Chapter 5, Problem 5.63P

(a)

Interpretation Introduction

Interpretation:

The number of moles of gas that are collected in $21\text{ L}$ steel tank at $45°\text{C}$ is to be calculated.

Concept introduction:

According to the Boyle’s law, the volume occupied by the gas is inversely proportional to the pressure at the constant temperature.

The relationship between pressure and volume can be expressed as follows,

$PV=\text{constant}$

Here, $P$ is the pressure and $V$ is the volume.

According to Charles's law, the volume occupied by the gas is directly proportional to the temperature at the constant pressure.

The relationship between pressure and temperature can be expressed as follows,

$V\alpha T$

Here, $T$ is the temperature and $V$ is the volume.

According to Avogadro’s law, the volume occupied by the gas is directly proportional to the mole of the gas at the constant pressure and temperature.

The relationship between volume and mole can be expressed as follows,

$\text{V }\alpha n$

Here, $n$ is the mole of the gas and $V$ is the volume.

The ideal gas equation can be expressed as follows,

$PV=nRT$

Here, $P$ is the pressure, $V$ is the volume, $T$ is the temperature, $n$ is the mole of the gas and $R$ is the gas constant.

The expression to calculate the density of the air is as follows,

$d=\frac{PM}{RT}$

Here, $P$ is the pressure, $M$ is the molecular mass, $T$ is the temperature, $d$ is the density of the air and $R$ is the gas constant.

The expression to calculate the number of a molecule of the air is as follows,

$\text{Number of molceule of air}=\left(\text{Mole of air}\right)\left(\text{Avogadro number}\right)$.

(b)

Interpretation Introduction

Interpretation:

The partial pressure of the ${\text{SO}}_{\text{2}}$ in the mixture of $7.95\times {10}^{-3}$$\text{ppmv}$ is to be calculated.

Concept introduction:

The expression to calculate the partial pressure ${\text{SO}}_{\text{2}}$ is as follows,

$P_{\text{gas}}=\left(X_{\text{gas}}\right)\left(P_{\text{total}}\right)$

Here, $P_{\text{gas}}$ is the partial pressure of gas, $X_{\text{gas}}$ mole fraction of gas and $P_{\text{total}}$ is the total pressure.

The expression to calculate the parts per million by volume $\left(\text{ppmv}\right)$ is as follows,

$\text{ppmv}=\frac{\left(\text{volume of component}\right)}{\left(\text{volume of mixture}\right)}\times {10}^6$