The tri-substituted π bond and E or Z configuration are to be interpreted. Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers. The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

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Answer 1

Question

Chapter 7, Problem 103IP

(a)

Interpretation Introduction

Interpretation: The tri-substituted π bond and E or Z configuration are to be interpreted.

Concept Introduction:

Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(b)

Interpretation Introduction

Interpretation: Total stereoisomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(c)

Interpretation Introduction

Interpretation: The enantiomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(e)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of each chiral center connected with ester oxygen is interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(f)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of the disubstituted π bond is to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as the structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

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Answer 2

Question

Chapter 7, Problem 103IP

(a)

Interpretation Introduction

Interpretation: The tri-substituted π bond and E or Z configuration are to be interpreted.

Concept Introduction:

Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(b)

Interpretation Introduction

Interpretation: Total stereoisomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(c)

Interpretation Introduction

Interpretation: The enantiomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(e)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of each chiral center connected with ester oxygen is interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(f)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of the disubstituted π bond is to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as the structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

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Answer 3

Question

Chapter 7, Problem 103IP

(a)

Interpretation Introduction

Interpretation: The tri-substituted π bond and E or Z configuration are to be interpreted.

Concept Introduction:

Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(b)

Interpretation Introduction

Interpretation: Total stereoisomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(c)

Interpretation Introduction

Interpretation: The enantiomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(e)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of each chiral center connected with ester oxygen is interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(f)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of the disubstituted π bond is to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as the structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

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Answer 4

Question

Chapter 7, Problem 103IP

(a)

Interpretation Introduction

Interpretation: The tri-substituted π bond and E or Z configuration are to be interpreted.

Concept Introduction:

Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(b)

Interpretation Introduction

Interpretation: Total stereoisomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(c)

Interpretation Introduction

Interpretation: The enantiomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(e)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of each chiral center connected with ester oxygen is interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(f)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of the disubstituted π bond is to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as the structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

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Answer 5

Chapter 7, Problem 103IP

(a)

Interpretation Introduction

Interpretation: The tri-substituted π bond and E or Z configuration are to be interpreted.

Concept Introduction:

Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(b)

Interpretation Introduction

Interpretation: Total stereoisomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(c)

Interpretation Introduction

Interpretation: The enantiomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(e)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of each chiral center connected with ester oxygen is interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

(f)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of the disubstituted π bond is to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as the structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

Answer 6

Chapter 7, Problem 103IP

(a)

Interpretation Introduction

Interpretation: The tri-substituted π bond and E or Z configuration are to be interpreted.

Concept Introduction:

Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

Answer 7

Chapter 7, Problem 103IP

(a)

Interpretation Introduction

Interpretation: The tri-substituted π bond and E or Z configuration are to be interpreted.

Concept Introduction:

Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

Answer 8

(b)

Interpretation Introduction

Interpretation: Total stereoisomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

Answer 9

(b)

Interpretation Introduction

Interpretation: Total stereoisomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

Answer 10

(c)

Interpretation Introduction

Interpretation: The enantiomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

Answer 11

(c)

Interpretation Introduction

Interpretation: The enantiomers for pladienolide B are to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

Answer 12

(e)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of each chiral center connected with ester oxygen is interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

Answer 13

(e)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of each chiral center connected with ester oxygen is interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

Answer 14

(f)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of the disubstituted π bond is to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as the structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

Answer 15

(f)

Interpretation Introduction

Interpretation: The diastereomer that is identical to pladienolide B except for the configuration of the disubstituted π bond is to be interpreted.

Concept Introduction: Isomers of the organic molecules with the same type of molecular structures and different types of structures. On the basis of the structure and 3D arrangement of the molecules, the isomers can be classified as the structural isomers and constitutional isomers.

The geometrical isomers are the isomers with different configurations around the double-bonded carbon atoms.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 7.2 - Prob. 1CC Ch. 7.3 - Prob. 2CC Ch. 7.3 - Prob. 1LTS Ch. 7.3 - Prob. 3PTS Ch. 7.3 - Prob. 4ATS Ch. 7.3 - Prob. 2LTS Ch. 7.3 - Prob. 5PTS Ch. 7.3 - Prob. 6ATS Ch. 7.3 - Prob. 7CC Ch. 7.4 - Prob. 8CC

Solution Summary: The author explains that the tri-substituted pi bond and E or Z configuration are to be interpreted.

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