Chapter 6.9, Problem 6.15P

(a)

Interpretation Introduction

To determine: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into $\text{butan}-1-\text{ol}$.

Interpretation: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into $\text{butan}-1-\text{ol}$ is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}\text{2}$ reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(b)

Interpretation Introduction

To determine: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into $\text{1-fluorobutane}$.

Interpretation: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into $\text{1-fluorobutane}$ is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}\text{2}$ reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(c)

Interpretation Introduction

To determine: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into $\text{1-iodobutane}$.

Interpretation: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into $\text{1-iodobutane}$ is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}\text{2}$ reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(d)

Interpretation Introduction

To determine: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into ${\text{CH}}_3-{\left({\text{CH}}_2\right)}_3-\text{CN}$.

Interpretation: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into ${\text{CH}}_3-{\left({\text{CH}}_2\right)}_3-\text{CN}$ is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}\text{2}$ reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(e)

Interpretation Introduction

To determine: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into the given alkyne compound.

Interpretation: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into the given alkyne compound is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}\text{2}$ reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(f)

Interpretation Introduction

To determine: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into ${\text{CH}}_3{\text{CH}}_2-\text{O}-{\left({\text{CH}}_{\text{2}}\right)}_3-{\text{CH}}_3$.

Interpretation: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into ${\text{CH}}_3{\text{CH}}_2-\text{O}-{\left({\text{CH}}_{\text{2}}\right)}_3-{\text{CH}}_3$ is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}\text{2}$ reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

(g)

Interpretation Introduction

To determine: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into ${\text{CH}}_3-{\left({\text{CH}}_2\right)}_3-{\text{NH}}_2$.

Interpretation: The usage of ${\text{S}}_{\text{N}}2$ reaction in the conversion of $1-\text{chlorobutane}$ into ${\text{CH}}_3-{\left({\text{CH}}_2\right)}_3-{\text{NH}}_2$ is to be predicted.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.

The nucleophilic reaction that contains a substrate as well as a nucleophile as the reactants which means a bimolecular nucleophilic reaction is termed as ${\text{S}}_{\text{N}}\text{2}$ reaction. It includes the bond-making and bond-breaking steps. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.