Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
7th Edition
ISBN: 9780134240152
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 5.4, Problem 15P
(a)
Interpretation Introduction
Interpretation:
Isomers for the given compound have to be drawn and their name should be determined.
Concept introduction:
- Compounds which have similar number of atoms but differ in physical and chemical properties and are called isomers and the phenomenon is called isomerism.
- Isomers have same molecular formula but differ in arrangement of atoms within a molecule.
- If two compound have the same molecular and structural formula, but differ in the spatial arrangement of different atoms or groups about a ring or about a double bond.
- If two identical groups occur on the same side of the double bond the compound is cis. If they are on opposite sides the compound is trans.
- E-Z designators are used as like cis-trans terminology for non-similar groups attached
alkenes . - In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher molecular weight. If the higher priority groups are on the same sides, then the configuration is designated as Z. If the higher priority groups are on the opposite sides, then the configuration is designated as E.
- Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
- Prefix represents the substituent present in the molecule and its position in the root name.
- Suffix denotes the presence of
functional group if any in the molecule. It can be an alkene,alkyne , alcohol,carboxylic acid , alcohol etc. - For alkenes, suffix will be ‘ene’
(b)
Interpretation Introduction
Interpretation:
Isomers for the given compound have to be drawn and their name should be determined.
Concept introduction:
- Compounds which have similar number of atoms but differ in physical and chemical properties and are called isomers and the phenomenon is called isomerism.
- Isomers have same molecular formula but differ in arrangement of atoms within a molecule.
- If two compound have the same molecular and structural formula, but differ in the spatial arrangement of different atoms or groups about a ring or about a double bond.
- If two identical groups occur on the same side of the double bond the compound is cis. If they are on opposite sides the compound is trans.
- E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.
- In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher molecular weight. If the higher priority groups are on the same sides, then the configuration is designated as Z. If the higher priority groups are on the opposite sides, then the configuration is designated as E.
- Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
- Prefix represents the substituent present in the molecule and its position in the root name.
- Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.
- For alkenes, suffix will be ‘ene’
(c)
Interpretation Introduction
Interpretation:
Isomers for the given compound have to be drawn and their name should be determined.
Concept introduction:
- Compounds which have similar number of atoms but differ in physical and chemical properties and are called isomers and the phenomenon is called isomerism.
- Isomers have same molecular formula but differ in arrangement of atoms within a molecule.
- If two compound have the same molecular and structural formula, but differ in the spatial arrangement of different atoms or groups about a ring or about a double bond.
- If two identical groups occur on the same side of the double bond the compound is cis. If they are on opposite sides the compound is trans.
- E-Z designators are used as like cis-trans terminology for non-similar groups attached alkenes.
- In E-Z designations, the groups attached to vinylic positions are checked by their priority on the basis of higher molecular weight. If the higher priority groups are on the same sides, then the configuration is designated as Z. If the higher priority groups are on the opposite sides, then the configuration is designated as E.
- Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
- Prefix represents the substituent present in the molecule and its position in the root name.
- Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.
- For alkenes, suffix will be ‘ene’
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Chapter 5 Solutions
Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)
Ch. 5.1 - Determine the degree of unsaturation and then draw...Ch. 5.1 - Prob. 4PCh. 5.2 - Prob. 5PCh. 5.2 - Draw the structure for each of the following: a....Ch. 5.2 - What is each compounds systematic name?Ch. 5.4 - Assign relative priorities to each set of...Ch. 5.4 - Tamoxifen slows the growth of some breast tumors...Ch. 5.4 - Draw and label the E and Z isomers for each of the...Ch. 5.4 - Prob. 12PCh. 5.4 - Name each of the following:
Ch. 5.4 - Prob. 14PCh. 5.4 - Prob. 15PCh. 5.6 - Prob. 16PCh. 5.6 - Prob. 17PCh. 5.6 - Prob. 18PCh. 5.6 - Prob. 20PCh. 5.7 - a. Which of the monosubstituted cyclohexanes in...Ch. 5.7 - a. for which reaction in each set will S be more...Ch. 5.7 - a. For a reaction with H = 12 kcal/ mol and S =...Ch. 5.7 - Prob. 25PCh. 5.7 - Prob. 26PCh. 5.7 - Prob. 27PCh. 5.9 - The rate constant for a reaction can be increased...Ch. 5.9 - Prob. 30PCh. 5.9 - a. Which reaction has a greater equilibrium...Ch. 5.10 - Draw a reaction coordinate diagram for a two-step...Ch. 5.10 - a. Which step in the reaction coordinate diagram...Ch. 5.10 - Draw a reaction coordinate diagram for the...Ch. 5.11 - Prob. 35PCh. 5 - What is each compounds systematic name?Ch. 5 - Draw the structure of a hydrocarbon that has six...Ch. 5 - Draw the condensed structure for each of the...Ch. 5 - Prob. 39PCh. 5 - Prob. 40PCh. 5 - Name the following:Ch. 5 - Prob. 42PCh. 5 - 43. Draw the skeletal structure of...Ch. 5 - In a reaction in which reactant A is in...Ch. 5 - Which bond is stronger? Briefly explain why.Ch. 5 - Prob. 46PCh. 5 - Prob. 47PCh. 5 - Assign relative priorities to each set of...Ch. 5 - Prob. 49PCh. 5 - By following the curved red arrows, draw the...Ch. 5 - Prob. 51PCh. 5 - Draw structures for the following: a....Ch. 5 - Prob. 53PCh. 5 - a. Which of the following reactions has the larger...Ch. 5 - a. What is the equilibrium constant for a reaction...Ch. 5 - Prob. 56PCh. 5 - Prob. 57PCh. 5 - Given that the free energy of the twist-boat...Ch. 5 - Prob. 59PCh. 5 - Prob. 1PCh. 5 - Prob. 2PCh. 5 - Prob. 3PCh. 5 - Prob. 4PCh. 5 - Prob. 5PCh. 5 - Prob. 6PCh. 5 - Draw curved arrows to show the movement of the...Ch. 5 - Prob. 8PCh. 5 - Prob. 9PCh. 5 - Prob. 10P
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