Bundle: Chemistry in Focus, Loose-leaf Version, 7th + OWLv2, 1 term (6 months) Printed Access Card
7th Edition
ISBN: 9781337812269
Author: Nivaldo J. Tro
Publisher: Cengage Learning
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Chapter 7, Problem 43E
Interpretation Introduction
Interpretation:
The element present within the given lamp is to be identified.
Concept Introduction:
Absorption spectroscopy is a technique of measurement of the absorption of radiation. The color of any substance depends on the color of the light absorbed by the molecules or atoms that compose the substance.
Absorption spectroscopy is very useful in distinguishing many chemical compounds from each other in a mixture.
The specificity of spectroscopy allows one to identify the unknown samples by comparing with the reference spectra.
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There is an instrument in Johnson 334 that measures total-reflectance x-ray fluorescence (TXRF) to do elemental analysis (i.e., determine what elements are present in a sample). A researcher is preparing a to measure calcium content in a series of well water samples by TXRF with an internal standard of vanadium (atomic symbol: V). She has prepared a series of standard solutions to ensure a linear instrument response over the expected Ca concentration range of 40-80 ppm. The concentrations of Ca and V (ppm) and the instrument response (peak area, arbitrary units) are shown below. Also included is a sample spectrum. Equation 1 describes the response factor, K, relating the analyte signal (SA) and the standard signal (SIS) to their respective concentrations (CA and CIS).
Ca, ppm
V, ppm
SCa, arb. units
SV, arb. units
20.0
10.0
14375.11
14261.02
40.0
10.0
36182.15
17997.10
60.0
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39275.74
12988.01
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57530.75
14268.54
100.0…
A mixture of 0.568 M H₂O, 0.438 M Cl₂O, and 0.710 M HClO are enclosed in a vessel at 25 °C.
H₂O(g) + C₁₂O(g) = 2 HOCl(g)
K = 0.0900 at 25°C
с
Calculate the equilibrium concentrations of each gas at 25 °C.
[H₂O]=
[C₁₂O]=
[HOCI]=
M
Σ
M
What units (if any) does the response factor (K) have? Does the response factor (K) depend upon how the concentration is expressed (e.g. molarity, ppm, ppb, etc.)?
Chapter 7 Solutions
Bundle: Chemistry in Focus, Loose-leaf Version, 7th + OWLv2, 1 term (6 months) Printed Access Card
Ch. 7 - Prob. 7.1YTCh. 7 - The lasers used in supermarket scanners emit red...Ch. 7 - Which photons contain more energy, X-ray photons...Ch. 7 - Arrange the kinds of light listed below in order...Ch. 7 - Prob. 1ECh. 7 - What kinds of molecules are responsible for the...Ch. 7 - Prob. 3ECh. 7 - Prob. 4ECh. 7 - What is the relationship between the wavelength of...Ch. 7 - Prob. 6E
Ch. 7 - Prob. 7ECh. 7 - What prevents large amounts of high-energy UV and...Ch. 7 - Prob. 9ECh. 7 - Prob. 10ECh. 7 - Prob. 11ECh. 7 - Prob. 12ECh. 7 - Prob. 13ECh. 7 - Prob. 14ECh. 7 - Prob. 15ECh. 7 - Prob. 16ECh. 7 - Describe how a laser works.Ch. 7 - Classify each of the following lasers as to type...Ch. 7 - Prob. 19ECh. 7 - Prob. 20ECh. 7 - Prob. 21ECh. 7 - Prob. 22ECh. 7 - Prob. 23ECh. 7 - The speed of sound is 330m/s. If fireworks are...Ch. 7 - The nearest star, Alpha Centauri, is 4.3 light-...Ch. 7 - Counting the seconds between a flash of lightning...Ch. 7 - Make a drawing, such as Figure 7.3, which shows...Ch. 7 - Make a drawing, such as Figure 7.3, which shows...Ch. 7 - Prob. 29ECh. 7 - Arrange the following three frequencies of light...Ch. 7 - Prob. 31ECh. 7 - Which wavelength of light is most likely to cause...Ch. 7 - List two types of electromagnetic radiation that...Ch. 7 - List two types of electromagnetic radiation that...Ch. 7 - Prob. 35ECh. 7 - Prob. 36ECh. 7 - Prob. 37ECh. 7 - Prob. 38ECh. 7 - Calculate the wavelength of the radio waves used...Ch. 7 - Calculate the wavelength of the radio waves used...Ch. 7 - Prob. 41ECh. 7 - Prob. 42ECh. 7 - Prob. 43ECh. 7 - A lamp emits red light of 671nm. What element is...Ch. 7 - Prob. 45ECh. 7 - Prob. 46ECh. 7 - Prob. 47ECh. 7 - Prob. 48ECh. 7 - Describe how white light interacts with a colored...Ch. 7 - Prob. 50ECh. 7 - Prob. 51ECh. 7 - Prob. 52ECh. 7 - Prob. 53ECh. 7 - Prob. 54ECh. 7 - Prob. 55ECh. 7 - Prob. 56ECh. 7 - Prob. 57ECh. 7 - Prob. 58ECh. 7 - Prob. 59E
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