Organic Chemistry: Principles And Mechanisms
Organic Chemistry: Principles And Mechanisms
2nd Edition
ISBN: 9780393630756
Author: KARTY, Joel
Publisher: W.w. Norton & Company,
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Concept explainers

Basics in Organic Reactions Mechanisms
In organic chemistry, the mechanism of an organic reaction is defined as a complete step-by-step explanation of how a reaction of organic compounds happens. A completely detailed mechanism would relate the first structure of the reactants with the last s…
Heterolytic Bond Breaking
Heterolytic bond breaking is also known as heterolysis or heterolytic fission or ionic fission. It is defined as breaking of a covalent bond between two different atoms in which one atom gains both of the shared pair of electrons. The atom that gains bo…
Polar Aprotic Solvent
Solvents that are chemically polar in nature and are not capable of hydrogen bonding (implying that a hydrogen atom directly linked with an electronegative atom is not found) are referred to as polar aprotic solvents. Some commonly used polar aprotic sol…
Oxygen Nucleophiles
Oxygen being an electron rich species with a lone pair electron, can act as a good nucleophile. Typically, oxygen nucleophiles can be found in these compounds- water, hydroxides and alcohols.
Carbon Nucleophiles
We are aware that carbon belongs to group IV and hence does not possess any lone pair of electrons. Implying that neutral carbon is not a nucleophile then how is carbon going to be nucleophilic? The answer to this is that when a carbon atom is attached t…
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Chapter 5, Problem 5.2YT
Interpretation Introduction

Interpretation:

Constructing a molecular modeling kit of a molecule for both, the original and its mirror image to verify whether a molecule is superimposable or not.

Concept introduction:

An atom and its mirror image are directly opposite to each other on opposite sides of the mirror. An atom and its mirror image are identical distances away from the mirror. When the mirror is perpendicular to the plane of the page, dash–wedge notation in the mirror image is identical to that in the original molecule. In any molecule, when the mirror image of the molecule is same and indistinguishable from the original, it is superimposable. In a tetrahedral molecule, when two atoms are same, then the molecules are superimposable.

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Chapter 5 Solutions

Organic Chemistry: Principles And Mechanisms

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