CHEMISTRY:PRIN.+REACTIONS-OWLV2 ACCESS
8th Edition
ISBN: 9781305079298
Author: Masterton
Publisher: Cengage Learning
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Textbook Question
Chapter 7, Problem 58QAP
Acrylonitrile, C3H3N is the building mer Orlon. Its Lewis structure is
What is the hybridization of nitrogen and of the three numbered carbon atoms?
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 7 Solutions
CHEMISTRY:PRIN.+REACTIONS-OWLV2 ACCESS
Ch. 7 - Prob. 1QAPCh. 7 - Prob. 2QAPCh. 7 - Follow the directions of Question 1 for (a) IO2-...Ch. 7 - Follow the directions of Question 1 for (a) CIF4-...Ch. 7 - Follow the directions of Question 1 for (a) OCl2...Ch. 7 - Follow the directions of Question 1 for (a) C22-...Ch. 7 - Oxalic acid, H2C2O4, is a poisonous compound found...Ch. 7 - Radio astronomers have detected the isoformyl ion,...Ch. 7 - Draw Lewis structures for the following species....Ch. 7 - Follow the directions of Question 9 for the...
Ch. 7 - Dinitrogen pentoxide, N2O5, when bubbled into...Ch. 7 - Formic acid is the irritating substance that gets...Ch. 7 - Two different molecules have the formula C2H2Cl2....Ch. 7 - Two different molecules have the formula C2H6O....Ch. 7 - Prob. 15QAPCh. 7 - Prob. 16QAPCh. 7 - Write a Lewis structure for (a) XeF3+ (b) PCl4+...Ch. 7 - Write a Lewis structure for (a) BCl4 (b) ClO- (c)...Ch. 7 - Write reasonable Lewis structures for the...Ch. 7 - Write reasonable Lewis structures for the...Ch. 7 - Prob. 21QAPCh. 7 - Draw resonance structures for (a) SeO3 (b) CS32-...Ch. 7 - Prob. 23QAPCh. 7 - Prob. 24QAPCh. 7 - The skeleton structure for disulfur dinitride,...Ch. 7 - Borazine, B3N3H6, has the skeleton Draw the...Ch. 7 - What is the formal charge on the indicated atom in...Ch. 7 - Prob. 28QAPCh. 7 - Below are two different Lewis structures for...Ch. 7 - Below are two different Lewis structures for the...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Predict the geometry of the following species: (a)...Ch. 7 - Give all the ideal bond angles (109.5, 120, or...Ch. 7 - Prob. 38QAPCh. 7 - Prob. 39QAPCh. 7 - An objectionable component of smog is acetyl...Ch. 7 - The uracil molecule is one of the bases in DNA....Ch. 7 - Niacin is one of the B vitamins (B3). Estimate the...Ch. 7 - Which of the species with octets in Question 31...Ch. 7 - Which of the species with octets in Question 32...Ch. 7 - Which of the species with octets in Question 33...Ch. 7 - Prob. 46QAPCh. 7 - There are three compounds with the formula...Ch. 7 - There are two different molecules with the formula...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - Give the hybridization of the central atom in each...Ch. 7 - In each of the following polyatomic ions, the...Ch. 7 - Follow the directions of Question 55 for the...Ch. 7 - Give the hybridization of each atom (except H) in...Ch. 7 - Acrylonitrile, C3H3N is the building mer Orlon....Ch. 7 - What is the hybridization of nitrogen inCh. 7 - What is the hybridization of carbon inCh. 7 - Give the hybridization of the central atom...Ch. 7 - Give the hybridization of the central atom...Ch. 7 - Give the number of sigma and pi bonds in the...Ch. 7 - Give the number of sigma and pi bonds in the...Ch. 7 - Give the number of sigma and pi bonds in each...Ch. 7 - Give the number of sigma and pi bonds in each...Ch. 7 - In which of the following molecules does the...Ch. 7 - Consider the pyrosulfate ion, S2O72-. It has no...Ch. 7 - Consider acetyl salicylic acid, better known as...Ch. 7 - Complete the table on next page.Ch. 7 - Given the following electro negativities...Ch. 7 - Based on the concept of formal charge, what is the...Ch. 7 - Describe the geometry of the species in which...Ch. 7 - Consider the following molecules: SiH4, PH3, H2S....Ch. 7 - Prob. 75QAPCh. 7 - In each of the following molecules, a central atom...Ch. 7 - Prob. 77QAPCh. 7 - A compound of chlorine and fluorine, CIFx, reacts...Ch. 7 - Draw the Lewis structure and describe the geometry...Ch. 7 - Consider the polyatomic ion IO65-. How many pairs...Ch. 7 - It is possible to write a simple Lewis structure...Ch. 7 - Phosphoryl chloride, POCl3, has the skeleton...
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