The formation of zwitterionic glycine, CH 2 ( NH 3 + ) ( COO − ) , from its fully acid form CH 2 ( NH 3 + ) ( COOH ) and its fully basic form CH 2 ( NH 2 ) ( COO − ) is CH 2 ( NH 3 + ) ( COOH ) + CH 2 ( NH 2 ) ( COO − ) ⇌ 2 CH 2 ( NH 3 + ) ( COO − ) Use the data in Table 5.1 to determine the equilibrium constant for this reaction. What does your answer imply about the relative amount of the zwitterion in solution?
The formation of zwitterionic glycine, CH 2 ( NH 3 + ) ( COO − ) , from its fully acid form CH 2 ( NH 3 + ) ( COOH ) and its fully basic form CH 2 ( NH 2 ) ( COO − ) is CH 2 ( NH 3 + ) ( COOH ) + CH 2 ( NH 2 ) ( COO − ) ⇌ 2 CH 2 ( NH 3 + ) ( COO − ) Use the data in Table 5.1 to determine the equilibrium constant for this reaction. What does your answer imply about the relative amount of the zwitterion in solution?
Solution Summary: The author states that the equilibrium constant for the given reaction of glycine solution is 6.48times 10-3.
Use the data in Table
5.1
to determine the equilibrium constant for this reaction. What does your answer imply about the relative amount of the zwitterion in solution?
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Chapter 5 Solutions
Student Solutions Manual for Ball's Physical Chemistry, 2nd
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