Elements of Physical Chemistry
7th Edition
ISBN: 9780192522764
Author: Peter Atkins; Julio de Paula
Publisher: Oxford University Press Academic UK
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Chapter 5, Problem 5B.1ST
Interpretation Introduction
Interpretation:
The composition of a solution in terms of the fraction of molecules that are B in which two isomers A and B are in equilibrium (
Concept Introduction:
Fraction can be defined as the ratio of the concentration of one isomer to the total concentration of solutes. As fraction is expressed in terms of concentration, it is related to equilibrium
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Draw the anti-Markovnikov product of the hydration of this alkene.
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
Chapter 5 Solutions
Elements of Physical Chemistry
Ch. 5 - Prob. 5A.1STCh. 5 - Prob. 5A.2STCh. 5 - Prob. 5A.3STCh. 5 - Prob. 5A.4STCh. 5 - Prob. 5A.5STCh. 5 - Prob. 5B.1STCh. 5 - Prob. 5B.2STCh. 5 - Prob. 5B.3STCh. 5 - Prob. 5C.1STCh. 5 - Prob. 5C.2ST
Ch. 5 - Prob. 5D.1STCh. 5 - Prob. 5D.2STCh. 5 - Prob. 5D.3STCh. 5 - Prob. 5D.4STCh. 5 - Prob. 5D.5STCh. 5 - Prob. 5E.1STCh. 5 - Prob. 5E.2STCh. 5 - Prob. 5F.1STCh. 5 - Prob. 5F.2STCh. 5 - Prob. 5F.3STCh. 5 - Prob. 5F.4STCh. 5 - Prob. 5F.5STCh. 5 - Prob. 5G.1STCh. 5 - Prob. 5G.2STCh. 5 - Prob. 5G.3STCh. 5 - Prob. 5H.1STCh. 5 - Prob. 5H.2STCh. 5 - Prob. 5H.3STCh. 5 - Prob. 5I.1STCh. 5 - Prob. 5I.2STCh. 5 - Prob. 5I.3STCh. 5 - Prob. 5I.4STCh. 5 - Prob. 5I.5STCh. 5 - Prob. 5I.6STCh. 5 - Prob. 5J.1STCh. 5 - Prob. 5J.2STCh. 5 - Prob. 5J.3STCh. 5 - Prob. 5J.4STCh. 5 - Prob. 5J.5STCh. 5 - Prob. 5A.1ECh. 5 - Prob. 5A.2ECh. 5 - Prob. 5A.3ECh. 5 - Prob. 5A.4ECh. 5 - Prob. 5A.5ECh. 5 - Prob. 5A.6ECh. 5 - Prob. 5A.7ECh. 5 - Prob. 5A.8ECh. 5 - Prob. 5A.9ECh. 5 - Prob. 5A.10ECh. 5 - Prob. 5A.11ECh. 5 - Prob. 5A.12ECh. 5 - Prob. 5A.13ECh. 5 - Prob. 5B.1ECh. 5 - Prob. 5B.2ECh. 5 - Prob. 5B.3ECh. 5 - Prob. 5B.4ECh. 5 - Prob. 5B.5ECh. 5 - Prob. 5C.1ECh. 5 - Prob. 5C.2ECh. 5 - Prob. 5C.3ECh. 5 - Prob. 5C.4ECh. 5 - Prob. 5D.1ECh. 5 - Prob. 5D.2ECh. 5 - Prob. 5D.3ECh. 5 - Prob. 5D.4ECh. 5 - Prob. 5E.1ECh. 5 - Prob. 5E.2ECh. 5 - Prob. 5F.4ECh. 5 - Prob. 5G.1ECh. 5 - Prob. 5G.2ECh. 5 - Prob. 5G.3ECh. 5 - Prob. 5H.1ECh. 5 - Prob. 5H.2ECh. 5 - Prob. 5H.3ECh. 5 - Prob. 5H.4ECh. 5 - Prob. 5I.1ECh. 5 - Prob. 5I.2ECh. 5 - Prob. 5I.3ECh. 5 - Prob. 5I.4ECh. 5 - Prob. 5J.1ECh. 5 - Prob. 5J.2ECh. 5 - Prob. 5J.3ECh. 5 - Prob. 5J.4ECh. 5 - Prob. 5.1DQCh. 5 - Prob. 5.2DQCh. 5 - Prob. 5.3DQCh. 5 - Prob. 5.4DQCh. 5 - Prob. 5.5DQCh. 5 - Prob. 5.6DQCh. 5 - Prob. 5.7DQCh. 5 - Prob. 5.8DQCh. 5 - Prob. 5.9DQCh. 5 - Prob. 5.10DQCh. 5 - Prob. 5.11DQCh. 5 - Prob. 5.12DQCh. 5 - Prob. 5.13DQCh. 5 - Prob. 5.14DQCh. 5 - Prob. 5.15DQCh. 5 - Prob. 5.16DQCh. 5 - Prob. 5.17DQCh. 5 - Prob. 5.1PCh. 5 - Prob. 5.2PCh. 5 - Prob. 5.3PCh. 5 - Prob. 5.4PCh. 5 - Prob. 5.5PCh. 5 - Prob. 5.6PCh. 5 - Prob. 5.7PCh. 5 - Prob. 5.8PCh. 5 - Prob. 5.9PCh. 5 - Prob. 5.10PCh. 5 - Prob. 5.11PCh. 5 - Prob. 5.12PCh. 5 - Prob. 5.13PCh. 5 - Prob. 5.14PCh. 5 - Prob. 5.15PCh. 5 - Prob. 5.16PCh. 5 - Prob. 5.17PCh. 5 - Prob. 5.18PCh. 5 - Prob. 5.19PCh. 5 - Prob. 5.20PCh. 5 - Prob. 5.21PCh. 5 - Prob. 5.22PCh. 5 - Prob. 5.23PCh. 5 - Prob. 5.24PCh. 5 - Prob. 5.25PCh. 5 - Prob. 5.27PCh. 5 - Prob. 5.28PCh. 5 - Prob. 5.29PCh. 5 - Prob. 5.30PCh. 5 - Prob. 5.31PCh. 5 - Prob. 5.32PCh. 5 - Prob. 5.33PCh. 5 - Prob. 5.34PCh. 5 - Prob. 5.35PCh. 5 - Prob. 5.36PCh. 5 - Prob. 5.37PCh. 5 - Prob. 5.38PCh. 5 - Prob. 5.39PCh. 5 - Prob. 5.40PCh. 5 - Prob. 5.41PCh. 5 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - Prob. 5.45PCh. 5 - Prob. 5.46PCh. 5 - Prob. 5.47PCh. 5 - Prob. 5.48PCh. 5 - Prob. 5.49PCh. 5 - Prob. 5.50PCh. 5 - Prob. 5.51PCh. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - Prob. 5.55PCh. 5 - Prob. 5.56PCh. 5 - Prob. 5.58PCh. 5 - Prob. 5.59PCh. 5 - Prob. 5.60PCh. 5 - Prob. 5.61PCh. 5 - Prob. 5.62PCh. 5 - Prob. 5.63PCh. 5 - Prob. 5.64PCh. 5 - Prob. 5.66PCh. 5 - Prob. 5.67PCh. 5 - Prob. 5.68PCh. 5 - Prob. 5.69PCh. 5 - Prob. 5.70PCh. 5 - Prob. 5.71PCh. 5 - Prob. 5.72PCh. 5 - Prob. 5.73PCh. 5 - Prob. 5.74PCh. 5 - Prob. 5.76PCh. 5 - Prob. 5.77PCh. 5 - Prob. 5.78PCh. 5 - Prob. 5.79PCh. 5 - Prob. 5.1PRCh. 5 - Prob. 5.2PRCh. 5 - Prob. 5.3PRCh. 5 - Prob. 5.4PR
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