EBK CHEMISTRY: AN ATOMS FIRST APPROACH
2nd Edition
ISBN: 8220100552236
Author: ZUMDAHL
Publisher: CENGAGE L
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Chapter 6, Problem 133CP
Interpretation Introduction
Interpretation: The flow rates of two burettes Y and Z has to be calculated individually.
Concept Introduction: The flow rate of system can be calculated by taking in the volume of the system to the time taken. The flow rate of system can be given by,
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 6 Solutions
EBK CHEMISTRY: AN ATOMS FIRST APPROACH
Ch. 6 - The (aq) designation listed after a solute...Ch. 6 - Characterize strong electrolytes versus weak...Ch. 6 - Distinguish between the terms slightly soluble and...Ch. 6 - Prob. 4RQCh. 6 - Prob. 5RQCh. 6 - When the following beakers are mixed, draw a...Ch. 6 - Prob. 7RQCh. 6 - What is an acid-base reaction? Strong bases are...Ch. 6 - Prob. 9RQCh. 6 - Assume you have a highly magnified view of a...
Ch. 6 - Prob. 2ALQCh. 6 - You have a sugar solution (solution A) with...Ch. 6 - Prob. 4ALQCh. 6 - Prob. 5ALQCh. 6 - Prob. 6ALQCh. 6 - Consider separate aqueous solutions of HCl and...Ch. 6 - Prob. 8ALQCh. 6 - Prob. 9ALQCh. 6 - The exposed electrodes of a light bulb are placed...Ch. 6 - Differentiate between what happens when the...Ch. 6 - Consider the following electrostatic potential...Ch. 6 - Prob. 15QCh. 6 - A typical solution used in general chemistry...Ch. 6 - Prob. 17QCh. 6 - A student wants to prepare 1.00 L of a 1.00-M...Ch. 6 - List the formulas of three soluble bromide salts...Ch. 6 - When 1.0 mole of solid lead nitrate is added to...Ch. 6 - What is an acid and what is a base? An acid-base...Ch. 6 - A student had 1.00 L of a 1.00-M acid solution....Ch. 6 - Prob. 23QCh. 6 - Prob. 24QCh. 6 - Prob. 25ECh. 6 - Match each name below with the following...Ch. 6 - Prob. 27ECh. 6 - Commercial cold packs and hot packs are available...Ch. 6 - Calculate the molarity of each of these solutions....Ch. 6 - A solution of ethanol (C2H5OH) in water is...Ch. 6 - Calculate the concentration of all ions present in...Ch. 6 - Prob. 32ECh. 6 - Prob. 33ECh. 6 - Prob. 34ECh. 6 - Prob. 35ECh. 6 - Prob. 36ECh. 6 - Prob. 37ECh. 6 - Prob. 38ECh. 6 - A solution is prepared by dissolving 10.8 g...Ch. 6 - A solution was prepared by mixing 50.00 mL of...Ch. 6 - Calculate the sodium ion concentration when 70.0...Ch. 6 - Suppose 50.0 mL of 0.250 M CoCl2 solution is added...Ch. 6 - Prob. 43ECh. 6 - A stock solution containing Mn2+ ions was prepaned...Ch. 6 - On the basis of the general solubility rules given...Ch. 6 - On the basis of the general solubility rules given...Ch. 6 - When the following solutions are mixed together,...Ch. 6 - When the following solutions are mixed together,...Ch. 6 - For the reactions in Exercise 47, write the...Ch. 6 - For the reactions in Exercise 48, write the...Ch. 6 - Write the balanced formula and net ionic equation...Ch. 6 - Give an example how each of the following...Ch. 6 - Write net ionic equations for the reaction, if...Ch. 6 - Write net ionic equations for the reaction, if...Ch. 6 - Prob. 55ECh. 6 - Prob. 56ECh. 6 - What mass of Na2CrO4 is required to precipitate...Ch. 6 - What volume of 0.100 M Na3PO4 is required to...Ch. 6 - What mass of solid aluminum hydroxide can be...Ch. 6 - What mass of barium sulfate can be produced when...Ch. 6 - What mass of solid AgBr is produced when 100.0 mL...Ch. 6 - What mass of silver chloride can be prepared by...Ch. 6 - A 100.0-mL aliquot of 0.200 M aqueous potassium...Ch. 6 - A 1.42-g sample of a pure compound, with formula...Ch. 6 - You are given a 1.50-g mixture of sodium nitrate...Ch. 6 - Write the balanced formula, complete ionic, and...Ch. 6 - Write the balanced formula, complete ionic, and...Ch. 6 - Write the balanced formula equation for the...Ch. 6 - Prob. 70ECh. 6 - What volume of each of the following acids will...Ch. 6 - Prob. 72ECh. 6 - Hydrochloric acid (75.0 mL of 0.250 M) is added to...Ch. 6 - Prob. 74ECh. 6 - A 25.00-mL sample of hydrochloric acid solution...Ch. 6 - A 10.00-mL sample of vinegar, an aqueous solution...Ch. 6 - What volume of 0.0200 M calcium hydroxide is...Ch. 6 - A 30.0-mL sample of an unknown strong base is...Ch. 6 - A student titrates an unknown amount of potassium...Ch. 6 - The concentration of a certain sodium hydroxide...Ch. 6 - Assign oxidation states for all atoms in each of...Ch. 6 - Assign the oxidation state for nitrogen in each of...Ch. 6 - Prob. 84ECh. 6 - Specify which of the following are...Ch. 6 - Specify which of the following equations represent...Ch. 6 - Consider the reaction between sodium metal and...Ch. 6 - Consider the reaction between oxygen (O2) gas and...Ch. 6 - Balance each of the following oxidationreduction...Ch. 6 - Balance each of the following oxidationreduction...Ch. 6 - Prob. 91AECh. 6 - Prob. 92AECh. 6 - Prob. 93AECh. 6 - Prob. 94AECh. 6 - Prob. 95AECh. 6 - Consider a 1.50-g mixture of magnesium nitrate and...Ch. 6 - A 1.00-g sample of an alkaline earth metal...Ch. 6 - A mixture contains only NaCl and Al2(SO4)3. A...Ch. 6 - The thallium (present as Tl2SO4) in a 9.486-g...Ch. 6 - Prob. 100AECh. 6 - A student added 50.0 mL of an NaOH solution to...Ch. 6 - Prob. 102AECh. 6 - Acetylsalicylic acid is the active ingredient in...Ch. 6 - When hydrochloric acid reacts with magnesium...Ch. 6 - A 2.20-g sample of an unknown acid (empirical...Ch. 6 - Carminic acid, a naturally occurring red pigment...Ch. 6 - Chlorisondamine chloride (C14H20Cl6N2) is a drug...Ch. 6 - Prob. 108AECh. 6 - Prob. 109AECh. 6 - Many oxidationreduction reactions can be balanced...Ch. 6 - Prob. 111AECh. 6 - Calculate the concentration of all ions present...Ch. 6 - A solution is prepared by dissolving 0.6706 g...Ch. 6 - For the following chemical reactions, determine...Ch. 6 - What volume of 0.100 M NaOH is required to...Ch. 6 - Prob. 116CWPCh. 6 - A 450.0-mL sample of a 0.257-M solution of silver...Ch. 6 - The zinc in a 1.343-g sample of a foot powder was...Ch. 6 - Prob. 119CWPCh. 6 - When organic compounds containing sulfur are...Ch. 6 - Prob. 121CWPCh. 6 - Prob. 122CPCh. 6 - The units of parts per million (ppm) and parts per...Ch. 6 - Prob. 124CPCh. 6 - Prob. 125CPCh. 6 - Prob. 126CPCh. 6 - Consider the reaction of 19.0 g of zinc with...Ch. 6 - A mixture contains only sodium chloride and...Ch. 6 - Prob. 129CPCh. 6 - Prob. 130CPCh. 6 - Prob. 131CPCh. 6 - Consider reacting copper(II) sulfate with iron....Ch. 6 - Prob. 133CPCh. 6 - Prob. 134CPCh. 6 - What volume of 0.0521 M Ba(OH)2 is required to...Ch. 6 - A 10.00-mL sample of sulfuric acid from an...Ch. 6 - Prob. 137CPCh. 6 - A 6.50-g sample of a diprotic acid requires 137.5...Ch. 6 - Citric acid, which can be obtained from lemon...Ch. 6 - Prob. 140CPCh. 6 - Prob. 141CPCh. 6 - Tris(pentatluorophenyl)borane, commonly known by...Ch. 6 - In a 1-L beaker, 203 mL of 0.307 M ammonium...Ch. 6 - The vanadium in a sample of ore is converted to...Ch. 6 - The unknown acid H2X can be neutralized completely...Ch. 6 - Three students were asked to find the identity of...Ch. 6 - You have two 500.0-mL aqueous solutions. Solution...
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