Chemistry: The Molecular Nature of Matter and Change - Standalone book
Chemistry: The Molecular Nature of Matter and Change - Standalone book
7th Edition
ISBN: 9780073511177
Author: Martin Silberberg Dr., Patricia Amateis Professor
Publisher: McGraw-Hill Education
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Chapter 6, Problem 6.76P

(a)

Interpretation Introduction

Interpretation:

The changes that are needed in the following reaction so that the enthalpy change is equal to ΔHf° for the compound are to be determined.

Cl(g)+Na(s)NaCl(s)

Concept introduction:

The standard enthalpy of formation (ΔHf°) is the enthalpy change of the formation of 1mol of compound from its elements and the reactants and products, in this case, is also present in their standard state.

Standard state includes 1atm pressure for gases, 1M concentration for substances in the aqueous phase and the most stable form of substance at 1atm pressure and 298K temperature. For example, metal like sodium exists in solid state and molecular elements like halogen exist in a gaseous state.

(b)

Interpretation Introduction

Interpretation:

The changes that are needed in the following reaction so that the enthalpy change is equal to ΔHf° for the compound are to be determined.

H2O(g)2H(g)+12O2(g)

Concept introduction:

The standard enthalpy of formation (ΔHf°) is the enthalpy change of the formation of 1mol of compound from its elements and the reactants and products, in this case, is also present in their standard state.

Standard state includes 1atm pressure for gases, 1M concentration for substances in the aqueous phase and the most stable form of substance at 1atm pressure and 298K temperature. For example, metal like sodium exists in solid state and molecular elements like halogen exist in a gaseous state.

(c)

Interpretation Introduction

Interpretation:

The changes that are needed in the following reaction so that the enthalpy change is equal to ΔHf° for the compound are to be determined.

12N2(g)+32H2NH3(g)

Concept introduction:

The standard enthalpy of formation (ΔHf°) is the enthalpy change of the formation of 1mol of compound from its elements and the reactants and products, in this case, is also present in their standard state.

Standard state includes 1atm pressure for gases, 1M concentration for substances in the aqueous phase and the most stable form of substance at 1atm pressure and 298K temperature. For example, metal like sodium exists in solid state and molecular elements like halogen exist in a gaseous state.

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Chapter 6 Solutions

Chemistry: The Molecular Nature of Matter and Change - Standalone book

Ch. 6.3 - When 25.0 mL of 2.00 M HNO3 and 50.0 mL of 1.00 M...Ch. 6.3 - Prob. 6.6BFPCh. 6.3 - Prob. 6.7AFPCh. 6.3 - Prob. 6.7BFPCh. 6.4 - Prob. 6.8AFPCh. 6.4 - Prob. 6.8BFPCh. 6.5 - Prob. 6.9AFPCh. 6.5 - Prob. 6.9BFPCh. 6.6 - Prob. 6.10AFPCh. 6.6 - Prob. 6.10BFPCh. 6.6 - Prob. 6.11AFPCh. 6.6 - Prob. 6.11BFPCh. 6.6 - Prob. B6.1PCh. 6.6 - Prob. B6.2PCh. 6 - Prob. 6.1PCh. 6 - Prob. 6.2PCh. 6 - Prob. 6.3PCh. 6 - Prob. 6.4PCh. 6 - Prob. 6.5PCh. 6 - Prob. 6.6PCh. 6 - Prob. 6.7PCh. 6 - Prob. 6.8PCh. 6 - A system releases 255 cal of heat to the...Ch. 6 - What is the change in internal energy (in J) of a...Ch. 6 - Prob. 6.11PCh. 6 - Prob. 6.12PCh. 6 - Thermal decomposition of 5.0 metric tons of...Ch. 6 - The nutritional calorie (Calorie) is equivalent to...Ch. 6 - If an athlete expends 1950 kJ/h, how long does it...Ch. 6 - Why is the work done when a system expands against...Ch. 6 - Prob. 6.17PCh. 6 - Hot packs used by skiers produce heat via the...Ch. 6 - Prob. 6.19PCh. 6 - Prob. 6.20PCh. 6 - For each process, state whether ΔH is less than...Ch. 6 - Prob. 6.22PCh. 6 - The external pressure on a gas sample is 2660...Ch. 6 - Prob. 6.24PCh. 6 - Prob. 6.25PCh. 6 - Prob. 6.26PCh. 6 - Prob. 6.27PCh. 6 - Prob. 6.28PCh. 6 - Prob. 6.29PCh. 6 - Prob. 6.30PCh. 6 - Prob. 6.31PCh. 6 - Prob. 6.32PCh. 6 - What data do you need to determine the specific...Ch. 6 - Is the specific heat capacity of a substance an...Ch. 6 - Prob. 6.35PCh. 6 - Both a coffee-cup calorimeter and a bomb...Ch. 6 - Find q when 22.0 g of water is heated from 25.0°C...Ch. 6 - Calculate q when 0.10 g of ice is cooled from...Ch. 6 - A 295-g aluminum engine part at an initial...Ch. 6 - Prob. 6.40PCh. 6 - Two iron bolts of equal mass—one at 100.°C, the...Ch. 6 - Prob. 6.42PCh. 6 - Prob. 6.43PCh. 6 - Prob. 6.44PCh. 6 - Prob. 6.45PCh. 6 - A 30.5-g sample of an alloy at 93.0°C is placed...Ch. 6 - High-purity benzoic acid (C6H5COOH; ΔH for...Ch. 6 - Two aircraft rivets, one iron and the other...Ch. 6 - A chemical engineer placed 1.520 g of a...Ch. 6 - When 25.0 mL of 0.500 M H2SO4 is added to 25.0 mL...Ch. 6 - Prob. 6.51PCh. 6 - Prob. 6.52PCh. 6 - Prob. 6.53PCh. 6 - Consider the following balanced thermochemical...Ch. 6 - Prob. 6.55PCh. 6 - Prob. 6.56PCh. 6 - When 1 mol of KBr(s) decomposes to its elements,...Ch. 6 - Prob. 6.58PCh. 6 - Compounds of boron and hydrogen are remarkable for...Ch. 6 - Prob. 6.60PCh. 6 - Prob. 6.61PCh. 6 - Prob. 6.62PCh. 6 - Prob. 6.63PCh. 6 - Prob. 6.64PCh. 6 - Prob. 6.65PCh. 6 - Prob. 6.66PCh. 6 - Prob. 6.67PCh. 6 - Prob. 6.68PCh. 6 - Write the balanced overall equation (equation 3)...Ch. 6 - Prob. 6.70PCh. 6 - Prob. 6.71PCh. 6 - Prob. 6.72PCh. 6 - Prob. 6.73PCh. 6 - Prob. 6.74PCh. 6 - Prob. 6.75PCh. 6 - Prob. 6.76PCh. 6 - Prob. 6.77PCh. 6 - Prob. 6.78PCh. 6 - Prob. 6.79PCh. 6 - Calculatefor each of the following: SiO2(s) +...Ch. 6 - Prob. 6.81PCh. 6 - Prob. 6.82PCh. 6 - The common lead-acid car battery produces a large...Ch. 6 - Prob. 6.84PCh. 6 - Prob. 6.85PCh. 6 - Prob. 6.86PCh. 6 - Prob. 6.87PCh. 6 - Prob. 6.88PCh. 6 - Prob. 6.89PCh. 6 - The following scenes represent a gaseous reaction...Ch. 6 - Prob. 6.91PCh. 6 - Prob. 6.92PCh. 6 - Prob. 6.93PCh. 6 - Prob. 6.94PCh. 6 - Prob. 6.95PCh. 6 - Prob. 6.96PCh. 6 - Prob. 6.97PCh. 6 - Prob. 6.98PCh. 6 - Prob. 6.99PCh. 6 - Prob. 6.100PCh. 6 - Prob. 6.101PCh. 6 - Prob. 6.102PCh. 6 - Prob. 6.103PCh. 6 - Liquid methanol (CH3OH) canbe used as an...Ch. 6 - Prob. 6.105P
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