Chemistry (OER)
2nd Edition
ISBN: 9781947172616
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 6, Problem 66E
Write a set of quantum numbers for each of the electrons with an
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19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water?
Group of answer choices
LiBr
LiI
LiF
LiCl
Q4: Write organic product(s) of the following reactions and show the curved-arrow mechanism
of the reactions.
Br
MeOH
OSO2CH3
MeOH
Chapter 6 Solutions
Chemistry (OER)
Ch. 6 - The light produced by a red neon sign is due to...Ch. 6 - An FM radio station found at 103.1 on the FM dial...Ch. 6 - FM-95, an FM radio station, broadcasts at a...Ch. 6 - A bright violet line occurs at 435.8 nm in the...Ch. 6 - Light with a wavelength of 614.5 nm looks orange....Ch. 6 - Heated lithium atoms emit photons of light with an...Ch. 6 - A photon of light produced by a surgical laser has...Ch. 6 - When rubidium ions are heated to a high...Ch. 6 - The emission spectrum of cesium contains two lines...Ch. 6 - Photons of infrared radiation are responsible for...
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