INTOR TO CHEMISTRY LLF
5th Edition
ISBN: 9781264501731
Author: BAUER
Publisher: MCG
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Chapter 6, Problem 53QP
Interpretation Introduction
Interpretation:
The possibility of
Concept Introduction:
The quantity of the product obtained according to the balanced equation of the reaction is called theoretical yield. The quantity of the product obtained when the reaction is conducted in the laboratory is called the actual yield.
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Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Part I.
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff:
Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
and
(3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism
the formation of the products
For
Chapter 6 Solutions
INTOR TO CHEMISTRY LLF
Ch. 6 - Prob. 1QCCh. 6 - Prob. 2QCCh. 6 - Prob. 3QCCh. 6 - Prob. 4QCCh. 6 - Prob. 5QCCh. 6 - Prob. 6QCCh. 6 - Prob. 7QCCh. 6 - Prob. 1PPCh. 6 - Prob. 2PPCh. 6 - Prob. 3PP
Ch. 6 - Prob. 4PPCh. 6 - Consider the combination reaction of nitrogen gas...Ch. 6 - Prob. 6PPCh. 6 - Prob. 7PPCh. 6 - Prob. 8PPCh. 6 - Prob. 9PPCh. 6 - Prob. 10PPCh. 6 - Prob. 11PPCh. 6 - Prob. 12PPCh. 6 - Prob. 13PPCh. 6 - Prob. 14PPCh. 6 - Prob. 1QPCh. 6 - Prob. 2QPCh. 6 - Prob. 3QPCh. 6 - Prob. 4QPCh. 6 - Prob. 5QPCh. 6 - Prob. 6QPCh. 6 - Prob. 7QPCh. 6 - Prob. 8QPCh. 6 - Prob. 9QPCh. 6 - Prob. 10QPCh. 6 - Prob. 11QPCh. 6 - Prob. 12QPCh. 6 - Prob. 13QPCh. 6 - Prob. 14QPCh. 6 - Prob. 15QPCh. 6 - Prob. 16QPCh. 6 - Prob. 17QPCh. 6 - Prob. 18QPCh. 6 - Prob. 19QPCh. 6 - Prob. 20QPCh. 6 - Prob. 21QPCh. 6 - Prob. 22QPCh. 6 - Prob. 23QPCh. 6 - Prob. 24QPCh. 6 - Prob. 25QPCh. 6 - Prob. 26QPCh. 6 - Prob. 27QPCh. 6 - Prob. 28QPCh. 6 - Prob. 29QPCh. 6 - Prob. 30QPCh. 6 - Prob. 31QPCh. 6 - Prob. 32QPCh. 6 - Prob. 33QPCh. 6 - The balanced equation for the reaction of chromium...Ch. 6 - Prob. 35QPCh. 6 - Prob. 36QPCh. 6 - Prob. 37QPCh. 6 - Prob. 38QPCh. 6 - Prob. 39QPCh. 6 - Prob. 40QPCh. 6 - Prob. 41QPCh. 6 - Prob. 42QPCh. 6 - Prob. 43QPCh. 6 - Prob. 44QPCh. 6 - Prob. 45QPCh. 6 - Prob. 46QPCh. 6 - Prob. 47QPCh. 6 - Prob. 48QPCh. 6 - Prob. 49QPCh. 6 - Prob. 50QPCh. 6 - Prob. 51QPCh. 6 - Prob. 52QPCh. 6 - Prob. 53QPCh. 6 - Prob. 54QPCh. 6 - Prob. 55QPCh. 6 - A student added zinc metal to copper(II) nitrate...Ch. 6 - Prob. 57QPCh. 6 - Prob. 58QPCh. 6 - When I2 is mixed with excess H2, 0.80 mol HI is...Ch. 6 - The reaction of lithium metal and water to form...Ch. 6 - Prob. 61QPCh. 6 - Prob. 62QPCh. 6 - If energy cannot be created or destroyed, what...Ch. 6 - Prob. 64QPCh. 6 - Prob. 65QPCh. 6 - Prob. 66QPCh. 6 - Prob. 67QPCh. 6 - Prob. 68QPCh. 6 - Prob. 69QPCh. 6 - Prob. 70QPCh. 6 - Prob. 71QPCh. 6 - Prob. 72QPCh. 6 - Prob. 73QPCh. 6 - Prob. 74QPCh. 6 - Prob. 75QPCh. 6 - Prob. 76QPCh. 6 - Prob. 77QPCh. 6 - Prob. 78QPCh. 6 - Prob. 79QPCh. 6 - Prob. 80QPCh. 6 - Prob. 81QPCh. 6 - Prob. 82QPCh. 6 - Prob. 83QPCh. 6 - Prob. 84QPCh. 6 - Prob. 85QPCh. 6 - Prob. 86QPCh. 6 - Prob. 87QPCh. 6 - Prob. 88QPCh. 6 - Prob. 89QPCh. 6 - Prob. 90QPCh. 6 - Prob. 91QPCh. 6 - Prob. 92QPCh. 6 - Prob. 93QPCh. 6 - Prob. 94QPCh. 6 - Prob. 95QPCh. 6 - Prob. 96QPCh. 6 - Prob. 97QPCh. 6 - Prob. 98QPCh. 6 - Prob. 99QPCh. 6 - Prob. 100QPCh. 6 - Prob. 101QPCh. 6 - Prob. 102QPCh. 6 - Prob. 103QPCh. 6 - Prob. 104QPCh. 6 - Prob. 105QPCh. 6 - Prob. 106QPCh. 6 - Prob. 107QPCh. 6 - Prob. 108QPCh. 6 - Prob. 109QPCh. 6 - Prob. 110QPCh. 6 - The balanced equation for the combustion of octane...Ch. 6 - Prob. 112QPCh. 6 - Prob. 113QPCh. 6 - Prob. 114QPCh. 6 - Prob. 115QPCh. 6 - Prob. 116QPCh. 6 - Prob. 117QPCh. 6 - Prob. 118QPCh. 6 - Prob. 119QPCh. 6 - Prob. 120QPCh. 6 - Prob. 121QPCh. 6 - Prob. 122QPCh. 6 - Prob. 123QPCh. 6 - Prob. 124QPCh. 6 - Prob. 125QPCh. 6 - A 150.0-g sample of copper is heated to 89.3C. The...Ch. 6 - How many moles of aqueous magnesium ions and...Ch. 6 - Prob. 128QPCh. 6 - How many moles of aqueous potassium ions and...Ch. 6 - Prob. 130QPCh. 6 - Prob. 131QPCh. 6 - Prob. 132QPCh. 6 - Prob. 133QPCh. 6 - Prob. 134QPCh. 6 - Prob. 135QPCh. 6 - Prob. 136QPCh. 6 - Prob. 137QPCh. 6 - Prob. 138QPCh. 6 - Prob. 139QPCh. 6 - Prob. 140QPCh. 6 - Prob. 141QPCh. 6 - When calculating percent yield for a reaction, the...Ch. 6 - Prob. 143QPCh. 6 - Prob. 144QPCh. 6 - Prob. 145QPCh. 6 - Prob. 146QP
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- 19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forwardQ4: Write organic product(s) of the following reactions and show the curved-arrow mechanism of the reactions. Br MeOH OSO2CH3 MeOHarrow_forward
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