Organic Chemistry As a Second Language: Second Semester Topics
4th Edition
ISBN: 9781119110651
Author: David R. Klein
Publisher: WILEY
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Textbook Question
Chapter 5.4, Problem 5.21P
Propose a mechanism for each of the following reactions:
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a) Write out 6 completely different reactions of acetophenone (reagent, product).
b) Write out 3 preparations of 1-methylcyclohexanol, using a different starting material
for each one. You may use preps where you just change the functional group, and/or
preps where you construct the carbon chain.
c) Write out 3 preparations of 2-ethoxybenzoic acid, a different starting material for
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12.
CH3
OH
OH
H&C
CH3
H₂C
N
OH H₂C
CH3
H&C
CH3 H₂C'
CH3
H.C
CH3OH
H.C
CH2CH3OH
CH3CEN
Which one of these 17 compounds is represented by this IR and this 'H NMR
spectrum?
IR Spectrum
3000
4000
3000
NMR Spectrum
2000
£500
RAVENUMBER
2000
1500
9
8
6
5
10
HP-00-290
ppm
m
1000
500
1000
4
°
Draw the structure of (E,6R) 6-methoxy-4-hepten-2-one.
Give the IUPAC name of this compound,
including stereochemistry.
Draw the most stable chair conformation of
(cis) 1,3-isobutylcyclohexane.
H
HC=CCH₂
CH2CH3
EN(CH3)2
-CN(CH3)2
Chapter 5 Solutions
Organic Chemistry As a Second Language: Second Semester Topics
Ch. 5.1 - Prob. 5.2PCh. 5.1 - Prob. 5.3PCh. 5.1 - Prob. 5.4PCh. 5.1 - Prob. 5.5PCh. 5.1 - Prob. 5.6PCh. 5.1 - Prob. 5.7PCh. 5.2 - Propose a mechanism for each of the following...Ch. 5.2 - Propose a mechanism for each of the following...Ch. 5.2 - Propose a mechanism for each of the following...Ch. 5.3 - Prob. 5.13P
Ch. 5.3 - Prob. 5.14PCh. 5.3 - Prob. 5.15PCh. 5.3 - Prob. 5.16PCh. 5.3 - Prob. 5.17PCh. 5.3 - Prob. 5.18PCh. 5.4 - Propose a mechanism for each of the following...Ch. 5.4 - Propose a mechanism for each of the following...Ch. 5.4 - Propose a mechanism for each of the following...Ch. 5.4 - Propose a mechanism for each of the following...
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