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Concept explainers
Interpretation:
Enantiomer of the given compound has to be drawn.
Concept introduction:
The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.
The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.
Enantiomers: These are the structures of compounds in which the configuration of all the carbon atoms is different from each other. Both the structures are non-superimposable on it mirror image.
Chiral centre: A chiral centre is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic centre.
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Chapter 5 Solutions
Organic Chemistry 3rd.ed. Klein Evaluation/desk Copy
- (6 pts - 2 pts each part) Although we focused our discussion on hydrogen light emission, all elements have distinctive emission spectra. Sodium (Na) is famous for its spectrum being dominated by two yellow emission lines at 589.0 and 589.6 nm, respectively. These lines result from electrons relaxing to the 3s subshell. a. What is the photon energy (in J) for one of these emission lines? Show your work. b. To what electronic transition in hydrogen is this photon energy closest to? Justify your answer-you shouldn't need to do numerical calculations. c. Consider the 3s subshell energy for Na - use 0 eV as the reference point for n=∞. What is the energy of the subshell that the electron relaxes from? Choose the same emission line that you did for part (a) and show your work.arrow_forwardNonearrow_forward(9 Pts) In one of the two Rare Earth element rows of the periodic table, identify an exception to the general ionization energy (IE) trend. For the two elements involved, answer the following questions. Be sure to cite sources for all physical data that you use. a. (2 pts) Identify the two elements and write their electronic configurations. b. (2 pts) Based on their configurations, propose a reason for the IE trend exception. c. (5 pts) Calculate effective nuclear charges for the last electron in each element and the Allred-Rochow electronegativity values for the two elements. Can any of these values explain the IE trend exception? Explain how (not) - include a description of how IE relates to electronegativity.arrow_forward
- Please explain thoroughly and provide steps to draw.arrow_forwardAs you can see in the picture, the instrument uses a Xe source. Given that the instrument is capable of measuring from 200-800nm, if Xe was not used, what other source(s) could be used? Refer to figure 7-3. How many monochrometers does this instrument have? Why? Trace the light as it goes from the Xenon lamp all the way to the circle just slightly to the right and a little bit down from S4. What do you think that circle is? In class we talked about many types of these, which kind do you think this one is for a fluorimeter? Why? Explain. What is/are some strategy(ies) that this instrument has for dealing with noise that you see present in the optics diagram? Why does a fluorescence cuvette have to be clear on four sides?arrow_forwardProvide steps and thoroughly solve.arrow_forward
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