EBK CHEMISTRY
1st Edition
ISBN: 9780133888584
Author: Tro
Publisher: VST
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Question
Chapter 6, Problem 44E
Interpretation Introduction
To find:
The formal charge on the highlighted atoms
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Q1:
a) Arrange the compounds in order of decreasing pKa, highest first.
ОН
ΟΗ
ῸΗ
дон
ОН
ОН
CI
Br
(4 pts - 2 pts each part) A route that can be taken to prepare a
hydrophobic (water-repellent) aerogel is to start with
trichloromethylsilane, CH3SiCl3 as the silicon source.
a. What is the chemical reaction that this undergoes to form a
product with Si-OH groups? Write as complete of a chemical
equation as you can.
CI
CI-SI-CH3
CI
b. The formation of a byproduct is what drives this reaction - what is the byproduct (if you
didn't already answer it in part (a)) and how/why does it form?
b) Circle the substrate that would not efficiently generate a Grignard reagent upon reaction
with Mg in ether.
CI
Br
ד
c) Circle the Grignard reagents that contain incompatible functional groups.
MgBr
HO
MgBr
MgBr
MgBr
MgBr
HO
MgBr
Chapter 6 Solutions
EBK CHEMISTRY
Ch. 6 - Which set of elements is arranged in order of...Ch. 6 - Prob. 2SAQCh. 6 - Which pair of atoms forms the most polar bond? C...Ch. 6 - Which pair of atoms forms a nonpolar covalent...Ch. 6 - Prob. 5SAQCh. 6 - Prob. 6SAQCh. 6 - Prob. 7SAQCh. 6 - Prob. 8SAQCh. 6 - Prob. 9SAQCh. 6 - Prob. 10SAQ
Ch. 6 - Prob. 11SAQCh. 6 - Predict the relative bond angles in BF3 and SO2Ch. 6 - Predict the molecular geometry about N in the...Ch. 6 - Which molecule is polar?Ch. 6 - What is electronegativity? What are the periodic...Ch. 6 - Explain the difference between a pure covalent...Ch. 6 - What is meant by the percent ionic character of a...Ch. 6 - Prob. 4ECh. 6 - What is the magnitude of the dipole moment formed...Ch. 6 - What is the basic procedure for writing a covalent...Ch. 6 - How do you determine the number of electrons that...Ch. 6 - What are resonance structures? What is a resonance...Ch. 6 - Prob. 9ECh. 6 - Prob. 10ECh. 6 - Prob. 11ECh. 6 - Prob. 12ECh. 6 - What is bond energy?Ch. 6 - Give some examples of some typical bond lengths....Ch. 6 - Why is molecular geometry important? Cite some...Ch. 6 - According to VSEPR theory, what determines the...Ch. 6 - Name and draw the five basic electron geometries,...Ch. 6 - Explain the difference between electron geometry...Ch. 6 - List the correct electron and molecular geometries...Ch. 6 - How do you apply VSEPR theory to predict the shape...Ch. 6 - How do you determine if a molecule is polar?Ch. 6 - Why is polarity a key connection between the...Ch. 6 - Prob. 23ECh. 6 - Determine if a bond between each pair of atoms...Ch. 6 - Prob. 25ECh. 6 - Draw the Lewis structure for BrF with an arrow...Ch. 6 - Prob. 27ECh. 6 - Write the Lewis structure for each molecule. NF3...Ch. 6 - Prob. 29ECh. 6 - Write the Lewis structure for each molecule. CH2O...Ch. 6 - Prob. 31ECh. 6 - Prob. 32ECh. 6 - Write the Lewis structure for each molecule or ion...Ch. 6 - Prob. 34ECh. 6 - Write a Lewis structure that obeys the octet rule...Ch. 6 - Prob. 36ECh. 6 - Use formal charge to determine which Lewis...Ch. 6 - Prob. 38ECh. 6 - How important is this resonance structure to the...Ch. 6 - Prob. 40ECh. 6 - Prob. 41ECh. 6 - Prob. 42ECh. 6 - Determine the formal charges of the atoms shown in...Ch. 6 - Prob. 44ECh. 6 - Prob. 45ECh. 6 - Write the Lewis structure for each molecule (octet...Ch. 6 - Prob. 47ECh. 6 - Write Lewis structures for each molecule or ion....Ch. 6 - Prob. 49ECh. 6 - Write Lewis structures for each molecule or ion....Ch. 6 - List these compounds in order of increasing...Ch. 6 - Which of these compounds has the stronger...Ch. 6 - A molecule with the formula AB3 has a trigonal...Ch. 6 - A molecule with the formula AB3 has a trigonal...Ch. 6 - For each molecular geometry shown here, list the...Ch. 6 - For each molecular geometry shown here, list the...Ch. 6 - Determine the electron geometry, molecular...Ch. 6 - Determine the electron geometry, molecular...Ch. 6 - Which species has the smaller bond angle, H3O+ or...Ch. 6 - Which species has the smaller bond angle; C1O4- or...Ch. 6 - Determine the molecular geometry and draw each...Ch. 6 - Determine the molecular geometry and draw each...Ch. 6 - Determine the molecular geometry about each...Ch. 6 - Prob. 64ECh. 6 - Prob. 65ECh. 6 - Prob. 66ECh. 6 - Prob. 67ECh. 6 - Determine the geometry about each interior atom in...Ch. 6 - Explain why CO2 and CCl4 are both nonpolar even...Ch. 6 - CH3F is a polar molecule, even though the...Ch. 6 - Determine whether each molecule in Exercise 57 is...Ch. 6 - Prob. 72ECh. 6 - Determine whether each molecule or ion is polar or...Ch. 6 - Determine whether each molecule is polar or...Ch. 6 - Each compound contains both ionic and covalent...Ch. 6 - Prob. 76ECh. 6 - Carbon ring structures are common in organic...Ch. 6 - Prob. 78ECh. 6 - Prob. 79ECh. 6 - Diazomethane is a highly poisonous, explosive...Ch. 6 - Prob. 81ECh. 6 - Phosgene (Cl2CO) is a poisonous gas that was used...Ch. 6 - The cyanate ion (OCN-) and the fulminate ion...Ch. 6 - Prob. 84ECh. 6 - Prob. 85ECh. 6 - Prob. 86ECh. 6 - Prob. 87ECh. 6 - Prob. 88ECh. 6 - Prob. 89ECh. 6 - Free radicals are important in many...Ch. 6 - A compound composed of only carbon and hydrogen is...Ch. 6 - A compound composed of only carbon and chlorine is...Ch. 6 - Prob. 93ECh. 6 - The genetic code is based on four different bases...Ch. 6 - Prob. 95ECh. 6 - Prob. 96ECh. 6 - Prob. 97ECh. 6 - A 0.167-g sample of an unknown compound contains...Ch. 6 - Use the dipole moments of HF and HCI (given at the...Ch. 6 - One form of phosphorus exists as P4 molecules....Ch. 6 - A compound has the formula C8H8 and does not...Ch. 6 - Prob. 102ECh. 6 - The bond angles increase steadily in the series...Ch. 6 - Draw the Lewis structure for acetamide (CH3CONH2),...Ch. 6 - Prob. 105ECh. 6 - In the very first chapter of this book, we...Ch. 6 - Which statement best captures the fundamental idea...Ch. 6 - Prob. 108E
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