Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 5, Problem 5.39E

The bisulfate (or hydrogen sulfate) anion, HSO 4 , is a weak acid. The equilibrium constant for the aqueous acid reaction

HSO 4 ( aq ) H + ( aq ) + SO 4 2 ( aq ) is 1.2 × 10 2 .

(a) Calculate Δ G ° for this equilibrium. Assume a temperature of 25.0 ° C .

(b) At low concentrations, activity coefficients are approximately 1 and the activity of a dissolved solute equals its molality. Determine the equilibrium molalities of a 0.010 -molal solution of sodium hydrogen sulfate.

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Chapter 5 Solutions

Physical Chemistry

Ch. 5 - 5.11. Determine the numerical value of Q for the...Ch. 5 - 5.12. True or false: If all the partial pressures...Ch. 5 - For the reaction 2SO3(g)2SO2(g)+O2(g) when 2mol of...Ch. 5 - 5.14. Determine and for the following reaction at...Ch. 5 - 5.15. Consider the reaction If the partial...Ch. 5 - 5.16. In atmospheric chemistry, the following...Ch. 5 - Prob. 5.17ECh. 5 - 5.18. Hydrogen cyanide can isomerize to hydrogen...Ch. 5 - 5.19. Assume that a reaction exists such that...Ch. 5 - Prob. 5.20ECh. 5 - 5.21. Show that if the coefficients of a balanced...Ch. 5 - 5.22. True or false: If for a gas-phase reaction,...Ch. 5 - 5.23. The balanced chemical reaction for the...Ch. 5 - The answers in exercise 5.23 should show that...Ch. 5 - At a high enough temperature, the equilibrium...Ch. 5 - Prob. 5.26ECh. 5 - 5.27. Nitrogen dioxide,, dimerizes easily to form...Ch. 5 - 5.28. Another nitrogen-oxygen reaction of some...Ch. 5 - Prob. 5.29ECh. 5 - Prob. 5.30ECh. 5 - Prob. 5.31ECh. 5 - 5.32. For the reaction . (a) Using in Appendix...Ch. 5 - 5.33. Use the data in Appendix to calculate ...Ch. 5 - 5.34. The of diamond, a crystalline form of...Ch. 5 - 5.35. The densities of graphite and diamond are ...Ch. 5 - Buckminsterfullerene, C60, is a spherical molecule...Ch. 5 - Prob. 5.37ECh. 5 - At what pressure does H2O have an activity of...Ch. 5 - The bisulfate or hydrogen sulfate anion, HSO4, is...Ch. 5 - Prob. 5.40ECh. 5 - Write the equilibrium constant expression for each...Ch. 5 - Prob. 5.42ECh. 5 - For the given chemical equilibrium, these data are...Ch. 5 - Biological standard states include specifying a...Ch. 5 - a At 25.0C, Kw for the autoionization of water is...Ch. 5 - 5.46. For a reaction whose standard enthalpy...Ch. 5 - 5.47. For the reaction and . Estimate for this...Ch. 5 - 5.48. The isotope exchange reaction has an...Ch. 5 - 5.49. Consider the following equilibrium: What...Ch. 5 - 5.50. For the equilibrium Equilibrium partial...Ch. 5 - The decomposition of NaHCO3, used in kitchens to...Ch. 5 - 5.52. For the equilibrium at,. In a flask, of...Ch. 5 - Prob. 5.53ECh. 5 - 5.54. For the reaction The equilibrium...Ch. 5 - Prob. 5.55ECh. 5 - 5.56. Of the amino acids listed in Table , which...Ch. 5 - 5.57. Determine the concentration of the three...Ch. 5 - 5.58. The formation of zwitterionic glycine, ,...Ch. 5 - 5.59. Monosodium glutamate, or MSG, is the sodium...Ch. 5 - Prob. 5.60ECh. 5 - Consider the balanced chemical reaction...Ch. 5 - For the gas-phase reaction 2H2+O22H2O rxnG is...Ch. 5 - Prob. 5.63ECh. 5 - Prob. 5.64E
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