CHEMISTRY ATOM FOCUSED EBK W/ A.C. >I<
CHEMISTRY ATOM FOCUSED EBK W/ A.C. >I<
2nd Edition
ISBN: 9780393657159
Author: Gilbert
Publisher: NORTON
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fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10
elow are experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.? 0.4 H (mm) 0.2 0.1- 0.3- 0 0.5 H (mm) 8.0 7.0 6.0 5.0 4.0- 3.0 T +++ 1.0 1.5 0 2.0 4.0 Flow Rate, u (cm/s) 6.0 8.0 Flow Rate, u (cm/s)

Chapter 6 Solutions

CHEMISTRY ATOM FOCUSED EBK W/ A.C. >I<

Ch. 6 - Prob. 6.11VPCh. 6 - Prob. 6.12VPCh. 6 - Prob. 6.13VPCh. 6 - Prob. 6.14VPCh. 6 - Prob. 6.15VPCh. 6 - Prob. 6.16VPCh. 6 - Prob. 6.17QACh. 6 - Prob. 6.18QACh. 6 - Prob. 6.19QACh. 6 - Prob. 6.20QACh. 6 - Prob. 6.21QACh. 6 - Prob. 6.22QACh. 6 - Prob. 6.23QACh. 6 - Prob. 6.24QACh. 6 - Prob. 6.25QACh. 6 - Prob. 6.26QACh. 6 - Prob. 6.27QACh. 6 - Prob. 6.28QACh. 6 - Prob. 6.29QACh. 6 - Prob. 6.30QACh. 6 - Prob. 6.31QACh. 6 - Prob. 6.32QACh. 6 - Prob. 6.33QACh. 6 - Prob. 6.34QACh. 6 - Prob. 6.35QACh. 6 - Prob. 6.36QACh. 6 - Prob. 6.37QACh. 6 - Prob. 6.38QACh. 6 - Prob. 6.39QACh. 6 - Prob. 6.40QACh. 6 - Prob. 6.41QACh. 6 - Prob. 6.42QACh. 6 - Prob. 6.43QACh. 6 - Prob. 6.44QACh. 6 - Prob. 6.45QACh. 6 - Prob. 6.46QACh. 6 - Prob. 6.47QACh. 6 - Prob. 6.48QACh. 6 - Prob. 6.49QACh. 6 - Prob. 6.50QACh. 6 - Prob. 6.51QACh. 6 - Prob. 6.52QACh. 6 - Prob. 6.53QACh. 6 - Prob. 6.54QACh. 6 - Prob. 6.55QACh. 6 - Prob. 6.56QACh. 6 - Prob. 6.57QACh. 6 - Prob. 6.58QACh. 6 - Prob. 6.59QACh. 6 - Prob. 6.60QACh. 6 - Prob. 6.61QACh. 6 - Prob. 6.62QACh. 6 - Prob. 6.63QACh. 6 - Prob. 6.64QACh. 6 - Prob. 6.65QACh. 6 - Prob. 6.66QACh. 6 - Prob. 6.67QACh. 6 - Prob. 6.68QACh. 6 - Prob. 6.69QACh. 6 - Prob. 6.70QACh. 6 - Prob. 6.71QACh. 6 - Prob. 6.72QACh. 6 - Prob. 6.73QACh. 6 - Prob. 6.74QACh. 6 - Prob. 6.75QACh. 6 - Prob. 6.76QACh. 6 - Prob. 6.77QACh. 6 - Prob. 6.78QACh. 6 - Prob. 6.79QACh. 6 - Prob. 6.80QACh. 6 - Prob. 6.81QACh. 6 - Prob. 6.82QACh. 6 - Prob. 6.83QACh. 6 - Prob. 6.84QACh. 6 - Prob. 6.85QACh. 6 - Prob. 6.86QACh. 6 - Prob. 6.87QACh. 6 - Prob. 6.88QACh. 6 - Prob. 6.89QACh. 6 - Prob. 6.90QACh. 6 - Prob. 6.91QACh. 6 - Prob. 6.92QACh. 6 - Prob. 6.93QACh. 6 - Prob. 6.94QACh. 6 - Prob. 6.95QACh. 6 - Prob. 6.96QACh. 6 - Prob. 6.97QACh. 6 - Prob. 6.98QACh. 6 - Prob. 6.99QACh. 6 - Prob. 6.100QA
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