Chemistry
14th Edition
ISBN: 9781264243709
Author: Chang, Raymond
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Textbook Question
Chapter 6, Problem 6.139QP
Construct a table with the headings q, w, ΔU, and ΔH. For each of the following processes, deduce whether each of the quantities listed is positive (+), negative (−), or zero (0). (a) Freezing of benzene. (b) Compression of an ideal gas at constant temperature. (c) Reaction of sodium with water. (d) Boiling liquid ammonia. (e) Heating a gas at constant volume. (f) Melting of ice.
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
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No additional Hs to color in top
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No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 6 Solutions
Chemistry
Ch. 6.2 - Classify each of the following as an open system,...Ch. 6.2 - Determine if the following processes are...Ch. 6.3 - A gas expands from 264 mL to 971 mL at constant...Ch. 6.3 - A gas expands and does P-V work on the...Ch. 6.3 - Two ideal gases at the same temperature and...Ch. 6.3 - Calculate the work done when a gas at a pressure...Ch. 6.3 - Prob. 3RCFCh. 6.4 - Calculate the heat evolved when 266 g of white...Ch. 6.4 - What is U for the formation of 1 mole of CO at 1...Ch. 6.4 - Which of the constant-pressure processes shown...
Ch. 6.4 - Given the thermochemical equation...Ch. 6.4 - Calculate U for the following reaction at 1 atm...Ch. 6.5 - An iron bar of mass 869 g cools from 94C to 5C....Ch. 6.5 - A quantity of 1.922 g of methanol (CH3OH) was...Ch. 6.5 - A 30.14-g stainless steel ball bearing at 117.82C...Ch. 6.5 - A quantity of 4.00 102 mL of 0.600 M HNO3 is...Ch. 6.5 - A 1-g sample of Al and a 1-g sample of Fe are...Ch. 6.5 - A 1.252 g-sample of cyclohexanol (C6H12O) was...Ch. 6.5 - A 100.0-g sample of an unknown metal at 125C is...Ch. 6.6 - Calculate the standard enthalpy of formation of...Ch. 6.6 - Benzene (C6H6) burns in air to produce carbon...Ch. 6.6 - Which of the following does not have Hfo=0 at 25C?...Ch. 6.6 - Explain why reactions involving reactant compounds...Ch. 6.6 - Using data from Appendix 2, calculate Hrxno for...Ch. 6.6 - Given the following information...Ch. 6.7 - Use the data in Appendix 2 to calculate the heat...Ch. 6 - Define these terms: system, surroundings, open...Ch. 6 - What is heat? How does heat differ from thermal...Ch. 6 - What are the units for energy commonly employed in...Ch. 6 - A truck initially traveling at 60 km per hour is...Ch. 6 - These are various forms of energy: chemical, heat,...Ch. 6 - Define these terms: thermochemistry, exothermic...Ch. 6 - Stoichiometry is based on the law of conservation...Ch. 6 - Describe two exothermic processes and two...Ch. 6 - Decomposition reactions are usually endothermic,...Ch. 6 - On what law is the first law of thermodynamics...Ch. 6 - Explain what is meant by a state function. Give...Ch. 6 - The internal energy of an ideal gas depends only...Ch. 6 - Consider these changes: (a) Hg(l)Hg(g) (b)...Ch. 6 - A sample of nitrogen gas expands in volume from...Ch. 6 - A gas expands in volume from 26.7 mL to 89.3 mL at...Ch. 6 - A gas expands and does P-V work on the...Ch. 6 - The work done to compress a gas is 74 J. As a...Ch. 6 - Calculate the work done when 50.0 g of tin...Ch. 6 - Calculate the work done in joules when 1.0 mole of...Ch. 6 - Prob. 6.21QPCh. 6 - In writing thermochemical equations, why is it...Ch. 6 - Explain the meaning of this thermochemical...Ch. 6 - Consider this reaction:...Ch. 6 - The first step in the industrial recovery of zinc...Ch. 6 - Determine the amount of heat (in kJ) given off...Ch. 6 - Consider the reaction...Ch. 6 - Consider the reaction...Ch. 6 - What is the difference between specific heat and...Ch. 6 - Define calorimetry and describe two commonly used...Ch. 6 - Consider the following data: Metal Al Cu Mass (g)...Ch. 6 - A piece of silver of mass 362 g has a heat...Ch. 6 - A 6.22-kg piece of copper metal is heated from...Ch. 6 - Calculate the amount of heat liberated (in kJ)...Ch. 6 - A sheet of gold weighing 10.0 g and at a...Ch. 6 - To a sample of water at 23.4C in a...Ch. 6 - A 0.1375-g sample of solid magnesium is burned in...Ch. 6 - A quantity of 85.0 mL of 0.900 M HCl is mixed with...Ch. 6 - What is meant by the standard-state condition?Ch. 6 - How are the standard enthalpies of an element and...Ch. 6 - What is meant by the standard enthalpy of a...Ch. 6 - Write the equation for calculating the enthalpy of...Ch. 6 - State Hesss law. Explain, with one example, the...Ch. 6 - Describe how chemists use Hesss law to determine...Ch. 6 - Which of the following standard enthalpy of...Ch. 6 - The Hfo values of the two allotropes of oxygen, O2...Ch. 6 - Which is the more negative quantity at 25C: Hfo...Ch. 6 - Predict the value of Hfo (greater than, less than,...Ch. 6 - In general, compounds with negative Hfo values are...Ch. 6 - Suggest ways (with appropriate equations) that...Ch. 6 - Calculate the heat of decomposition for this...Ch. 6 - The standard enthalpies of formation of ions in...Ch. 6 - Calculate the heats of combustion for the...Ch. 6 - Calculate the heats of combustion for the...Ch. 6 - Methanol, ethanol, and n-propanol are three common...Ch. 6 - The standard enthalpy change for the following...Ch. 6 - From the standard enthalpies of formation,...Ch. 6 - Pentaborane-9, B5H9, is a colorless, highly...Ch. 6 - Determine the amount of heat (in kJ) given off...Ch. 6 - At 850C, CaCO3 undergoes substantial decomposition...Ch. 6 - From these data,...Ch. 6 - From the following data,...Ch. 6 - From the following heats of combustion,...Ch. 6 - Calculate the standard enthalpy change for the...Ch. 6 - Prob. 6.65QPCh. 6 - Why is the lattice energy of a solid always a...Ch. 6 - Consider two ionic compounds A and B. A has a...Ch. 6 - Mg2+ is a smaller cation than Na+ and also carries...Ch. 6 - Why is it dangerous to add water to a concentrated...Ch. 6 - Which of the following does not have Hfo=O at 25C?...Ch. 6 - Calculate the expansion work done when 3.70 moles...Ch. 6 - Prob. 6.73QPCh. 6 - Given the thermochemical equations:...Ch. 6 - The standard enthalpy change H for the thermal...Ch. 6 - Hydrazine, N2H4, decomposes according to the...Ch. 6 - A quantity of 2.00 102 mL of 0.862 M HCl is mixed...Ch. 6 - A 3.53-g sample of ammonium nitrate (NH4NO3) was...Ch. 6 - Consider the reaction...Ch. 6 - Prob. 6.80QPCh. 6 - Prob. 6.81QPCh. 6 - A 2.10-mole sample of crystalline acetic acid,...Ch. 6 - Prob. 6.83QPCh. 6 - You are given the following data:...Ch. 6 - A gaseous mixture consists of 28.4 mole percent of...Ch. 6 - When 2.740 g of Ba reacts with O2 at 298 K and 1...Ch. 6 - Methanol (CH3OH) is an organic solvent and is also...Ch. 6 - A 44.0-g sample of an unknown metal at 99.0C was...Ch. 6 - Using the data in Appendix 2, calculate the...Ch. 6 - Producer gas (carbon monoxide) is prepared by...Ch. 6 - Prob. 6.91QPCh. 6 - Prob. 6.92QPCh. 6 - Ethanol (C2H5OH) and gasoline (assumed to be all...Ch. 6 - The combustion of what volume of ethane (C2H6),...Ch. 6 - Prob. 6.95QPCh. 6 - Prob. 6.96QPCh. 6 - Explain the cooling effect experienced when...Ch. 6 - For which of the following reactions does...Ch. 6 - Prob. 6.99QPCh. 6 - A quantity of 0.020 mole of a gas initially at...Ch. 6 - Prob. 6.101QPCh. 6 - Prob. 6.102QPCh. 6 - Prob. 6.103QPCh. 6 - Prob. 6.104QPCh. 6 - A person ate 0.50 pound of cheese (an energy...Ch. 6 - Prob. 6.106QPCh. 6 - Prob. 6.107QPCh. 6 - The enthalpy of combustion of benzoic acid...Ch. 6 - Prob. 6.109QPCh. 6 - Prob. 6.110QPCh. 6 - Glaubers salt, sodium sulfate decahydrate (Na2SO4 ...Ch. 6 - A balloon 16 m in diameter is inflated with helium...Ch. 6 - Acetylene (C2H2) can be hydrogenated (reacting...Ch. 6 - Prob. 6.114QPCh. 6 - An excess of zinc metal is added to 50.0 mL of a...Ch. 6 - (a) A person drinks four glasses of cold water...Ch. 6 - Prob. 6.118QPCh. 6 - Why are cold, damp air and hot, humid air more...Ch. 6 - Prob. 6.120QPCh. 6 - Prob. 6.121QPCh. 6 - Prob. 6.122QPCh. 6 - Prob. 6.123QPCh. 6 - Determine the standard enthalpy of formation of...Ch. 6 - Prob. 6.125QPCh. 6 - Ice at 0C is placed in a Styrofoam cup containing...Ch. 6 - Prob. 6.127QPCh. 6 - Prob. 6.128QPCh. 6 - Calculate the internal energy of a Goodyear blimp...Ch. 6 - Prob. 6.131QPCh. 6 - Acetylene (C2H2) can be made by reacting calcium...Ch. 6 - The average temperature in deserts is high during...Ch. 6 - From a thermochemical point of view, explain why a...Ch. 6 - Calculate the U for the following reaction at 298...Ch. 6 - Lime is a term that includes calcium oxide (CaO,...Ch. 6 - A 4.117-g impure sample of glucose (C6H12O6) was...Ch. 6 - Construct a table with the headings q, w, U, and...Ch. 6 - The combustion of 0.4196 g of a hydrocarbon...Ch. 6 - Metabolic activity in the human body releases...Ch. 6 - Give an example for each of the following...Ch. 6 - From the following data, calculate the heat of...Ch. 6 - Starting at A, an ideal gas undergoes a cyclic...Ch. 6 - For reactions in condensed phases (liquids and...Ch. 6 - The diagrams (a)(d) represent various physical and...Ch. 6 - A 20.3-g sample of an unknown metal and a 28.5-g...Ch. 6 - Prob. 6.148QPCh. 6 - Prob. 6.149QPCh. 6 - The fastest serve in tennis is about 150 mph. Can...Ch. 6 - Prob. 6.151QPCh. 6 - It has been estimated that 3 trillion standard...Ch. 6 - Prob. 6.153QPCh. 6 - Prob. 6.154QPCh. 6 - Prob. 6.155QPCh. 6 - We hear a lot about how the burning of...
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