Check whether the given allene is chiral or achiral. Concept Introduction: Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds. Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre. An achiral carbon is a carbon having two or more identical groups around it. Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light. Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis. Example: Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

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Answer 1

Question

Chapter 5.9, Problem 28CC

(a)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(b)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(c)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(d)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangemen6t of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

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Identifying electron-donating and For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene. Molecule Inductive Effects NH2 ○ donating NO2 Explanation Check withdrawing no inductive effects Resonance Effects Overall Electron-Density ○ donating O withdrawing O no resonance effects O donating O withdrawing O donating withdrawing O no inductive effects Ono resonance effects O electron-rich electron-deficient O similar to benzene O electron-rich O electron-deficient O similar to benzene olo 18 Ar 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility

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Answer 2

Question

Chapter 5.9, Problem 28CC

(a)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(b)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(c)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(d)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangemen6t of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

Expert Solution & Answer

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Answer 3

Question

Chapter 5.9, Problem 28CC

(a)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(b)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(c)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(d)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangemen6t of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

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Answer 4

Question

Chapter 5.9, Problem 28CC

(a)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(b)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(c)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(d)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangemen6t of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

Expert Solution & Answer

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Answer 5

Chapter 5.9, Problem 28CC

(a)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(b)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(c)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

(d)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangemen6t of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

Answer 6

Chapter 5.9, Problem 28CC

(a)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

Answer 7

Chapter 5.9, Problem 28CC

(a)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangement of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangemen6t of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Check whether the given allene is chiral or achiral.

Concept Introduction:

Allenes are compounds with two or more double bonds side-by side. Such bonds are called cumulated double bonds.

Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.

An achiral carbon is a carbon having two or more identical groups around it.

Chirality: The geometric property of molecules where the structure of the molecule and its mirror image are not superimposable is known as chirality. Chiral molecules are optically active and they can rotate the plane polarized light.

Allenes shows axial chirality. Axial chirality is a stereoisomerism resulting from the non-planar arrangemen6t of four groups in pairs about a chiral axis.

Example:

Here cumulated π bonds of an allene lie in perpendicular planes and so unsymmetrically substituted allenes are chiral.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 5.1 - In the following compound, identify each unit...Ch. 5.1 - Prob. 2CC Ch. 5.1 - Prob. 3CC Ch. 5.2 - Prob. 1LTS Ch. 5.2 - Prob. 4PTS Ch. 5.2 - Prob. 5ATS Ch. 5.2 - Prob. 6ATS Ch. 5.2 - Prob. 2LTS Ch. 5.2 - Prob. 7PTS Ch. 5.2 - Prob. 8ATS

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