(a)
Interpretation:
From the given energy diagram – the transition state and intermediates should be identified
Concept introduction:
The transition states and intermediates can be identified by using following energy profile diagram
Transition state: transition state is defined as a maximum instability of the
Intermediate: intermediate is referred as a stable form of the reaction, it forms from the reactant and it could be isolate from the reaction mixture eventually it can be converted in to the final product.
(b)
Interpretation:
From the given energy diagram – the transition state and intermediates should be identified
Concept introduction:
The transition states and intermediates can be identified by using following energy profile diagram
Transition state: transition state is defined as a maximum instability of the chemical reaction, it requires more energy to attend the transition state finally it will convert in to an intermediate or product and its state is determined by the mechanisms of the particular reaction.
Intermediate: intermediate is referred as a stable form of the reaction, it forms from the reactant and it could be isolate from the reaction mixture eventually it can be converted in to the final product.
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Chapter 6 Solutions
ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT
- Use the literature Ka value of the acetic acid, and the data below to answer these questions. Note: You will not use the experimental titration graphs to answer the questions that follow. Group #1: Buffer pH = 4.35 Group #2: Buffer pH = 4.70 Group #3: Buffer pH = 5.00 Group #4: Buffer pH = 5.30 Use the Henderson-Hasselbalch equation, the buffer pH provided and the literature pKa value of acetic acid to perform the following: a) calculate the ratios of [acetate]/[acetic acid] for each of the 4 groups buffer solutions above. b) using the calculated ratios, which group solution will provide the best optimal buffer (Hint: what [acetate]/[acetic acid] ratio value is expected for an optimal buffer?) c) explain your choicearrow_forwardHow would you prepare 1 liter of a 50 mM Phosphate buffer at pH 7.5 beginning with K3PO4 and 1 M HCl or 1 M NaOH? Please help and show calculations. Thank youarrow_forwardDraw the four most importantcontributing structures of the cation intermediate thatforms in the electrophilic chlorination of phenol,(C6H5OH) to form p-chlorophenol. Put a circle aroundthe best one. Can you please each step and also how you would approach a similar problem. Thank you!arrow_forward
- A 100mM lactic acid/lactate buffer was found to have a lactate to lactic acid ratio of 2 and a pH of 4.2. What is the pKa of lactic acid? Can you please help show the calculations?arrow_forwardUsing line angle formulas, draw thestructures of and name four alkanes that have total of 7carbons, one of which is tertiary.Please explain this in detail and can you also explain how to approach a similar problem like this as well?arrow_forwardUsing dashed line wedge projections drawthe indicated compounds and indicate whether thecompound you have drawn is R or S.(a) The two enantiomers of 2-chlorobutane. Can you please explain your steps and how you would approach a similar problem. Thank you!arrow_forward
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