Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321910417
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 6.9, Problem 6.8.1PE
A cell has a standard cell potential of +0.177 V at 298K. What is the value of the equilibrium constant for the reaction
- If n = 1?
- If n = 2?
- If n =3?
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
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Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
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You will find it useful to keep in mind that NH3 is a weak base.
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bases: ☐
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other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
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other: ☐
0,0,...
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
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Round your answer to 2 significant digits.
yes
no
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
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Chapter 6 Solutions
Chemistry: The Central Science (13th Edition)
Ch. 6.1 - Prob. 6.1.1PECh. 6.1 - Practice Exercise 2 If one of the waves in the...Ch. 6.1 - Prob. 6.2.1PECh. 6.1 - Prob. 6.2.2PECh. 6.2 - Assuming standard conditions, arrange the...Ch. 6.2 - Prob. 6.3.2PECh. 6.3 - Practice Exercise 1 In the top part of Figure...Ch. 6.3 - Prob. 6.4.2PECh. 6.4 - Prob. 6.5.1PECh. 6.4 - For each of the following reactions, write a...
Ch. 6.5 - Prob. 6.6.1PECh. 6.5 - Prob. 6.6.2PECh. 6.8 - Prob. 6.7.1PECh. 6.8 - Prob. 6.7.2PECh. 6.9 - A cell has a standard cell potential of +0.177 V...Ch. 6.9 - Prob. 6.8.2PECh. 6.9 - Prob. 6.9.1PECh. 6.9 - Prob. 6.9.2PECh. 6 - Prob. 1DECh. 6 - Prob. 1ECh. 6 - Prob. 2ECh. 6 - Prob. 3ECh. 6 - Prob. 4ECh. 6 - Prob. 5ECh. 6 - The familiar phenomenon of a rainbow results from...Ch. 6 - Prob. 7ECh. 6 - Prob. 8ECh. 6 - Prob. 9ECh. 6 - Prob. 10ECh. 6 - Prob. 11ECh. 6 - Prob. 12ECh. 6 - Prob. 13ECh. 6 - Prob. 14ECh. 6 - Prob. 15ECh. 6 - In some applications nickel-cadmium batteries have...Ch. 6 - Prob. 17ECh. 6 - Prob. 18ECh. 6 - Prob. 19ECh. 6 - Prob. 20ECh. 6 - Prob. 21ECh. 6 - Prob. 22ECh. 6 - Prob. 23ECh. 6 - Prob. 24ECh. 6 - Prob. 25ECh. 6 - Prob. 26ECh. 6 - Prob. 27ECh. 6 - Metallic magnesium can be made by the electrolysis...Ch. 6 - 20.93
Calculate the mass of Li formed by...Ch. 6 - Prob. 30ECh. 6 - Prob. 31ECh. 6 - Prob. 32ECh. 6 - Prob. 33ECh. 6 - Titanium metal requires a photon with a minimum...Ch. 6 - Explain how the existence of line spectra is...Ch. 6 - Prob. 36ECh. 6 - Prob. 37ECh. 6 - Prob. 38ECh. 6 - Prob. 39ECh. 6 - Prob. 40ECh. 6 - Prob. 41ECh. 6 - Prob. 42ECh. 6 - Prob. 43ECh. 6 - Prob. 44ECh. 6 - Prob. 45ECh. 6 - Prob. 46ECh. 6 - Prob. 47ECh. 6 - Prob. 48ECh. 6 - Prob. 49ECh. 6 - Prob. 50ECh. 6 - Prob. 51ECh. 6 - Prob. 52ECh. 6 - Prob. 53ECh. 6 - Prob. 54ECh. 6 - Prob. 55ECh. 6 - Prob. 56ECh. 6 - Prob. 57ECh. 6 - Prob. 58ECh. 6 - Prob. 59ECh. 6 - Prob. 60ECh. 6 - Prob. 61ECh. 6 - Prob. 62ECh. 6 - Prob. 63ECh. 6 - Prob. 64ECh. 6 - Prob. 65ECh. 6 - Prob. 66ECh. 6 - Prob. 67ECh. 6 - Prob. 68ECh. 6 - Prob. 69ECh. 6 - Prob. 70ECh. 6 - Prob. 71ECh. 6 - Prob. 72ECh. 6 - Prob. 73ECh. 6 - Prob. 74ECh. 6 - Prob. 75ECh. 6 - Prob. 76ECh. 6 - Prob. 77ECh. 6 - Prob. 78ECh. 6 - Prob. 79ECh. 6 - Prob. 80ECh. 6 - Prob. 81AECh. 6 - Prob. 82AECh. 6 - Prob. 83AECh. 6 - In August 2011, the Juno spacecraft Was launched...Ch. 6 - Prob. 85AECh. 6 - Prob. 86AECh. 6 - Prob. 87AECh. 6 - Prob. 88AECh. 6 - Prob. 89AECh. 6 - Prob. 90AECh. 6 - Prob. 91AECh. 6 - Prob. 92AECh. 6 - Prob. 93AECh. 6 - Prob. 94AECh. 6 - Prob. 95AECh. 6 - Prob. 96AECh. 6 - Prob. 97AECh. 6 - Prob. 98AECh. 6 - Prob. 99AECh. 6 - Prob. 100AECh. 6 - Prob. 101AECh. 6 - Prob. 102AECh. 6 - A voltaic cell utilizes the following reaction:...Ch. 6 - Prob. 104AECh. 6 - Prob. 105IECh. 6 - Prob. 106IECh. 6 - Prob. 107IECh. 6 - Prob. 108IECh. 6 - Prob. 109IECh. 6 - 20. 72 A voltaic cell is constructed that is based...
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