Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Textbook Question
Chapter 7, Problem 185CP
The ionization energy for a 1s electron in a silver atom is 2.462 × 106 kJ/mol.
a. Determine an approximate value for Zeff for the Ag 1s electron. Assume the
b. How does Zeff from part a compare to Z for Ag? Rationalize the relative numbers.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
3. Which of the following states that the electrons in an atom fill lower-
energy atomic orbitals before filling higher-energy? *
O Pauli's Exclusion Principle
O Aufbau Principle
Hund's Rule for Multiplicity
O Slater's Rule for Effective Nuclear Charge
Explain why the graph of ionization energy versus atomic number (across a row) is not linear. Where are the exceptions?
Division of electron shells within the Main Energy Level. eg. s, p, d, and f. *
A Hund's Rule
B.Subshell
C.Valence Electron
D.Pauli's Excdusion Principle
Determine the element with the highest electron
affinity
K19.
Fe26
Br35
Kr84
56
80
A Br
BK
C Kr
bfe
Chapter 7 Solutions
Chemistry
Ch. 7 - Four types of electromagnetic radiation (EMR) are...Ch. 7 - Characterize the Bohr model of the atom. In the...Ch. 7 - What experimental evidence supports the quantum...Ch. 7 - List the most important ideas of the quantum...Ch. 7 - What are quantum numbers? What information do we...Ch. 7 - How do 2p orbitals differ from each other? How do...Ch. 7 - Four blocks of elements in a periodic table refer...Ch. 7 - What is the difference between core electrons and...Ch. 7 - Prob. 9RQCh. 7 - The radius trend and the ionization energy trend...
Ch. 7 - Prob. 1ALQCh. 7 - Defend and criticize Bohrs model. Why was it...Ch. 7 - The first four ionization energies for the...Ch. 7 - Compare the first ionization energy of helium to...Ch. 7 - Which has the larger second ionization energy,...Ch. 7 - Explain why a graph of ionization energy versus...Ch. 7 - Without referring to your text, predict the trend...Ch. 7 - Account for the fact that the line that separates...Ch. 7 - Make sense of the fact that metals tend to lose...Ch. 7 - Explain electron from a quantum mechanical...Ch. 7 - Which is larger, the H 1s orbital or the Li 1s...Ch. 7 - There are an infinite number of allowed electronic...Ch. 7 - Prob. 13ALQCh. 7 - Choose the best response for the following. The...Ch. 7 - Consider the following statement "The ionization...Ch. 7 - Prob. 16ALQCh. 7 - How does probability fit into the description of...Ch. 7 - What is meant by an orbital?Ch. 7 - Explain the difference between the probability...Ch. 7 - Is the following statement true or false? The...Ch. 7 - Which is higher in energy, the 2s or 2p orbital,...Ch. 7 - Prove mathematically that it is more energetically...Ch. 7 - What type of relationship (direct or inverse) e...Ch. 7 - What do we mean by the frequency of...Ch. 7 - Explain the photoelectric effectCh. 7 - Describe briefly why the study of electromagnetic...Ch. 7 - How does the wavelength of a fast-pitched baseball...Ch. 7 - The following is an energy-level diagram for...Ch. 7 - The Bohr model works for only one electron...Ch. 7 - We can represent both probability and radial...Ch. 7 - Consider the representations of the p and d atomic...Ch. 7 - The periodic table consists of four blocks of...Ch. 7 - Many times the claim is made that subshells...Ch. 7 - Prob. 36QCh. 7 - Elements with very large ionization energies also...Ch. 7 - The changes in electron affinity as one goes down...Ch. 7 - Why is it much harder to explain the line spectra...Ch. 7 - Scientists use emission spectra to confirm the...Ch. 7 - Does the minimization of electron-electron...Ch. 7 - In the hydtogen atom, what is the physical...Ch. 7 - On which quantum numbers does the energy of an...Ch. 7 - Although Mendeleev predicted the existence of...Ch. 7 - Photosynthesis uses 660-nm light to convert CO2...Ch. 7 - An FM radio station broadcasts at 99.5 MHz....Ch. 7 - Microwave radiation has a wavelength on the order...Ch. 7 - A photon of ultraviolet (UV) light possesses...Ch. 7 - Octyl methoxycinoamate and oxybenzone are common...Ch. 7 - Human color vision is " produced" by the nervous...Ch. 7 - Consider the following waves representing...Ch. 7 - One type of electromagnetic radiation has a...Ch. 7 - Carbon absorbs energy at a wavelength of 150. nm....Ch. 7 - X rays have wavelengths on the order of 1 1010 m....Ch. 7 - The work function of an element is the energy...Ch. 7 - It takes 208.4 kJ of energy to remove 1 mole of...Ch. 7 - It takes 7.21 1019 J of energy to remove an...Ch. 7 - Ionization energy is the energy required to remove...Ch. 7 - Calculate the de Broglie wavelength for each of...Ch. 7 - Neutron diffraction is used in determining the...Ch. 7 - A particle has a velocity that is 90.% of the...Ch. 7 - Calculate the wavelength of light emiued when each...Ch. 7 - Calculate the wavelength of light emitted when...Ch. 7 - Using vertical lines, indicate the transitions...Ch. 7 - Using vertical lines, indicate the transitions...Ch. 7 - Consider only the transitions involving the first...Ch. 7 - Assume that a hydrogen atoms electron has been...Ch. 7 - Does a photon of visible light ( 400 to 700 nm)...Ch. 7 - An electron is excited from the n = 1 ground state...Ch. 7 - Calculate the maximum wavelength of light capable...Ch. 7 - Consider an electron for a hydrogen atom in an...Ch. 7 - An excited hydrogen atom with an electron in the n...Ch. 7 - An excited hydrogen atom emits light with a...Ch. 7 - Using the Heisenberg uncertainty principle,...Ch. 7 - The Heisenberg uncertainty principle can be...Ch. 7 - What are the possible values for the quantum...Ch. 7 - Identify each of the following orbitals and...Ch. 7 - Which of the following sets of quantum numbers are...Ch. 7 - Which of the following sets of quantum numbers are...Ch. 7 - What is the physical significance of the value of...Ch. 7 - In defining the sizes of orbitals, why must we use...Ch. 7 - Total radial probability distributions for the...Ch. 7 - Tbe relative orbital levels for the hydrogen atom...Ch. 7 - How many orbitals in an atom can have the...Ch. 7 - How many electrons in an atom can have the...Ch. 7 - Give the maximum number of electrons in an atom...Ch. 7 - Give the maximum number of electrons in an atom...Ch. 7 - Draw atomic orbital diagrams representing the...Ch. 7 - For elements l36, there are two exceptions to the...Ch. 7 - The elements Si, Ga, As, Ge, Al, Cd, S, and Se are...Ch. 7 - Write the expected electron configurations for...Ch. 7 - How many electrons would be predicted in the...Ch. 7 - For each of the following elements, which set of...Ch. 7 - Write the expected ground-state electron...Ch. 7 - Using only the periodic table inside the front...Ch. 7 - Given the valence electron orbital level diagram...Ch. 7 - Identify the following elements. a. An excited...Ch. 7 - In the ground state of mercury, Hg, a. how many...Ch. 7 - In the ground state of element 115, Uup, a. how...Ch. 7 - Give a possible set of values of the four quantum...Ch. 7 - Give a possible set of values of the four quantum...Ch. 7 - Valence electrons are those electrons in the...Ch. 7 - How many valence electrons do each of the...Ch. 7 - A certain oxygen atom has the electron...Ch. 7 - Which of the following electron configurations...Ch. 7 - Which of elements 1-36 have two unpaired electrons...Ch. 7 - The first-row transition metals from chromium...Ch. 7 - One bit of evidence that the quantum mechanical...Ch. 7 - Identify how many unpaired electrons are present...Ch. 7 - Prob. 111ECh. 7 - Arrange the following groups of atoms in order of...Ch. 7 - Prob. 113ECh. 7 - Arrange the atoms in Exercise 108 in order of...Ch. 7 - In each of the following sets, which atom or ion...Ch. 7 - In each of the following sets, which atom or ion...Ch. 7 - Element 106 has been named seaborgium, Sg, in...Ch. 7 - The first ionization energies of As and Se are...Ch. 7 - Rank the elements Be, B, C, N, and O in order of...Ch. 7 - Consider the following ionization energies for...Ch. 7 - The following graph plots the first, second, and...Ch. 7 - For each of the following pairs of elements (C and...Ch. 7 - For each of the following pairs of elements (Mg...Ch. 7 - The electron affinities of the elements from...Ch. 7 - In the second row of the periodic table, Be, N,...Ch. 7 - Prob. 127ECh. 7 - Order the atoms in each of the following sets from...Ch. 7 - The electron affinity for sulfur is more negative...Ch. 7 - Which has the more negative electron affinity, the...Ch. 7 - Write equations corresponding to the following: a....Ch. 7 - Using data from the text, determine the following...Ch. 7 - Prob. 133ECh. 7 - Prob. 135ECh. 7 - Cesium was discovered in natural mineral waters in...Ch. 7 - 'The bright yellow light emitted by a sodium vapor...Ch. 7 - Does the information on alkali metals in Table 2-8...Ch. 7 - Predict the atomic number of the next alkali metal...Ch. 7 - "Lithium" is often prescribed as a...Ch. 7 - Prob. 142ECh. 7 - Complete and balance the equations for the...Ch. 7 - Complete and balance the equations for the...Ch. 7 - An unknown element is a nonmetal and has a valence...Ch. 7 - A carbon-oxygen double bond in a certain organic...Ch. 7 - Photogray lenses incorporate small amounts of...Ch. 7 - Mars is roughly 60 million km from the earth. How...Ch. 7 - Consider the following approximate visible light...Ch. 7 - One of the visible lines in the hydrogen emission...Ch. 7 - Using Fig. 2-30, list the elements (ignore the...Ch. 7 - Are the following statements true for the hydrogen...Ch. 7 - Although no currently known elements contain...Ch. 7 - Which of the following orbital designations are...Ch. 7 - The four most abundant elements by mass in the...Ch. 7 - Consider the eight most abundant elements in the...Ch. 7 - An ion having a 4+ charge and a mass of 49.9 u has...Ch. 7 - The successive ionization energies for an unknown...Ch. 7 - In the ground state of cadmium, Cd, a. how many...Ch. 7 - Consider the following idealized PES spectrum for...Ch. 7 - It takes 476 kJ to remove 1 mole of electrons from...Ch. 7 - Calculate, to four significant figures, the...Ch. 7 - Assume that a hydrogen atoms electron bas been...Ch. 7 - Determine the maximum number of electrons that can...Ch. 7 - Consider the ground state of arsenic, As. How many...Ch. 7 - Which of the following statements is(are) true? a....Ch. 7 - Identify the following three elements. a. The...Ch. 7 - For each of the following pairs of elements,...Ch. 7 - Which of the following statements is(are) true? a....Ch. 7 - Three elements have the electron configurations...Ch. 7 - The figure below represents part of the emission...Ch. 7 - One of the emission spectral lines for Be3+ has a...Ch. 7 - The figure below represents part of the emission...Ch. 7 - When lhe excited electron in a hydrogen atom falls...Ch. 7 - Prob. 177CPCh. 7 - For hydrogen atoms, the wave function for the...Ch. 7 - The wave function for the 2pz, orbital in the...Ch. 7 - Answer the following questions, assuming that ms,...Ch. 7 - Assume that we are in another universe with...Ch. 7 - Without looking at data in the text, sketch a...Ch. 7 - The following numbers are the ratios of second...Ch. 7 - We expect the atomic radius to increase going down...Ch. 7 - The ionization energy for a 1s electron in a...Ch. 7 - An atom of a particular element is traveling at...Ch. 7 - As the weapons officer aboard the Srarship...Ch. 7 - Answer the following questions based on the given...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Using the Bohr model, determine the energy in joules of the photon produced when an electron in a L2+ ion moves from the orbit with n = 2 to the orbit with n = 1.arrow_forwardUsing the Bohr model, determine the energy in joules of the photon produced when an electron in a He+ ion moves from the orbit with n = 5 to the orbit with n = 2.arrow_forwardAnswer the following questions, assuming that ms, could have three values rather than two and that the rules for n, l, and ml are the normal ones. a. How many electrons would an orbital be able to hold? b. How many elements would the first and second periods in the periodic table contain? c. How many elements would be contained in the first transition metal series? d. How many electrons would the set of 4f orbitals be able to bold?arrow_forward
- (a) How many subshells are present in the n = 4 shell? (b) How many orbitals are in the 3d subshell? (c) What is the maximum value of that is allowed in the shell with n = 3? (d) What are the values of n and for a 3p subshell? Give all allowed values of the m quantum number for this subshell.arrow_forwardAre the following statements true for the hydrogen atom only, true for all atoms, or not true for any atoms? a. The principal quantum number completely determines the energy of a given electron. b. The angular momentum quantum number, l, determines the shapes of the atomic orbitals. c. The magnetic quantum number, ml, determines the direction that the atomic orbitals point in space.arrow_forwardIn one area of Australia, the cattle did not thrive despite the presence of suitable forage. An investigation showed the cause to be the absence of sufficient cobalt in the soil. Cobalt forms cations in two oxidation states, Co2 and Co3+. Write the electron structure of the two cations.arrow_forward
- Does the information on alkali metals in Table 2-8 of the text confirm the general periodic trends in ionization energy and atomic radius? Explain.arrow_forwarda. Write the electron configuration for Ba²+. (Express your answer as a series of orbitals, in order of increasing orbital energy. For example, the electron configuration of Li would be entered as 1s²2s¹ or [He]2s¹.) b. Write the electron configuration for Ca²+. (Express your answer as a series of orbitals, in order of increasing orbital energy. For example, the electron configuration of Li would be entered as 1s²2s¹ or [He]2s¹.) c. Write the electron configuration for P³-. (Express your answer as a series of orbitals, in order of increasing orbital energy. For example, the electron configuration of Li would be entered as 1s²2s¹ or [He]2s¹.) d. Write the electron configuration for Te²-. (Express your answer as a series of orbitals, in order of increasing orbital energy. For example, the electron configuration of Li would be entered as 1s²2s¹ or [He]2s¹.)arrow_forwardThe ionic radii of K+, Cl−, and S2− are 138, 181, and 184 pm, respectively. Which of the following statements best describes why these isoelectronic species have different radii? Select one: a. The radii of Cl− and S2− are sufficiently close that there is no suitable explanation to explain the variances in ionic radii. b. The effective nuclear charge of the ions determines the size of the radii. c. Alkali metals always have smaller radii that p-block elements. d. There is no explanation to explain why these species have different radii.arrow_forward
- 1. Which set of coefficients balances the equation a SiCl4 + b NH3 = c Si3N4 + d HCl? 2.Which of the following answers shows the correct relationships between the ionization energies of the atoms Na, Mg, and K? Select one: a. IE(Mg) > IE(K) > IE(Na). b. IE(Mg) > IE(Na) > IE(K). c. IE(Mg) > IE(Na) and IE(K) > IE(Na). d. IE(Na) > IE(K) and IE(Na) > IE(Mg). e. IE(K) > IE(Na) > IE(Mg).arrow_forward3. The figure below shows the Radial wave function, Y(r) vs. r, in red and the Radial probability function (also called radial distribution function), 4rr²Y (r) vs. r, in blue, for an atomic orbital. a) What is the n quantum number of this atomic orbital? Radial probability distribution b) What is thel quantum number of this atomic orbital? c) What is the highest number of electrons that can occupy this orbital? d) At what distance from the nucleus is the electron most likely to exist? (in Å) Radial wave function 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 Radius (Å)arrow_forwardSolve question 1 and the subparts (a,b,c). Write four quantum numbers to describe the highest energy electron in the magnesium atom. Be sure to include the four symbols and four correct numbers. a. Arrange the following in order of increasing first ionization energy: Br, F, I, Cl b. Write the complete electron configuration for Mg2+. c. Which would be larger? Na or Na+ ? Explain why?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Quantum Numbers, Atomic Orbitals, and Electron Configurations; Author: Professor Dave Explains;https://www.youtube.com/watch?v=Aoi4j8es4gQ;License: Standard YouTube License, CC-BY
QUANTUM MECHANICAL MODEL/Atomic Structure-21E; Author: H to O Chemistry;https://www.youtube.com/watch?v=mYHNUy5hPQE;License: Standard YouTube License, CC-BY