Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion
Organic Chemistry, 3e WileyPLUS Registration Card + Loose-leaf Print Companion
3rd Edition
ISBN: 9781119340577
Author: Klein
Publisher: Wiley (WileyPLUS Products)
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Chapter 6, Problem 43IP
Interpretation Introduction

Interpretation:

For the given reaction effect of Keq , ΔG (Gibbs free energy), temperature, ΔΗ (Enthalpy), Ea and ΔS (Entropy) should be identified.

Concept introduction:

Equilibrium constants ( Keq ) [Products] [Reactants]

Equilibrium constants ( Keq ) is only affected by temperature, because if number of moles of the reagent increases product will also increases and the ratio constant.

ΔΗ (Enthalpy) could be determined by using following formula

ΔΗ (Enthalpy of the reaction) = ΔΗ (bonds broken) – ΔΗ (bonds formed)

ΔS (Entropy) can be identified by using formula.

ΔS = Number of products – Number of reactant

General formula to calculate the Gibbs free energy is ΔG = ΔΗ –TΔS

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Shown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown.  Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.)  (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)
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Draw a reasonable mechanism for the following reaction:

Chapter 6 Solutions

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