The authenticity of the statement, “The effective nuclear charge can be thought of as the true nuclear charge minus a screening constant due to the other electron in the atom.”
The authenticity of the statement, “The effective nuclear charge can be thought of as the true nuclear charge minus a screening constant due to the other electron in the atom.”
To determine: The authenticity of the statement, “The effective nuclear charge can be thought of as the true nuclear charge minus a screening constant due to the other electron in the atom.”
(ii)
Interpretation Introduction
To determine: The authenticity of the statement, “Effective nuclear charge increases going from left to right across a row of the periodic table.”
(iii)
Interpretation Introduction
To determine: The authenticity of the statement, “Valence electrons screen the nuclear charge more effectively than do core electrons.”
(iv)
Interpretation Introduction
To determine: The authenticity of the statement “The effective nuclear charge shows a sudden decrease when we go from the end of one row to the beginning of the next row of the periodic table.”
(v)
Interpretation Introduction
To determine: The authenticity of the statement “The change in effective nuclear charge going down a column of the periodic table is generally less than that going across a row of the periodic table.”
8. The emission spectrum below for a one-electron (hydrogen-like) species in the
gas phase shows all the lines, before they merge together, resulting from
transitions to the ground state from higher energy states. Line A has a
wavelength of 10.8 nm.
BA
Increasing wavelength, \ -
a) What are the upper and lower principal quantum numbers corresponding to
the lines labeled A and B?
b) Identify the one-electron species that exhibits the spectrum.
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Solution
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
+98
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possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
+90
MgBr
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possible
CH3CH2CH2MgBr
Q10
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Q11
?
?
+100
in 1 attempt
2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3