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(a)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(a)
Answer to Problem 47PP
The systematic name of the given compound must be 2-chloropropane and the common name is isopropyl chloride.
Explanation of Solution
In the given organic compound, the parent longest chain contains 3 carbon atoms so the root word must be propane with one substituent; chloro at C2 position. Thus, the systematic name of the given compound must be 2-chloropropane and the common name is isopropyl chloride.
(b)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(b)
Answer to Problem 47PP
The systematic name of the given compound must be 2-bromo-2-methylpropane and the common name is tert-butyl bromide.
Explanation of Solution
In the given organic compound, the parent longest chain contains 3 carbon atoms so the root word must be propane with two substituents: chloro and methyl at 2 positions. Thus, the systematic name of the given compound must be 2-bromo-2-methylpropane and the common name is tert-butyl bromide.
(c)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(c)
Answer to Problem 47PP
The systematic name of the given compound must be 1-iodopropane and the common name is propyl iodide.
Explanation of Solution
In the given organic compound the parent longest chain contains 3 carbon atoms so the root word must be propane with one substituent; iodo at 1 position. Thus, the systematic name of the given compound must be 1-iodopropane and the common name is propyl iodide.
(d)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(d)
Answer to Problem 47PP
The systematic name of the given compound must be (R)-2-bromobutane and the common name is (R)- sec-butyl bromide.
Explanation of Solution
In the given organic compound the parent longest chain contains 4 carbon atoms so the root word must be butane with one substituent; bromo at C2 position. Thus, the systematic name of the given compound must be (R)-2-bromobutane and the common name is (R)- sec-butyl bromide. The prefix (R) indicates the clockwise rotation of the groups bonded at the chiral C atom when arranged from 1 to 4 in the increasing order of their
(e)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(e)
Answer to Problem 47PP
The systematic name of the given compound must be 1-chloro-2,2- dimethylpropane and common name is neopentyl chloride.
Explanation of Solution
In the given organic compound, the parent longest chain contains 3 carbon atoms so the root word must be propane with three substituents as methyl and chloro at C1 and C2 position. Thus, the systematic name of the given compound must be 1-chloro-2,2- dimethylpropane and the common name is neopentyl chloride.
(f)
Interpretation: The systematic name and common name of the given organic compound is to be interpreted.
Concept Introduction: Organic compounds are chemical compounds that are mainly composed of carbon and hydrogen atoms. The naming of organic compounds is followed the IUPAC rules. The longest chain of carbon atoms is considered the parent chain. The substituents must be given with the least locant number. The locant number must be written as the prefix in the IUPAC name.
(f)
Answer to Problem 47PP
The systematic name of the given compound must be 4-bromo-3,3-dimethyl-4-propylhaptane.
Explanation of Solution
In the given organic compound the parent longest chain contains 7 carbon atoms so the root word must be haptane with four substituents as propyl, methyl and bromo. Thus, the systematic name of the given compound must be 4-bromo-3,3-dimethyl-4-propylhaptane.
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Chapter 7 Solutions
ORGANIC CHEMISTRY,SOLNS...-ETEXT+BOX
- Calculating the pH of a salt solution Calculate the pH at 25 °C of a 0.29M solution of potassium butanoate (KC3H,CO2). Note that butanoic acid (HC3H,CO2) is a weak acid with a pKa of 4.82. Round your answer to 1 decimal place. pH = -0 Х olo 18 Ararrow_forward: At a certain temperature, the equilibrium constant K for the following reaction is 1.58 × 10-12 N2(g) + O2(g) = 2 NO(g) Use this information to complete the following table. Suppose a 38. L reaction vessel is filled with 0.93 mol of N2 and 0.93 mol of O2. What can you say about the composition of the mixture in the vessel at equilibrium? There will be very little N2 and O2. There will be very little NO. What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 2 NO(g) N2(9)+02(9) What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 3 N2(9)+302(g) 6 NO(g) Neither of the above is true. K = ☐ K = ☐ ☐ X10 Х D ? 000 18 Ar Barrow_forwardwhen performing the reaction that involves 2 equivalents of 3-(diethylamino)-phenol and Phthalic anhydride with sulfuric acid and water react to form rhodamine b where the Phthalic anhydride cleaves in acid and how does Excessive Washing (w/ Base) & Subsequent Resonance Structure get affectedarrow_forward
- 3. The strongest acid of the following compounds is ___.A. p-nitrophenol; B. m-nitrophenol; C. o-chlorophenol;D. p-methoxyphenol; E. o-methylphenol Please explain your steps and thought process. Thank you!arrow_forwardUsing the general properties of equilibrium constants At a certain temperature, the equilibrium constant K for the following reaction is 1.3 × 10 4: Cl2(g) + CHCl3(g) HCl(g) + CC₁(g) Use this information to complete the following table. Suppose a 16. L reaction vessel is filled with 1.6 mol of HCI and 1.6 mol of CCl4. What can you say about the composition of the mixture in the vessel at equilibrium? There will be very little Cl2 and CHCl3. ☐ x10 There will be very little HCI and CCl4. Neither of the above is true. What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. HCl(g)+CC14(g) 12 Cl2(9)+CHCl3(9) K = 0 ☐ What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 2 Cl₂(9)+2CHCl3(9) 2 HCl(9)+2CC₁₁(9) K = ✓ 00. 18 Ararrow_forward10. The most important reason why Br- is a better nucleophile than Cl-is ___. A. polarizability; B. size; C. solvation; D. basicity; E. polarity. Please include all steps. Thanks!arrow_forward
- Predicting the qualitative acid-base properties of salts Consider the following data on some weak acids and weak bases: base acid Ка K₁₁ name formula name formula nitrous acid HNO2 4.5×10 4 pyridine CHEN 1.7 × 10 9 4 hydrofluoric acid HF 6.8 × 10 methylamine CH3NH2 | 4.4 × 10¯ Use this data to rank the following solutions in order of increasing pH. In other words, select a '1' next to the solution that will have the lowest pH, a '2' next to the solution that will have the next lowest pH, and so on. solution 0.1 M NaNO2 0.1 M KF pH choose one v choose one v 0.1 M C5H5NHBr 0.1 M CH3NH3CI choose one v ✓ choose one 1 (lowest) 2 ☑ 3 4 (highest) 000 18 Ararrow_forward4. The major product from treatment of 2-propanol with the Jonesreagent is ___.A. acetone; B. none of the other answers is correct C. propene; D.propanoic acid; E carbon dioxide. Please include all steps! Thank you!arrow_forward7. All of the following compounds that are at the same oxidation levelare ___.u. methyl epoxide, v. propyne, w. propanal, x. propene,y. 2,2-dihydroxypropane, z. isopropanol?A. u,v,w,y; B. u,v,w; C. v,w,y,z; D. v, z; E. x,y,z Please include all steps. Thank you!arrow_forward
- 9. Which one of the following substituents is the worst leaving group inan SN2 reaction? A. -NH2; B. -OH; C. –F; D. NH3; E. H2O Please include all steps. Thanks!arrow_forwardUsing the general properties of equilibrium constants At a certain temperature, the equilibrium constant K for the following reaction is 2.5 × 105: CO(g) + H2O(g) CO2(g) + H2(g) Use this information to complete the following table. Suppose a 7.0 L reaction vessel is filled with 1.7 mol of CO and 1.7 mol of H2O. What can you say about the composition of the mixture in the vessel at equilibrium? What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. CO2(9)+H2(g) CO(g)+H₂O(g) What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 3 CO(g)+3H2O(g) = 3 CO2(g)+3H2(g) There will be very little CO and H2O. x10 There will be very little CO2 and H2. 000 Neither of the above is true. K = ☐ K = ☐ 18 Ararrow_forward8. When ethane thiol is treated with hydrogen peroxide the product is___.A. ethane disulfide; B. diethyl sulfide; C. ethane sulfoxide; D. ethanesulfate; E. ethyl mercaptan. Please include all steps. Thanks!arrow_forward
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