OWLv2 with MindTap Reader, 4 terms (24 months) Printed Access Card for Zumdahl/Zumdahl's Chemistry, 9th
9th Edition
ISBN: 9781285185446
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 6, Problem 102AE
Calculate ∆H° for the reaction
A 5.00-g chunk of potassium is dropped into 1.00 kg water at 24.0°c. What is the final temperature of the water after the preceding reaction occurs? Assume that all the heat is used to raise the temperature of the water. (Never run this reaction. It is very dangerous; it bursts into flame!)
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
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18
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1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
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18
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
Ar
Chapter 6 Solutions
OWLv2 with MindTap Reader, 4 terms (24 months) Printed Access Card for Zumdahl/Zumdahl's Chemistry, 9th
Ch. 6 - Define the following terms: potential energy,...Ch. 6 - Consider the following potential energy diagrams...Ch. 6 - What is the first law of thermodynamics? How can a...Ch. 6 - When a gas expands, what is the sign of w? Why?...Ch. 6 - What is the heat gained/released at constant...Ch. 6 - High-quality audio amplifiers generate large...Ch. 6 - Explain how calorimetry works to calculate H or E...Ch. 6 - What is Hesss law? When a reaction is reversed,...Ch. 6 - Define the standard enthalpy of formation. What...Ch. 6 - Objects placed together eventually reach the same...
Ch. 6 - What is meant by the term lower in energy? Which...Ch. 6 - A fire is started in a fireplace by striking a...Ch. 6 - Liquid water turns to ice. Is this process...Ch. 6 - Consider the following statements: ''Heat is a...Ch. 6 - Consider 5.5 L of a gas at a pressure of 3.0 atm...Ch. 6 - Consider 5.5 L of a gas at a pressure of 3.0 atm...Ch. 6 - What if energy was not conserved? 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