General, Organic, and Biological Chemistry Seventh Edition
7th Edition
ISBN: 9781305767867
Author: H. Stephan Stoker
Publisher: Cengage Learning
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Chapter 5, Problem 5.30EP
(a)
Interpretation Introduction
Interpretation:
The total number of electron dots that is present in
Concept Introduction:
Lewis structure clearly depicts the bonding and nonbonding electrons in the atom. This is only partially useful for the molecule that contains one or more multiple bonds and when coordinate covalent bond is present in the molecule. For drawing Lewis structure a systematic procedure is followed. They are,
- The total number of valence electrons that is present in molecule is calculated by adding all the valence electrons of the atoms present in the molecule.
- The chemical symbols for the atoms that is present in the molecule is written in the order that they are bonded. After this a single covalent bond is placed between each atoms as two electrons.
- The nonbonding electrons are added to each atom that is bonded to the central atom so that it contains octet of electrons. For hydrogen alone the “octet” is only two electrons.
- The remaining electrons has to be placed on the central atom in the structure.
- If there is no octet of electrons present in the central atom, then use one or more pairs of nonbonding electrons that is bonded to the central atom to form double or triple bonds.
- The total number of electrons has to be counted and it has to be confirmed whether the count is same as that of the number of valence electrons that is available for bonding.
(b)
Interpretation Introduction
Interpretation:
The total number of electron dots that is present in
Concept Introduction:
Lewis structure clearly depicts the bonding and nonbonding electrons in the atom. This is only partially useful for the molecule that contains one or more multiple bonds and when coordinate covalent bond is present in the molecule. For drawing Lewis structure a systematic procedure is followed. They are,
- The total number of valence electrons that is present in molecule is calculated by adding all the valence electrons of the atoms present in the molecule.
- The chemical symbols for the atoms that is present in the molecule is written in the order that they are bonded. After this a single covalent bond is placed between each atoms as two electrons.
- The nonbonding electrons are added to each atom that is bonded to the central atom so that it contains octet of electrons. For hydrogen alone the “octet” is only two electrons.
- The remaining electrons has to be placed on the central atom in the structure.
- If there is no octet of electrons present in the central atom, then use one or more pairs of nonbonding electrons that is bonded to the central atom to form double or triple bonds.
- The total number of electrons has to be counted and it has to be confirmed whether the count is same as that of the number of valence electrons that is available for bonding.
(c)
Interpretation Introduction
Interpretation:
The total number of electron dots that is present in
Concept Introduction:
Lewis structure clearly depicts the bonding and nonbonding electrons in the atom. This is only partially useful for the molecule that contains one or more multiple bonds and when coordinate covalent bond is present in the molecule. For drawing Lewis structure a systematic procedure is followed. They are,
- The total number of valence electrons that is present in molecule is calculated by adding all the valence electrons of the atoms present in the molecule.
- The chemical symbols for the atoms that is present in the molecule is written in the order that they are bonded. After this a single covalent bond is placed between each atoms as two electrons.
- The nonbonding electrons are added to each atom that is bonded to the central atom so that it contains octet of electrons. For hydrogen alone the “octet” is only two electrons.
- The remaining electrons has to be placed on the central atom in the structure.
- If there is no octet of electrons present in the central atom, then use one or more pairs of nonbonding electrons that is bonded to the central atom to form double or triple bonds.
- The total number of electrons has to be counted and it has to be confirmed whether the count is same as that of the number of valence electrons that is available for bonding.
(b)
Interpretation Introduction
Interpretation:
The total number of electron dots that is present in
Concept Introduction:
Lewis structure clearly depicts the bonding and nonbonding electrons in the atom. This is only partially useful for the molecule that contains one or more multiple bonds and when coordinate covalent bond is present in the molecule. For drawing Lewis structure a systematic procedure is followed. They are,
- The total number of valence electrons that is present in molecule is calculated by adding all the valence electrons of the atoms present in the molecule.
- The chemical symbols for the atoms that is present in the molecule is written in the order that they are bonded. After this a single covalent bond is placed between each atoms as two electrons.
- The nonbonding electrons are added to each atom that is bonded to the central atom so that it contains octet of electrons. For hydrogen alone the “octet” is only two electrons.
- The remaining electrons has to be placed on the central atom in the structure.
- If there is no octet of electrons present in the central atom, then use one or more pairs of nonbonding electrons that is bonded to the central atom to form double or triple bonds.
- The total number of electrons has to be counted and it has to be confirmed whether the count is same as that of the number of valence electrons that is available for bonding.
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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
хе
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Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
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Predict the major products of this organic reaction:
H
OH
1. LiAlH4
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?
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
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G
C
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For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first
stable product you expect to form in solution.
NH2
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?
Will the first product that forms in this reaction
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No
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Yes
No
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Chapter 5 Solutions
General, Organic, and Biological Chemistry Seventh Edition
Ch. 5.1 - Covalent bond formation most often involves...Ch. 5.1 - Which of the following concepts is closely...Ch. 5.1 - Prob. 3QQCh. 5.1 - Prob. 4QQCh. 5.2 - Prob. 1QQCh. 5.2 - Prob. 2QQCh. 5.2 - Prob. 3QQCh. 5.2 - Prob. 4QQCh. 5.2 - Prob. 5QQCh. 5.2 - Prob. 6QQ
Ch. 5.3 - Prob. 1QQCh. 5.3 - Prob. 2QQCh. 5.3 - Prob. 3QQCh. 5.3 - Prob. 4QQCh. 5.3 - Prob. 5QQCh. 5.4 - Prob. 1QQCh. 5.4 - Prob. 2QQCh. 5.4 - Prob. 3QQCh. 5.5 - Which of the following is an incorrect statement...Ch. 5.5 - Prob. 2QQCh. 5.5 - Prob. 3QQCh. 5.6 - Prob. 1QQCh. 5.6 - Prob. 2QQCh. 5.6 - Prob. 3QQCh. 5.6 - Prob. 4QQCh. 5.6 - Prob. 5QQCh. 5.7 - Prob. 1QQCh. 5.7 - Prob. 2QQCh. 5.7 - Prob. 3QQCh. 5.8 - Prob. 1QQCh. 5.8 - In VSEPR theory, an angular molecular geometry is...Ch. 5.8 - Prob. 3QQCh. 5.8 - Prob. 4QQCh. 5.8 - Prob. 5QQCh. 5.9 - Prob. 1QQCh. 5.9 - Prob. 2QQCh. 5.9 - Prob. 3QQCh. 5.9 - Prob. 4QQCh. 5.10 - Prob. 1QQCh. 5.10 - Prob. 2QQCh. 5.10 - Prob. 3QQCh. 5.10 - As the difference in electronegativity between two...Ch. 5.10 - Prob. 5QQCh. 5.10 - Prob. 6QQCh. 5.11 - Prob. 1QQCh. 5.11 - Prob. 2QQCh. 5.11 - Prob. 3QQCh. 5.11 - Prob. 4QQCh. 5.11 - Prob. 5QQCh. 5.12 - Prob. 1QQCh. 5.12 - Prob. 2QQCh. 5.12 - Prob. 3QQCh. 5.12 - Prob. 4QQCh. 5.12 - Prob. 5QQCh. 5.12 - Prob. 6QQCh. 5 - Contrast the types of elements involved in ionic...Ch. 5 - Contrast the mechanisms by which ionic and...Ch. 5 - Prob. 5.3EPCh. 5 - Prob. 5.4EPCh. 5 - Indicate whether or not covalent bond formation is...Ch. 5 - Indicate whether or not covalent bond formation is...Ch. 5 - Draw Lewis structures to illustrate the covalent...Ch. 5 - Draw Lewis structures to illustrate the covalent...Ch. 5 - How many nonbonding electron pairs are present in...Ch. 5 - How many nonbonding electron pairs are present in...Ch. 5 - The component elements for four binary molecular...Ch. 5 - The component elements for four binary molecular...Ch. 5 - Specify the number of single, double, and triple...Ch. 5 - Specify the number of single, double, and triple...Ch. 5 - Convert each of the Lewis structures in Problem...Ch. 5 - Convert each of the Lewis structures in Problem...Ch. 5 - Prob. 5.17EPCh. 5 - Prob. 5.18EPCh. 5 - Prob. 5.19EPCh. 5 - Identify the Period 3 nonmetal that would normally...Ch. 5 - How many valence electrons do atoms possess that...Ch. 5 - Prob. 5.22EPCh. 5 - What aspect of the following Lewis structure...Ch. 5 - What aspect of the following Lewis structure...Ch. 5 - Identify the coordinate covalent bond(s) present,...Ch. 5 - Identify the coordinate covalent bond(s) present,...Ch. 5 - Without actually drawing the Lewis structure,...Ch. 5 - Without actually drawing the Lewis structure,...Ch. 5 - Prob. 5.29EPCh. 5 - Prob. 5.30EPCh. 5 - Draw the Lewis structure for each of the molecules...Ch. 5 - Draw the Lewis structure for each of the molecules...Ch. 5 - Draw Lewis structures to illustrate the bonding in...Ch. 5 - Draw Lewis structures to illustrate the bonding in...Ch. 5 - How many electron dots should appear in the Lewis...Ch. 5 - Prob. 5.36EPCh. 5 - Draw Lewis structures for the following polyatomic...Ch. 5 - Draw Lewis structures for the following polyatomic...Ch. 5 - Draw Lewis structures for the following compounds...Ch. 5 - Draw Lewis structures for the following compounds...Ch. 5 - Draw Lewis structures for the following molecules...Ch. 5 - Draw Lewis structures for the following molecules...Ch. 5 - In which of the following pairs of diatomic...Ch. 5 - In which of the following pairs of diatomic...Ch. 5 - Prob. 5.45EPCh. 5 - What is the molecular geometry associated with...Ch. 5 - Specify the molecular geometry of each of the...Ch. 5 - Specify the molecular geometry of each of the...Ch. 5 - Prob. 5.49EPCh. 5 - Prob. 5.50EPCh. 5 - Prob. 5.51EPCh. 5 - Prob. 5.52EPCh. 5 - Prob. 5.53EPCh. 5 - Prob. 5.54EPCh. 5 - Using VSEPR theory, predict the molecular geometry...Ch. 5 - Using VSEPR theory, predict the molecular geometry...Ch. 5 - Prob. 5.57EPCh. 5 - Specify both the VSEPR electron group geometry...Ch. 5 - Prob. 5.59EPCh. 5 - Prob. 5.60EPCh. 5 - Using a periodic table, but not a table of...Ch. 5 - Using a periodic table, but not a table of...Ch. 5 - Prob. 5.63EPCh. 5 - Prob. 5.64EPCh. 5 - Place + above the atom that is relatively positive...Ch. 5 - Place + above the atom that is relatively positive...Ch. 5 - Rank the following bonds in order of increasing...Ch. 5 - Rank the following bonds in order of increasing...Ch. 5 - Classify each of the following bonds as nonpolar...Ch. 5 - Classify each of the following bonds as nonpolar...Ch. 5 - Prob. 5.71EPCh. 5 - Prob. 5.72EPCh. 5 - Fill in the blanks in each line of the following...Ch. 5 - Fill in the blanks in each line of the following...Ch. 5 - Four hypothetical elements, A, B, C, and D, have...Ch. 5 - Four hypothetical elements, A, B, C, and D, have...Ch. 5 - Indicate whether each of the following...Ch. 5 - Prob. 5.78EPCh. 5 - Indicate whether each of the following triatomic...Ch. 5 - Indicate whether each of the following triatomic...Ch. 5 - Indicate whether each of the following molecules...Ch. 5 - Indicate whether each of the following molecules...Ch. 5 - Prob. 5.83EPCh. 5 - Prob. 5.84EPCh. 5 - Indicate which molecule in each of the following...Ch. 5 - Indicate which molecule in each of the following...Ch. 5 - Successive substitution of F atoms for H atoms in...Ch. 5 - Successive substitution of F atoms for H atoms in...Ch. 5 - Prob. 5.89EPCh. 5 - Indicate whether or not each of the following...Ch. 5 - Prob. 5.91EPCh. 5 - Name the following binary molecular compounds? a....Ch. 5 - Prob. 5.93EPCh. 5 - Prob. 5.94EPCh. 5 - Prob. 5.95EPCh. 5 - Prob. 5.96EPCh. 5 - Prob. 5.97EPCh. 5 - Prob. 5.98EPCh. 5 - Write chemical formulas for the following binary...Ch. 5 - Write chemical formulas for the following binary...Ch. 5 - Prob. 5.101EPCh. 5 - Prob. 5.102EPCh. 5 - The compound whose molecles contain one atom of C...Ch. 5 - Prob. 5.104EPCh. 5 - Prob. 5.105EPCh. 5 - The correct name for the compound K2SO4 is not...Ch. 5 - Prob. 5.107EPCh. 5 - Prob. 5.108EP
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