PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
2nd Edition
ISBN: 9781266811852
Author: SMITH
Publisher: MCG
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Chapter 5, Problem 5.42UKC
Interpretation Introduction
Interpretation:
The chemical equation for the given reaction in the molecular art has to be written.
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Answer
2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton
transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted
without ambiguity.
a.
CH3
Ph
OEt
هد
Ph
CH3
Hint: the species on the left is an ynolate, which behaves a lot like an enolate.
b.
CH3
H3C
CH3
CH3
H3C
an unexpected product,
containing a single 9-
membered ring
the expected product,
containing two fused rings
H3C-I
(H3C)2CuLi
an enolate
Chapter 5 Solutions
PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
Ch. 5.1 - Use the molecular art to identify the process as a...Ch. 5.1 - Use the molecular at to identify the process as a...Ch. 5.1 - Prob. 5.3PCh. 5.1 - Prob. 5.4PCh. 5.1 - Write a chemical equation from the following...Ch. 5.2 - Prob. 5.6PCh. 5.2 - Prob. 5.7PCh. 5.2 - Prob. 5.8PCh. 5.2 - Prob. 5.9PCh. 5.2 - Prob. 5.10P
Ch. 5.3 - Prob. 5.11PCh. 5.3 - Prob. 5.12PCh. 5.3 - How many molecules are contained in each of the...Ch. 5.3 - Prob. 5.14PCh. 5.4 - Prob. 5.15PCh. 5.4 - Prob. 5.16PCh. 5.4 - Prob. 5.18PCh. 5.4 - Prob. 5.19PCh. 5.5 - Use the balanced equation for the reaction of N2...Ch. 5.5 - Prob. 5.21PCh. 5.6 - Using the balanced equation for fermentation...Ch. 5.6 - Prob. 5.23PCh. 5.6 - Prob. 5.24PCh. 5.6 - Prob. 5.25PCh. 5.7 - Prob. 5.26PCh. 5.7 - Prob. 5.27PCh. 5.7 - Prob. 5.28PCh. 5.7 - Early pacemakers generated an electrical impulse...Ch. 5.8 - Prob. 5.30PCh. 5.8 - Prob. 5.31PCh. 5.8 - Prob. 5.32PCh. 5.8 - Prob. 5.33PCh. 5.9 - Prob. 5.34PCh. 5.9 - Prob. 5.35PCh. 5.9 - Prob. 5.36PCh. 5.10 - Prob. 5.37PCh. 5.10 - In which direction is the equilibrium shifted with...Ch. 5 - Use the molecular art to identify the process as a...Ch. 5 - Prob. 5.40UKCCh. 5 - Prob. 5.41UKCCh. 5 - Prob. 5.42UKCCh. 5 - Prob. 5.43UKCCh. 5 - Prob. 5.44UKCCh. 5 - Prob. 5.45UKCCh. 5 - Spinach, cabbage, and broccoli are excellent...Ch. 5 - Prob. 5.47UKCCh. 5 - Prob. 5.48UKCCh. 5 - Prob. 5.49UKCCh. 5 - Rechargeable nickelcadmium batteries are used in...Ch. 5 - Prob. 5.51UKCCh. 5 - Prob. 5.52UKCCh. 5 - Prob. 5.53UKCCh. 5 - Prob. 5.54UKCCh. 5 - Prob. 5.55APCh. 5 - Prob. 5.56APCh. 5 - Prob. 5.57APCh. 5 - Prob. 5.58APCh. 5 - Prob. 5.59APCh. 5 - Prob. 5.60APCh. 5 - Prob. 5.61APCh. 5 - Prob. 5.62APCh. 5 - Prob. 5.63APCh. 5 - Consider the reaction, 2 NO + 2 CO N2 + 2 CO2....Ch. 5 - Prob. 5.65APCh. 5 - Prob. 5.66APCh. 5 - Prob. 5.67APCh. 5 - Prob. 5.68APCh. 5 - Prob. 5.69APCh. 5 - Prob. 5.70APCh. 5 - Prob. 5.71APCh. 5 - Prob. 5.72APCh. 5 - Prob. 5.73APCh. 5 - Prob. 5.74APCh. 5 - Prob. 5.75APCh. 5 - Prob. 5.76APCh. 5 - Prob. 5.77APCh. 5 - Prob. 5.78APCh. 5 - Prob. 5.79APCh. 5 - Prob. 5.80APCh. 5 - Prob. 5.81APCh. 5 - Prob. 5.82APCh. 5 - Prob. 5.83APCh. 5 - Prob. 5.84APCh. 5 - Prob. 5.85APCh. 5 - Prob. 5.86APCh. 5 - Prob. 5.87APCh. 5 - Prob. 5.88APCh. 5 - Prob. 5.89APCh. 5 - Prob. 5.90APCh. 5 - Prob. 5.91APCh. 5 - Prob. 5.92APCh. 5 - Prob. 5.93APCh. 5 - Prob. 5.94APCh. 5 - Prob. 5.95APCh. 5 - Prob. 5.96APCh. 5 - Prob. 5.97APCh. 5 - Prob. 5.98APCh. 5 - Prob. 5.99APCh. 5 - Prob. 5.100APCh. 5 - Prob. 5.101APCh. 5 - Prob. 5.102APCh. 5 - Prob. 5.103CP
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