Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134112831
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 6, Problem 5E
Interpretation Introduction
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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
Will the first
MgBr
product that forms in this reaction
create a new CC bond?
olo
?
OH
جمله
O Yes
Ⓒ No
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Click and drag to start drawing a
structure.
Yes
No
X
☐ :
☐
टे
PH
Assign all the protons
PROPOSE REACTION MECHANISM FOR ACID-CATALYZED REACTION OF 3-PENTANONE WITH DIMETHYLAMINE
Chapter 6 Solutions
Chemistry: A Molecular Approach (4th Edition)
Ch. 6 - A chemical system produces 155 kJ of heat and does...Ch. 6 - Q2. Which sample is most likely to undergo the...Ch. 6 - Prob. 3SAQCh. 6 - Q4. A 12.5-g sample of granite initially at 82.0...Ch. 6 - Q5. A cylinder with a moving piston expands from...Ch. 6 - Prob. 6SAQCh. 6 - Q7. Hydrogen gas reacts with oxygen to form...Ch. 6 - Prob. 8SAQCh. 6 - Prob. 9SAQCh. 6 - Prob. 10SAQ
Ch. 6 - Prob. 11SAQCh. 6 - Prob. 12SAQCh. 6 - Prob. 13SAQCh. 6 - Prob. 14SAQCh. 6 - Q15. Natural gas burns in air to form carbon...Ch. 6 - 1. What is thermochemistry? Why is it important?
Ch. 6 - 2. What is energy? What is work? List some...Ch. 6 - Prob. 3ECh. 6 - 4. State the law of conservation of energy. How...Ch. 6 - Prob. 5ECh. 6 - 6. State the first law of thermodynamics. What are...Ch. 6 - Prob. 7ECh. 6 - 8. What is a state function? List some examples of...Ch. 6 - 9. What is internal energy? Is internal energy a...Ch. 6 - 10. If energy flows out of a chemical system and...Ch. 6 - 11. If the internal energy of the products of a...Ch. 6 - 12. What is heat? Explain the difference between...Ch. 6 - 13. How is the change in internal energy of a...Ch. 6 - 14. Explain how the sum of heat and work can be a...Ch. 6 - 15. What is heat capacity? Explain the difference...Ch. 6 - 16. Explain how the high specific heat capacity of...Ch. 6 - 17. If two objects, A and B, of different...Ch. 6 - 18. What is pressure–volume work? How is it...Ch. 6 - 19. What is calorimetry? Explain the difference...Ch. 6 - 20. What is the change in enthalpy (ΔH) for a...Ch. 6 - 21. Explain the difference between an exothermic...Ch. 6 - 22. From a molecular viewpoint, where does the...Ch. 6 - 23. From a molecular viewpoint, where does the...Ch. 6 - 24. Is the change in enthalpy for a reaction an...Ch. 6 - Prob. 25ECh. 6 - Prob. 26ECh. 6 - 27. What is a standard state? What is the standard...Ch. 6 - Prob. 28ECh. 6 - 29. How do you calculate from tabulated standard...Ch. 6 - Prob. 30ECh. 6 - 31. What are the main environmental problems...Ch. 6 - Prob. 32ECh. 6 - Prob. 33ECh. 6 - Prob. 34ECh. 6 - Prob. 35ECh. 6 - 36. A particular frost-free refrigerator uses...Ch. 6 - 37. Which statement is true of the internal energy...Ch. 6 - Prob. 38ECh. 6 - 39. Identify each energy exchange as primarily...Ch. 6 - 40. Identify each energy exchange as primarily...Ch. 6 - 41. A system releases 622 kJ of heat and does 105...Ch. 6 - 42. A system absorbs 196 kJ of heat and the...Ch. 6 - 43. The gas in a piston (defined as the system)...Ch. 6 - Prob. 44ECh. 6 - Prob. 45ECh. 6 - Prob. 46ECh. 6 - 47. How much heat is required to warm 1.50 L of...Ch. 6 - 48. How much heat is required to warm 1.50 kg of...Ch. 6 - 49. Suppose that 25 g of each substance is...Ch. 6 - 50. An unknown mass of each substance, initially...Ch. 6 - 51. How much work (in J) is required to expand the...Ch. 6 - Prob. 52ECh. 6 - 53. The air within a piston equipped with a...Ch. 6 - 54. A gas is compressed from an initial volume of...Ch. 6 - 55. When 1 mol of a fuel burns at constant...Ch. 6 - 56. The change in internal energy for the...Ch. 6 - 57. Determine whether each process is exothermic...Ch. 6 - 58. Determine whether each process is exothermic...Ch. 6 - 59. Consider the thermochemical equation for the...Ch. 6 - 60. What mass of natural gas (CH4) must burn to...Ch. 6 - Prob. 61ECh. 6 - Prob. 62ECh. 6 - Prob. 63ECh. 6 - Prob. 64ECh. 6 - 65. A silver block, initially at 58.5 °C, is...Ch. 6 - Prob. 66ECh. 6 - 67. A 31.1-g wafer of pure gold, initially at 69.3...Ch. 6 - Prob. 68ECh. 6 - Prob. 69ECh. 6 - 70. A 2.74-g sample of a substance suspected of...Ch. 6 - 71. Exactly 1.5 g of a fuel burns under conditions...Ch. 6 - 72. In order to obtain the largest possible amount...Ch. 6 - 73. When 0.514 g of biphenyl (C12H10) undergoes...Ch. 6 - Prob. 74ECh. 6 - 75. Zinc metal reacts with hydrochloric acid...Ch. 6 - Prob. 76ECh. 6 - 77. For each generic reaction, determine the value...Ch. 6 - Prob. 78ECh. 6 - 79. Calculate ΔHrxn for the reaction:
Fe2O3(s) + 3...Ch. 6 - 80. Calculate ΔHrxn for the reaction:
CaO(s) +...Ch. 6 - 81. Calculate ΔHrxn for the reaction:
5 C(s) + 6...Ch. 6 - 82. Calculate ΔHrxn for the reaction:
CH4(g) + 4...Ch. 6 - 83. Write an equation for the formation of each...Ch. 6 - Prob. 84ECh. 6 - 85. Hydrazine (N2H4) is a fuel used by some...Ch. 6 - Prob. 86ECh. 6 - Prob. 87ECh. 6 - Prob. 88ECh. 6 - 89. During photosynthesis, plants use energy from...Ch. 6 - Prob. 90ECh. 6 - 91. Top fuel dragsters and funny cars burn...Ch. 6 - 92. The explosive nitroglycerin (C3H5N3O9)...Ch. 6 - 93. Determine the mass of CO2 produced by burning...Ch. 6 - Prob. 94ECh. 6 - Prob. 95ECh. 6 - Prob. 96ECh. 6 - Prob. 97ECh. 6 - Prob. 98ECh. 6 - 99. Evaporating sweat cools the body because...Ch. 6 - Prob. 100ECh. 6 - 101. Use standard enthalpies of formation to...Ch. 6 - 102. Dry ice is solid carbon dioxide. Instead of...Ch. 6 - 103. A 25.5-g aluminum block is warmed to 65.4 °C...Ch. 6 - Prob. 104ECh. 6 - Prob. 105ECh. 6 - Prob. 106ECh. 6 - 107. Derive a relationship between ΔH and ΔE for a...Ch. 6 - Prob. 108ECh. 6 - Prob. 109ECh. 6 - Prob. 110ECh. 6 - Prob. 111ECh. 6 - 112. When 10.00 g of phosphorus is burned in O2(g)...Ch. 6 - Prob. 113ECh. 6 - 114. The of TiI3(s) is –328 kJ/mol and the ΔH°...Ch. 6 - Prob. 115ECh. 6 - Prob. 116ECh. 6 - Prob. 117ECh. 6 - 118. A pure gold ring and a pure silver ring have...Ch. 6 - Prob. 119ECh. 6 - Prob. 120ECh. 6 - Prob. 121ECh. 6 - Prob. 122ECh. 6 - Prob. 123ECh. 6 - Prob. 124ECh. 6 - Prob. 125ECh. 6 - Prob. 126ECh. 6 - Prob. 127ECh. 6 - Prob. 128ECh. 6 - Prob. 129ECh. 6 - Prob. 130ECh. 6 - 131. Which statement is true of the internal...Ch. 6 - Prob. 132ECh. 6 - 133. Which expression describes the heat evolved...Ch. 6 - Prob. 134ECh. 6 - 135. A 1-kg cylinder of aluminum and 1-kg jug of...Ch. 6 - Prob. 136ECh. 6 - 137. When 1 mol of a gas burns at constant...Ch. 6 - Prob. 138ECh. 6 - Prob. 139ECh. 6 - Have each group member write a problem involving...Ch. 6 - Prob. 141QGWCh. 6 - Prob. 142QGWCh. 6 - Prob. 143QGWCh. 6 - Prob. 144DIA
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- Assign all the protonsarrow_forwardAssign all the carbonsarrow_forward9 7 8 C 9 8 200 190 B 5 A -197.72 9 8 7 15 4 3 0: ང་ 200 190 180 147.52 134.98 170 160 150 140 130 120 110 100 90 90 OH 10 4 3 1 2 -143.04 140. 180 170 160 150 140 130 120 110 100 90 CI 3 5 1 2 141.89 140.07 200 190 180 170 160 150 140 130 120 110 100 ៖- 90 129. 126.25 80 70 60 -60 50 40 10 125.19 -129.21 80 70 3.0 20 20 -8 60 50 10 ppm -20 40 128.31 80 80 70 60 50 40 40 -70.27 3.0 20 10 ppm 00˚0-- 77.17 30 20 20 -45.36 10 ppm -0.00 26.48 22.32 ―30.10 ―-0.00arrow_forward
- Assign all the carbonsarrow_forwardC 5 4 3 CI 2 the Righ B A 5 4 3 The Lich. OH 10 4 5 3 1 LOOP- -147.52 T 77.17 -45.36 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm B -126.25 77.03 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm 200 190 180 170 160 150 140 130 120 110 100 90 80 TO LL <-50.00 70 60 50 40 30 20 10 ppm 45.06 30.18 -26.45 22.36 --0.00 45.07 7.5 1.93 2.05 -30.24 -22.36 C A 7 8 5 ° 4 3 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 8 5 4 3 ཡི་ OH 10 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 5 4 3 2 that th 7 I 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 115 2.21 4.00 1.0 ppm 6.96 2.76 5.01 1.0 ppm 6.30 1.00arrow_forwardCurved arrows were used to generate the significant resonance structure and labeled the most significant contribute. What are the errors in these resonance mechanisms. Draw out the correct resonance mechanisms with an brief explanation.arrow_forward
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- Assign ALL signals for the proton and carbon NMR spectra on the following pages.arrow_forward7.5 1.93 2.05 C B A 4 3 5 The Joh. 9 7 8 1 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 7 8 0.86 OH 10 4 3 5 1 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 7 8 CI 4 3 5 1 2 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 2.21 4.00 1.5 2.00 2.07 1.0 ppm 2.76arrow_forwardAssign the functional group bands on the IR spectra.arrow_forward
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