6.71 Several excited states of the neon atom are important in the operation of a helium-neon laser. In these excited states, one electron of the neon atom is promoted from the 2p level to a higher energy orbital. An excited neon atom with a 1 s 2 2 s 2 2 p 5 5 s 1 electron configuration can emit a photon with a wavelength of 3391 nm as it makes a transition to a lower energy state with a 1 s 2 2 s 2 2 p 5 4 p 1 electron configuration. Other transitions are also possible. If an excited neon atom with a 1 s 2 2 s 2 2 p 5 3 p 1 electron configuration makes a transition to a lower energy state with a 1 s 2 2 s 2 2 p 5 3 p 1 electron configuration, it emits a photon with a wavelength of 632.8 nm. Find the wavelength of the photon that would be emitted in a transition from the 1 s 2 2 s 2 2 p 5 4 p 1 electron configuration to the 1 s 2 2 s 2 2 p 5 3 p 1 electron configuration. (It should help if you start by drawing an energy-level diagram.)
6.71 Several excited states of the neon atom are important in the operation of a helium-neon laser. In these excited states, one electron of the neon atom is promoted from the 2p level to a higher energy orbital. An excited neon atom with a 1 s 2 2 s 2 2 p 5 5 s 1 electron configuration can emit a photon with a wavelength of 3391 nm as it makes a transition to a lower energy state with a 1 s 2 2 s 2 2 p 5 4 p 1 electron configuration. Other transitions are also possible. If an excited neon atom with a 1 s 2 2 s 2 2 p 5 3 p 1 electron configuration makes a transition to a lower energy state with a 1 s 2 2 s 2 2 p 5 3 p 1 electron configuration, it emits a photon with a wavelength of 632.8 nm. Find the wavelength of the photon that would be emitted in a transition from the 1 s 2 2 s 2 2 p 5 4 p 1 electron configuration to the 1 s 2 2 s 2 2 p 5 3 p 1 electron configuration. (It should help if you start by drawing an energy-level diagram.)
6.71 Several excited states of the neon atom are important in the operation of a helium-neon laser. In these excited states, one electron of the neon atom is promoted from the 2p level to a higher energy orbital.
An excited neon atom with a
1
s
2
2
s
2
2
p
5
5
s
1
electron configuration can emit a photon with a wavelength of 3391 nm as it makes a transition to a lower energy state with a
1
s
2
2
s
2
2
p
5
4
p
1
electron configuration. Other transitions are also possible. If an excited neon atom with a
1
s
2
2
s
2
2
p
5
3
p
1
electron configuration makes a transition to a lower energy state with a
1
s
2
2
s
2
2
p
5
3
p
1
electron configuration, it emits a photon with a wavelength of 632.8 nm. Find the wavelength of the photon that would be emitted in a transition from the
1
s
2
2
s
2
2
p
5
4
p
1
electron configuration to the
1
s
2
2
s
2
2
p
5
3
p
1
electron configuration. (It should help if you start by drawing an energy-level diagram.)
10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
८८
2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Quantum Numbers, Atomic Orbitals, and Electron Configurations; Author: Professor Dave Explains;https://www.youtube.com/watch?v=Aoi4j8es4gQ;License: Standard YouTube License, CC-BY