Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card
5th Edition
ISBN: 9781305367487
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 5, Problem 65QRT
Interpretation Introduction
Interpretation:
The electronic configuration of
Concept Introduction:
Hund’s rule: Each orbital must be singly occupied before any orbital is occupied. All the electrons in singly occupied orbitals have same spin.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 5 Solutions
Bundle: Chemistry: The Molecular Science, 5th, Loose-Leaf + OWLv2 with Quick Prep 24-Months Printed Access Card
Ch. 5.1 - In the upper atmosphere there is solar radiation...Ch. 5.1 - A fellow chemistry student says that low-frequency...Ch. 5.1 - One type of solar radiation in the upper...Ch. 5.2 - Prob. 5.2PSPCh. 5.2 - Prob. 5.3ECh. 5.3 - Prob. 5.4ECh. 5.3 - Prob. 5.3PSPCh. 5.3 - The hydrogen atom contains only one electron, but...Ch. 5.3 - (a) Calculate the frequency and the wavelength of...Ch. 5.3 - Show that the value of the Rydberg constant per...
Ch. 5.4 - Calculate the de Broglie wavelength of a neutron...Ch. 5.5 - Prob. 5.7ECh. 5.5 - Prob. 5.8ECh. 5.5 - Prob. 5.6PSPCh. 5.5 - Prob. 5.9ECh. 5.5 - Prob. 5.10CECh. 5.5 - Prob. 5.11ECh. 5.5 - Prob. 5.12ECh. 5.5 - Prob. 5.13CECh. 5.7 - Use atomic orbital box diagrams to determine which...Ch. 5.7 - Prob. 5.7PSPCh. 5.7 - Prob. 5.15ECh. 5.7 - Prob. 5.8PSPCh. 5.8 - (a) What Period 3 anion with a 2 charge has the...Ch. 5.8 - Prob. 5.10PSPCh. 5.8 - Fluoride ion, F, has no unpaired electrons....Ch. 5.9 - Prob. 5.11PSPCh. 5.10 - Which of these isoelectronic ions, Ba2+, Cs+, or...Ch. 5.11 - Prob. 5.13PSPCh. 5.13 - Consider these ionic compounds: KCl, CaS, CaO,...Ch. 5 - Prob. 1QRTCh. 5 - Prob. 2QRTCh. 5 - Prob. 3QRTCh. 5 - Prob. 4QRTCh. 5 - Prob. 5QRTCh. 5 - Prob. 6QRTCh. 5 - Prob. 7QRTCh. 5 - Prob. 8QRTCh. 5 -
Write the electron configurations for the valence...Ch. 5 - Prob. 10QRTCh. 5 - Prob. 11QRTCh. 5 - Prob. 12QRTCh. 5 - Prob. 13QRTCh. 5 - The colors of the visible spectrum and the...Ch. 5 - Prob. 15QRTCh. 5 - Prob. 16QRTCh. 5 - Prob. 17QRTCh. 5 - Prob. 18QRTCh. 5 - Prob. 19QRTCh. 5 - Light of very long wavelength strikes a...Ch. 5 - Prob. 21QRTCh. 5 - Prob. 22QRTCh. 5 - Prob. 23QRTCh. 5 - A photoemissive material has a threshold energy,...Ch. 5 - Prob. 25QRTCh. 5 - Prob. 26QRTCh. 5 - Prob. 27QRTCh. 5 - Prob. 28QRTCh. 5 - Prob. 29QRTCh. 5 - Prob. 30QRTCh. 5 - Prob. 31QRTCh. 5 - Calculate the energy and wavelength of the photon...Ch. 5 - Calculate the energy and the wavelength of the...Ch. 5 - Spectroscopists have observed He+ in outer space....Ch. 5 - Prob. 35QRTCh. 5 - Prob. 36QRTCh. 5 - Prob. 37QRTCh. 5 - Prob. 38QRTCh. 5 - Prob. 39QRTCh. 5 - Prob. 40QRTCh. 5 - Prob. 41QRTCh. 5 - Give possible values for all four quantum numbers...Ch. 5 - Prob. 43QRTCh. 5 - Assign a correct set of four quantum numbers for...Ch. 5 - Prob. 45QRTCh. 5 - Prob. 46QRTCh. 5 - Assign a correct set of four quantum numbers for...Ch. 5 - Prob. 48QRTCh. 5 - Prob. 49QRTCh. 5 - Prob. 50QRTCh. 5 - Prob. 51QRTCh. 5 - Prob. 52QRTCh. 5 - Prob. 53QRTCh. 5 - Titanium metal and Cr2+ have the same number of...Ch. 5 - Consider a 2+ ion that has six 3d electrons; which...Ch. 5 - Prob. 56QRTCh. 5 - Prob. 57QRTCh. 5 - Prob. 58QRTCh. 5 - Prob. 59QRTCh. 5 - Prob. 60QRTCh. 5 - Prob. 61QRTCh. 5 - Prob. 62QRTCh. 5 - Prob. 63QRTCh. 5 - Prob. 64QRTCh. 5 - Prob. 65QRTCh. 5 - Prob. 66QRTCh. 5 - Prob. 67QRTCh. 5 - Prob. 68QRTCh. 5 - Prob. 69QRTCh. 5 - Prob. 70QRTCh. 5 - Prob. 71QRTCh. 5 - Prob. 72QRTCh. 5 - Prob. 73QRTCh. 5 - Prob. 74QRTCh. 5 - Prob. 75QRTCh. 5 - Prob. 76QRTCh. 5 - Prob. 77QRTCh. 5 - Prob. 78QRTCh. 5 - Use electron configurations to explain why (a)...Ch. 5 - Prob. 80QRTCh. 5 - Arrange these elements in order of increasing...Ch. 5 - Prob. 82QRTCh. 5 - Arrange these elements in order of increasing...Ch. 5 - Prob. 84QRTCh. 5 - Prob. 85QRTCh. 5 - Prob. 86QRTCh. 5 - Prob. 87QRTCh. 5 - Prob. 88QRTCh. 5 - Prob. 89QRTCh. 5 - Compare the elements B, Al, C, Si. (a) Which has...Ch. 5 - Prob. 91QRTCh. 5 - Prob. 92QRTCh. 5 - Prob. 93QRTCh. 5 - Prob. 94QRTCh. 5 - Determine the lattice energy for LiCl(s) given...Ch. 5 - Prob. 96QRTCh. 5 - Prob. 97QRTCh. 5 - Prob. 98QRTCh. 5 - Prob. 99QRTCh. 5 - Prob. 100QRTCh. 5 - Prob. 101QRTCh. 5 - Prob. 102QRTCh. 5 - Prob. 103QRTCh. 5 - Prob. 104QRTCh. 5 - Prob. 105QRTCh. 5 - Prob. 106QRTCh. 5 - Prob. 107QRTCh. 5 - Prob. 108QRTCh. 5 - Prob. 109QRTCh. 5 - Prob. 113QRTCh. 5 - Prob. 114QRTCh. 5 - Prob. 115QRTCh. 5 - Prob. 116QRTCh. 5 - Prob. 117QRTCh. 5 - Prob. 119QRTCh. 5 - Prob. 120QRTCh. 5 - Prob. 121QRTCh. 5 - Prob. 123QRTCh. 5 - Prob. 124QRTCh. 5 - Prob. 125QRTCh. 5 - Prob. 126QRTCh. 5 - Prob. 127QRTCh. 5 - Prob. 128QRTCh. 5 - Prob. 129QRTCh. 5 - Calculate the effective nuclear charge, Z, on...Ch. 5 - Prob. 131QRTCh. 5 - Prob. 133QRTCh. 5 - Prob. 134QRTCh. 5 - Prob. 135QRTCh. 5 - According to a relationship developed by Niels...Ch. 5 - Prob. 137QRTCh. 5 - Prob. 138QRTCh. 5 - Prob. 139QRTCh. 5 - Prob. 140QRTCh. 5 - Prob. 141QRTCh. 5 - Prob. 142QRTCh. 5 - Prob. 143QRTCh. 5 - Prob. 144QRTCh. 5 - Prob. 5.ACPCh. 5 - Prob. 5.CCP
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