Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134554525
Author: Tro
Publisher: PEARSON
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Textbook Question
Chapter 6, Problem 29E
How many moles of atoms are in each elemental sample?
a.
b.
c.
d.
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 6 Solutions
Introductory Chemistry (6th Edition)
Ch. 6 - Q1. How many atoms are there in 5.8 mol helium?
a....Ch. 6 - A sample of pure silver has a mass of 155g How...Ch. 6 - How many carbon atoms are there in a 12.5kg sample...Ch. 6 - Q4. Which sample contains the greatest number of...Ch. 6 - Q5. What is the average mass (in grams) of a...Ch. 6 - Q6. How many moles of O are in 1.6 mol of?
1.6 mol...Ch. 6 - Q7. How many grams of Cl are in?
Ch. 6 - Q8. Which sample contains the greatest number of F...Ch. 6 - Q9. The compound is 35.8% A by mass. What mass of...Ch. 6 - Q10. Which compound has the highest mass percent...
Ch. 6 - What is the mass percent N in C2H8N2 ? a. 23.3% N...Ch. 6 - Q12. A compound is 52.14% C, 13.13% H, and 34.73%...Ch. 6 - A compound has the empirical formula CH2O and a...Ch. 6 - Prob. 14SAQCh. 6 - Why is chemical composition important?Ch. 6 - 2. How can you efficiently determine the number of...Ch. 6 - How many atoms are in 1 mol of atoms?Ch. 6 - 4. How many molecules are in 1 mol of molecules?
Ch. 6 - 5. What is the mass of 1 mol of atoms for an...Ch. 6 - What is the mass of 1 mol of molecules for a...Ch. 6 - What is the mass of 1 mol atoms of each element?...Ch. 6 - 8. What is the mass of 1 mol of molecules of each...Ch. 6 - 9. The subscripts in a chemical formula give...Ch. 6 - 10 Write the conversion factors between moles of...Ch. 6 - Prob. 11ECh. 6 - 12. What is the mathematical formula for...Ch. 6 - How are the empirical formula and the molecular...Ch. 6 - 14. Why is it important to be able to calculate an...Ch. 6 - 15. What is the empirical formula mass of a...Ch. 6 - 16. How are the molar mass and empirical formula...Ch. 6 - How many mercury atoms are in 5.8mol of mercury?Ch. 6 - 18. How many moles of gold atoms do gold atoms...Ch. 6 - How many atoms are in each elemental sample? a....Ch. 6 - 20. How many moles of atoms are in each elemental...Ch. 6 - Complete the table. Element Moles Number of Atoms...Ch. 6 - 22. Complete the table.
Element Moles Number of...Ch. 6 - Consider these definitions. 1 doz =12 1gross =144...Ch. 6 - 24. A pure copper penny contains approximately ...Ch. 6 - 25. How many moles of tin atoms are in a pure tin...Ch. 6 - 26. A lead fishing weight contains 0.12 mol of...Ch. 6 - 27. A pure gold coin contains 0.145 mol of gold....Ch. 6 - 28. A helium balloon contains 0.46 g of helium....Ch. 6 - How many moles of atoms are in each elemental...Ch. 6 - 30. What is the mass in grams of each elemental...Ch. 6 - Complete the table. Element Mole Mass Ne ____...Ch. 6 - Complete the table. Element Moles Mass Cr 0.00442...Ch. 6 - 33. Apure silver ring contains mmol (millmol) Ag....Ch. 6 - A pure gold ring contains 0.0102 mmol (millmol)...Ch. 6 - How many aluminum atoms are in 3.78 g of aluminum?Ch. 6 - 36. What is the mass of platinum atoms?
Ch. 6 - How many atoms are in each elemental sample? a....Ch. 6 - Calculate the mass in grams of each elemental...Ch. 6 - 39. How many carbon atoms are in a diamond (pure...Ch. 6 - How many helium atoms are in a helium blimp...Ch. 6 - 41. How many titanium atoms are in a pure titanium...Ch. 6 - 42. How many copper atoms are in a pure copper...Ch. 6 - 43. Complete the table.
Element Mass Moles Number...Ch. 6 - 44. Complete the table.
Element Mass Moles Number...Ch. 6 - Which sample contains the greatest number of...Ch. 6 - Which sample contains the greatest number of...Ch. 6 - 47. Determine the number of molecules (or formula...Ch. 6 - 48. Determine the mass of each sample.
a. mol...Ch. 6 - 49. Complete the table.
Compound Mass Moles Number...Ch. 6 - 50. Complete the table.
Compound Mass Moles Number...Ch. 6 - A mothball, composed of naphthalene (C10H8), has a...Ch. 6 - Calculate the mass in grams of a single water...Ch. 6 -
53. How many molecules are in each sample?
a.
b....Ch. 6 -
54. Calculate the mass in grams of each...Ch. 6 - 55. A sugar crystal contains approximately sucrose...Ch. 6 - A salt crystal has a mass of 0.12 mg. How many...Ch. 6 - How much money, in dollars, dose 1 mol of pennies...Ch. 6 - A typical dust particle has a diameter of about...Ch. 6 - 59. Determine the number of moles of in mol .
Ch. 6 - 60. How many moles of O are in mol ?
Ch. 6 - 61. Which sample contains the greatest number of...Ch. 6 - Prob. 62ECh. 6 - Determine the number of moles of C in each sample....Ch. 6 - Determine the number of moles of H in each sample....Ch. 6 - 65. For each set of molecular models, write a...Ch. 6 - 66. For each set of molecular models, write a...Ch. 6 - 67. How many grams of are in 38.0 g of each...Ch. 6 - 68. Calculate the number of grams of sodium in...Ch. 6 - Iron is found in Earths crust as several different...Ch. 6 - 70. Lead is found in Earth’s crust as several lead...Ch. 6 - A 2.45-g sample of strontium completely reacts...Ch. 6 - A 4.78-g sample of aluminum completely reacts with...Ch. 6 - A 1.912g sample of calcium chloride is decomposed...Ch. 6 - Prob. 74ECh. 6 - 75. Copper(II) fluoride contains 37.42% F by mass....Ch. 6 - Silver chloride, used in silver plating, contains...Ch. 6 - In small amounts, the fluoride ion (often consumed...Ch. 6 - The iodide ion, usually consumed as potassium...Ch. 6 - 79. Calculate the mass percent composition of...Ch. 6 - Calculate the mass percent composition of carbon...Ch. 6 - 81. Calculate the mass percent composition of each...Ch. 6 - 82. Calculate the mass percent composition of each...Ch. 6 - 83. Calculate the mass percent composition of O in...Ch. 6 - Calculate the mass percent composition of Cl in...Ch. 6 - Various iron ores have different amounts of iron...Ch. 6 - 86. Plats need nitrogen to grow, so many...Ch. 6 - 87. A compound containing nitrogen and oxygen is...Ch. 6 - 88. A compound containing selenium and fluorine is...Ch. 6 - 89. Samples of several compounds are decomposed,...Ch. 6 - Samples of several compounds are decomposed, and...Ch. 6 - 91. The rotten smell of a decaying animal carcass...Ch. 6 - 92. Citric acid, the compound responsible for the...Ch. 6 - 93. These compounds are found in many natural...Ch. 6 - Calculate the empirical formula for each...Ch. 6 - 95. A sample of phosphorus burns in air and forms...Ch. 6 - A 2.241-g sample of nickel reacts with oxygen to...Ch. 6 - A sample of nitrogen reacts with chlorine to form...Ch. 6 - 98. A sample of phosphorus reacts with selenium...Ch. 6 - 99. A compound containing carbon and hydrgen has a...Ch. 6 - A compound containing phosphorus and oxygen has a...Ch. 6 - 101. The molar masses and empirical formulas of...Ch. 6 - The molar masses and empirical formulas of several...Ch. 6 - 103. A. pure copper cube has an edge length of...Ch. 6 - Prob. 104ECh. 6 - A drop of water has a volume of approximately 0.05...Ch. 6 - Fingernail-polish remover is primarily acetone...Ch. 6 - 107. Complete the...Ch. 6 - Prob. 108ECh. 6 - Determine the chemical formula of each compound...Ch. 6 - Prob. 110ECh. 6 - Prob. 111ECh. 6 - Prob. 112ECh. 6 - 113. A leak in the air conditioning system of an...Ch. 6 - 114. A leak in the air conditioning system of an...Ch. 6 - 115. Hydrogen is a possible future fuel. However,...Ch. 6 - Prob. 116ECh. 6 - Complete the table of compounds that contain only...Ch. 6 - 118. Complete the table of compounds that contain...Ch. 6 - Butanedione, a component of butter and body odor,...Ch. 6 - 120. Caffeine, a stimulant found in coffee and...Ch. 6 - 121. Nicotine, a stimulant found tobacco, has the...Ch. 6 - Prob. 122ECh. 6 - 123. A sample contains both KBr and KI in unknown...Ch. 6 - 124. A sample contains both and Ne in unknown...Ch. 6 - Ethanethiol (C2H6S) is a compound with a...Ch. 6 - 126. Methanethiol has a disagreeable odor and is...Ch. 6 - Prob. 127ECh. 6 - Prob. 128ECh. 6 - you can use the concepts in this chapter to obtain...Ch. 6 - Prob. 130ECh. 6 - 131. In 1996, the media reported that possible...Ch. 6 - 132. Using grammatically correct English...Ch. 6 - Discuss these questions with the group and record...Ch. 6 - Amylose is a polysaccharide that plants use to...
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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