When a photoelectric effect experiment was carried out using a metal 'M' and light at wavelength λ 1 , electrons were emitted with a kinetic energy of 1 .6 × 1 0 − 19 J . The wavelength was reduced to 1/2 of its original value and the experiment was repeated (still using the same metal target). This time electrons were emitted with a kinetic energy of 6 .4 × 1 0 − 19 J .The electron binding energy for the metal M needs to be calculated. Concept introduction: The photelectric effect alludes to the ejection, or emission of the electrons from the surface ofusually a metal in reply to the incident light. In the incident light the contained energy is absorbed through electrons in the metal, providing the electrons required energy to be “bumped” out of or released from the metal’s surface. As per the Maxwell wave theory of light,the more concentrated the incident light, the higher the energy through which the electrons should be emitted from the metal. The emitted electron’s average kinetic energy should increment with the incident light’s intensity.
When a photoelectric effect experiment was carried out using a metal 'M' and light at wavelength λ 1 , electrons were emitted with a kinetic energy of 1 .6 × 1 0 − 19 J . The wavelength was reduced to 1/2 of its original value and the experiment was repeated (still using the same metal target). This time electrons were emitted with a kinetic energy of 6 .4 × 1 0 − 19 J .The electron binding energy for the metal M needs to be calculated. Concept introduction: The photelectric effect alludes to the ejection, or emission of the electrons from the surface ofusually a metal in reply to the incident light. In the incident light the contained energy is absorbed through electrons in the metal, providing the electrons required energy to be “bumped” out of or released from the metal’s surface. As per the Maxwell wave theory of light,the more concentrated the incident light, the higher the energy through which the electrons should be emitted from the metal. The emitted electron’s average kinetic energy should increment with the incident light’s intensity.
Solution Summary: The author explains the photelectric effect, which ejects electrons from the surface of a metal in response to the incident light.
Definition Definition Phenomenon in which a substance absorbs electromagnetic radiation and electrically charged particles are emitted from or inside it.
Chapter 6, Problem 6.82PAE
Interpretation Introduction
Interpretation: When a photoelectric effect experiment was carried out using a metal 'M' and light at wavelength λ1, electrons were emitted with a kinetic energy of 1.6×10−19 J. The wavelength was reduced to 1/2 of its original value and the experiment was repeated (still using the same metal target). This time electrons were emitted with a kinetic energy of 6.4×10−19 J.The electron binding energy for the metal M needs to be calculated.
Concept introduction:
The photelectric effect alludes to the ejection, or emission of the electrons from the surface ofusually a metal in reply to the incident light.
In the incident light the contained energy is absorbed through electrons in the metal, providing the electrons required energy to be “bumped” out of or released from the metal’s surface.
As per the Maxwell wave theory of light,the more concentrated the incident light, the higher the energy through which the electrons should be emitted from the metal. The emitted electron’s average kinetic energy should increment with the incident light’s intensity.
Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
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