The relationship between the two compounds in the given pair of compounds has to be determined. Concept Introduction: The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer. The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space. Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite. Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances. Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center. An achiral carbon is a carbon having two or more identical groups around it.

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Answer 1

Question

Chapter 5, Problem 53PP

(a)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

(b)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(c)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

(d)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

(e)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

(f)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

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Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: 0.2 mol of KOH is added to 1.0 L of a 0.5 M HF solution. bases: Х other: ☐ acids: 0.10 mol of HI is added to 1.0 L of a solution that is 1.4M in both HF and NaF. bases: other: ☐ 0,0,... ด ? 18 Ar

Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that NH3 is a weak base. acids: ☐ 1.8 mol of HCl is added to 1.0 L of a 1.0M NH3 bases: ☐ solution. other: ☐ 0.18 mol of HNO3 is added to 1.0 L of a solution that is 1.4M in both NH3 and NH₁Br. acids: bases: ☐ other: ☐ 0,0,... ? 000 18 Ar B 1

Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NH3 (g) = N2 (g) +3H₂ —N2 (g) AGº = 34. kJ Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NH 3 tend to rise or fall? ☐ x10 fall Х Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH 3 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no atm 00. 18 Ar 무ㅎ ?

Answer 2

Question

Chapter 5, Problem 53PP

(a)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

(b)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(c)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

(d)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

(e)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

(f)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

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Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 5, Problem 53PP

(a)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

(b)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(c)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

(d)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

(e)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

(f)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 5, Problem 53PP

(a)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

(b)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(c)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

(d)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

(e)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

(f)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 5, Problem 53PP

(a)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

(b)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

(c)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

(d)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

(e)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

(f)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

Answer 6

Chapter 5, Problem 53PP

(a)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

Answer 7

Chapter 5, Problem 53PP

(a)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

Answer 8

(b)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 9

(b)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Answer 10

(c)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Answer 11

(c)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Answer 12

(d)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Answer 13

(d)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

Cis–trans isomerism (or) geometric isomerism or configurational isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Answer 14

(e)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

Answer 15

(e)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

Answer 16

(f)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

Answer 17

(f)

Interpretation Introduction

Interpretation: The relationship between the two compounds in the given pair of compounds has to be determined.

Concept Introduction:

The stereoisomerism is the arrangement of atoms in molecules whose connectivity remains the same but their arrangement in different in each isomer.

The two molecules are described as stereoisomers if they are made of the same atoms connected in the same sequence, but the atoms are positions differently in space.

Enantiomers: These are the structures of compounds in which the configuration of all the Enantiomers: These are stereoisomers that are not superimposable mirror images of each other and the configurations at all stereo genic centers are exactly opposite.

Diastereomers: These are stereoisomers that are not enantiomers of one another. They have different physical properties so that they are viewed as different chemical substances.

Chiral center: A chiral center is defined as the tetrahedral carbon atom in an organic molecule that is connected to four non-identical groups/substituents. It is sometimes known as a stereo genic center.

An achiral carbon is a carbon having two or more identical groups around it.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 5.1 - In the following compound, identify each unit...Ch. 5.1 - Prob. 2CC Ch. 5.1 - Prob. 3CC Ch. 5.2 - Prob. 1LTS Ch. 5.2 - Prob. 4PTS Ch. 5.2 - Prob. 5ATS Ch. 5.2 - Prob. 6ATS Ch. 5.2 - Prob. 2LTS Ch. 5.2 - Prob. 7PTS Ch. 5.2 - Prob. 8ATS

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