
a)
Interpretation:
The ranking of the substituent is to done from the following sets of substituent.
Concept introduction:
Rule 1:
a) Higher
b) An atom node duplicated closer to the root ranks higher than one duplicated further.
Rule 2: Higher
Rule 3: Z precedes E and this precedes nonstereogenic (nst) double bonds.
Rule 4:
a) Chiral stereogenic units precede pseudoasymmetric stereogenic units and these precede nonstereogenic units (R = S > r = s > nst).
b) When two ligards have different descriptor pairs, the one with the first chosen like descriptor pairs has priority over the one with a corresponding unlike descriptor pairs.
c) r precedes s.
Rule 5: An atom or group with descriptor R has priority over its enantiomorph S.
b)
Interpretation:
The ranking of the substituent is to done from the following sets of substituent.
Concept introduction:
Rule 1:
a) Higher atomic number precedes lower.
b) An atom node duplicated closer to the root ranks higher than one duplicated further.
Rule 2: Higher atomic mass number precedes lower.
Rule 3: Z precedes E and this precedes nonstereogenic (nst) double bonds.
Rule 4:
a) Chiral stereogenic units precede pseudoasymmetric stereogenic units and these precede nonstereogenic units (R = S > r = s > nst).
b) When two ligards have different descriptor pairs, the one with the first chosen like descriptor pairs has priority over the one with a corresponding unlike descriptor pairs.
c) r precedes s.
Rule 5: An atom or group with descriptor R has priority over its enantiomorph S.
c)
Interpretation:
The ranking of the substituent is to done from the following sets of substituent.
Concept introduction:
Rule 1:
a) Higher atomic number precedes lower.
b) An atom node duplicated closer to the root ranks higher than one duplicated further.
Rule 2: Higher atomic mass number precedes lower.
Rule 3: Z precedes E and this precedes nonstereogenic (nst) double bonds.
Rule 4:
a) Chiral stereogenic units precede pseudoasymmetric stereogenic units and these precede nonstereogenic units (R = S > r = s > nst).
b) When two ligards have different descriptor pairs, the one with the first chosen like descriptor pairs has priority over the one with a corresponding unlike descriptor pairs.
c) r precedes s.
Rule 5: An atom or group with descriptor R has priority over its enantiomorph S.
d)
Interpretation:
The ranking of the substituent is to done from the following sets of substituent.
Concept introduction:
Rule 1:
a) Higher atomic number precedes lower.
b) An atom node duplicated closer to the root ranks higher than one duplicated further.
Rule 2: Higher atomic mass number precedes lower.
Rule 3: Z precedes E and this precedes nonstereogenic (nst) double bonds.
Rule 4:
a) Chiral stereogenic units precede pseudoasymmetric stereogenic units and these precede nonstereogenic units (R = S > r = s > nst).
b) When two ligards have different descriptor pairs, the one with the first chosen like descriptor pairs has priority over the one with a corresponding unlike descriptor pairs.
c) r precedes s.
Rule 5: An atom or group with descriptor R has priority over its enantiomorph S.

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Chapter 5 Solutions
Study Guide with Student Solutions Manual for McMurry's Organic Chemistry, 9th
- If a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.arrow_forwardWhat is the major organic product of the following nucleophilic acyl substitution reaction of an acid chloride below?arrow_forwardWould the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forward
- If a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.arrow_forwardPlease help me answer the following questions using the data I included. 1&2arrow_forwardAssign all the Protons in HNMRarrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning

