrium gets reestablished by shifting in the reaction to oppose that change.

For example, if number of moles increases, the equilibrium shifts in the reaction to decrease the number of moles.

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Chapter 7 Solutions

Introduction to General, Organic and Biochemistry

Ch. 7 - 7-12 Two kinds of gas molecules are reacted at a...Ch. 7 - 7-13 Why are reactions between ions in aqueous...Ch. 7 - Prob. 4PCh. 7 - 7-15 A certain reaction is exothermic by 9...Ch. 7 - 7-16 A quart of milk quickly spoils if left at...Ch. 7 - 7-17 If a certain reaction takes 16 h to go to...Ch. 7 - Prob. 8PCh. 7 - Prob. 9PCh. 7 - Prob. 10PCh. 7 - Prob. 11PCh. 7 - 7-22 If you add a piece of marble, CaCO3 to a 6 M...Ch. 7 - Prob. 13PCh. 7 - Prob. 14PCh. 7 - Prob. 15PCh. 7 - 7-26 Write the chemical equations corresponding to...Ch. 7 - Prob. 17PCh. 7 - 7-28 When the following reaction reached...Ch. 7 - 7-29 The following reaction was allowed to reach...Ch. 7 - Prob. 20PCh. 7 - 7-31 Here are equilibrium constants for several...Ch. 7 - 7-32 A particular reaction has an equilibrium...Ch. 7 - Prob. 23PCh. 7 - Prob. 24PCh. 7 - 7-35 A reaction has a high rate constant but a...Ch. 7 - 7-36 Complete the following table showing the...Ch. 7 - Prob. 27PCh. 7 - Prob. 28PCh. 7 - Prob. 29PCh. 7 - 7-40 Is there any change in conditions that change...Ch. 7 - 7-41 The equilibrium constant at 1127°C for the...Ch. 7 - Prob. 32PCh. 7 - 7-43 (Chemical Connections 7A and 7B) Why is a...Ch. 7 - Prob. 34PCh. 7 - 7-45 (Chemical Connections 7C) A painkiller—for...Ch. 7 - 7-46 (Chemical Connections 7D) What reaction takes...Ch. 7 - Prob. 37PCh. 7 - Prob. 38PCh. 7 - Prob. 39PCh. 7 - 7-50 Draw an energy diagram for an exothermic...Ch. 7 - Prob. 41PCh. 7 - Prob. 42PCh. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Prob. 46PCh. 7 - 7-57 Write the reaction to which the following...Ch. 7 - Prob. 48PCh. 7 - Prob. 49PCh. 7 - Prob. 50PCh. 7 - Prob. 51PCh. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - Prob. 56PCh. 7 - Prob. 57PCh. 7 - Prob. 58PCh. 7 - 7-69 Pure carbon exists is several forms, two of...Ch. 7 - Prob. 60PCh. 7 - 7-71 You have a beaker that contains solid silver...Ch. 7 - Prob. 62PCh. 7 - Prob. 63PCh. 7 - Prob. 64PCh. 7 - Prob. 65PCh. 7 - Prob. 66PCh. 7 - Prob. 67PCh. 7 - Prob. 68PCh. 7 - Prob. 69PCh. 7 - Prob. 70PCh. 7 - Prob. 71PCh. 7 - Prob. 72PCh. 7 - Prob. 73PCh. 7 - Prob. 74PCh. 7 - 7-82 An equilibrium mixture of O2, SO2, and SO3...Ch. 7 - Prob. 76PCh. 7 - Prob. 77P
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