Chemistry - Modified MasteringChemistry
7th Edition
ISBN: 9780133892321
Author: McMurry
Publisher: PEARSON
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Chapter 5, Problem 5.29CP
What atom has the following orbital-filling diagram?
[Ar]
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
2200
2000
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1400
1200
1000
800
Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 5 Solutions
Chemistry - Modified MasteringChemistry
Ch. 5 - Prob. 5.1PCh. 5 - Conceptual APPLY 5.2 Two electromagnetic waves are...Ch. 5 - PRACTICE 5.3 The biological effects of a given...Ch. 5 - Prob. 5.4ACh. 5 - Prob. 5.5PCh. 5 - Conceptual APPLY 5.6 Compare the two elements Rb...Ch. 5 - PRACTICE 5.7 The Balmer equation can be extended...Ch. 5 - APPLY 5.8 (a) What is the longest-wavelength line...Ch. 5 - Prob. 5.9PCh. 5 - Prob. 5.10A
Ch. 5 - Prob. 5.11PCh. 5 - APPLY 5.10 Extend Table 5.2 to show allowed...Ch. 5 - Conceptual PRACTICE 5.13 Give a possible...Ch. 5 - Conceptual APPLY 5.14 How many nodal planes...Ch. 5 - Prob. 5.15PCh. 5 - Conceptual APPLY 5.16 Identify the atoms with the...Ch. 5 - Prob. 5.17PCh. 5 - APPLY 5.18 Predict which bond length will be the...Ch. 5 - PROBLEM 5.19 Mercury vapor is contained inside the...Ch. 5 - PROBLEM 5.20 When electricity is used to add...Ch. 5 - Prob. 5.21PCh. 5 - PROBLEM 5.22 Three different wavelengths in the...Ch. 5 - Prob. 5.23PCh. 5 - Two electromagnetic waves are represented below....Ch. 5 - The following diagram shows the energy levels of...Ch. 5 - Identify each of the following orbitals, and give...Ch. 5 - Where on the blank outline of the periodic table...Ch. 5 - One of the elements shown on the following...Ch. 5 - What atom has the following orbital-filling...Ch. 5 - The following orbital-filling diagram represents...Ch. 5 - Prob. 5.31CPCh. 5 - Which has the higher frequency, red light or...Ch. 5 - Prob. 5.33SPCh. 5 - The Hubble Space Telescope detects electromagnetic...Ch. 5 - Prob. 5.35SPCh. 5 - Prob. 5.36SPCh. 5 - Prob. 5.37SPCh. 5 - Prob. 5.38SPCh. 5 - Prob. 5.39SPCh. 5 - Prob. 5.40SPCh. 5 - Prob. 5.41SPCh. 5 - Prob. 5.42SPCh. 5 - Prob. 5.43SPCh. 5 - Prob. 5.44SPCh. 5 - Prob. 5.45SPCh. 5 - Prob. 5.46SPCh. 5 - Prob. 5.47SPCh. 5 - Prob. 5.48SPCh. 5 - Prob. 5.49SPCh. 5 - Prob. 5.50SPCh. 5 - Prob. 5.51SPCh. 5 - Prob. 5.52SPCh. 5 - Prob. 5.53SPCh. 5 - Prob. 5.54SPCh. 5 - Prob. 5.55SPCh. 5 - Spectroscopy is a technique that uses the...Ch. 5 - Prob. 5.57SPCh. 5 - Prob. 5.58SPCh. 5 - Prob. 5.59SPCh. 5 - Prob. 5.60SPCh. 5 - Prob. 5.61SPCh. 5 - Prob. 5.62SPCh. 5 - What velocity would an electron ( mass=9.111031...Ch. 5 - Prob. 5.64SPCh. 5 - Prob. 5.65SPCh. 5 - Prob. 5.66SPCh. 5 - Prob. 5.67SPCh. 5 - Prob. 5.68SPCh. 5 - Prob. 5.69SPCh. 5 - Prob. 5.70SPCh. 5 - Prob. 5.71SPCh. 5 - Prob. 5.72SPCh. 5 - Prob. 5.73SPCh. 5 - Prob. 5.74SPCh. 5 - Prob. 5.75SPCh. 5 - Prob. 5.76SPCh. 5 - Prob. 5.77SPCh. 5 - Prob. 5.78SPCh. 5 - Prob. 5.79SPCh. 5 - Prob. 5.80SPCh. 5 - Prob. 5.81SPCh. 5 - Prob. 5.82SPCh. 5 - Prob. 5.83SPCh. 5 - Prob. 5.84SPCh. 5 - Prob. 5.85SPCh. 5 - Prob. 5.86SPCh. 5 - Prob. 5.87SPCh. 5 - Prob. 5.88SPCh. 5 - Prob. 5.89SPCh. 5 - Prob. 5.90SPCh. 5 - Prob. 5.91SPCh. 5 - Prob. 5.92SPCh. 5 - Prob. 5.93SPCh. 5 - Prob. 5.94SPCh. 5 - Prob. 5.95SPCh. 5 - Prob. 5.96SPCh. 5 - Draw orbital-filling diagrams for atoms with the...Ch. 5 - Prob. 5.98SPCh. 5 - Prob. 5.99SPCh. 5 - Prob. 5.100SPCh. 5 - Prob. 5.101SPCh. 5 - Prob. 5.102SPCh. 5 - Prob. 5.103SPCh. 5 - Prob. 5.104SPCh. 5 - Prob. 5.105SPCh. 5 - Prob. 5.106SPCh. 5 - Prob. 5.107SPCh. 5 - Prob. 5.108SPCh. 5 - Prob. 5.109SPCh. 5 - What is the expected ground-state electron...Ch. 5 - What is the atomic number and expected...Ch. 5 - Prob. 5.112CPCh. 5 - Prob. 5.113CPCh. 5 - Prob. 5.114CPCh. 5 - 5.115 Lines in a certain series of the hydrogen...Ch. 5 - Prob. 5.116CPCh. 5 - Prob. 5.117CPCh. 5 - Prob. 5.118CPCh. 5 - Prob. 5.119CPCh. 5 - Prob. 5.120CPCh. 5 - Prob. 5.121CPCh. 5 - Prob. 5.122CPCh. 5 - Prob. 5.123CPCh. 5 - Prob. 5.124CPCh. 5 - Prob. 5.125CPCh. 5 - Prob. 5.126CPCh. 5 - Prob. 5.127CPCh. 5 - Prob. 5.128CPCh. 5 - Prob. 5.129CPCh. 5 - Prob. 5.130CPCh. 5 - Prob. 5.131CPCh. 5 - Prob. 5.132CPCh. 5 - Prob. 5.133CPCh. 5 - Prob. 5.134CPCh. 5 - Prob. 5.135CPCh. 5 - Prob. 5.136CPCh. 5 - Prob. 5.137CPCh. 5 - Prob. 5.138CPCh. 5 - Prob. 5.139MPCh. 5 - Prob. 5.140MPCh. 5 - Prob. 5.141MP
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