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Concept explainers
Interpretation: The structure for the exo product formed by the reaction of cyclopentadiene with maleic anhydride should be predicted.
Concept introduction:
The reaction between a diene (4π electron system) and a dienophile (2π electron system) to give a substituted cyclohexane derivative is termed as Diels Alder reaction. This reaction is a cycloaddition reaction.
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Answer to Problem 1Q
The structure for the exo product formed by the reaction of cyclopentadiene with maleic anhydride is represented as follows:
Explanation of Solution
Cyclopentadiene is a 4π electron system thus, it will be the diene. On the other hand, maleic anhydride is a 2π electron system thus, it will act as a dienophile. Therefore, the product formation for the reaction between cyclopentadiene and maleic anhydride should be represented as follows:
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Chapter 52 Solutions
EBK A SMALL SCALE APPROACH TO ORGANIC L
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- Nonearrow_forwardNonearrow_forwardWhat spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.arrow_forward
- Nonearrow_forwardNonearrow_forwardIn the solid state, oxalic acid occurs as a dihydrate with the formula H2C2O4 C+2H2O. Use this formula to calculate the formula weight of oxalic acid. Use the calculated formula weight and the number of moles (0.00504mol) of oxalic acid in each titrated unknown sample recorded in Table 6.4 to calculate the number of grams of pure oxalic acid dihydrate contained in each titrated unknown sample.arrow_forward
- EBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENTOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
- Macroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole
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