The difference in the behavior of the sample of gas and liquid should be determined if the sample is transferred from one container to a large one. Concept introduction: Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another. For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

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Answer 1

Question

Definition Definition Substance that constitutes everything in the universe. Matter consists of atoms, which are composed of electrons, protons, and neutrons. Different atoms combine together to give rise to molecules that act as a foundation for all kinds of substances. There are five states of matter based on their energies of attraction: solid, liquid, gases, plasma, and BEC (Bose-Einstein condensates).

Chapter 5, Problem 5.1P

(a)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is transferred from one container to a large one.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(a)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. Due to high kinetic energy, the particles can move randomly so they occupy the volume of the container. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

(b)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is heated in an expandable container without any change in the state of matter.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(b)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the container will increase whereas the volume of a sample with liquid does not change on heating.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the gas will increase whereas the volume of a sample with liquid does not change on heating.

(c)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is placed in a cylinder with a piston and external force is applied.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(c)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant whereas the volume of the gas is reduced.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces and lesser intermolecular space between particles compared to gases. When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant as liquids are not compressible whereas the volume of the gas is reduced because gases are highly compressible due to large intermolecular distance.

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Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

Answer 2

Question

Definition Definition Substance that constitutes everything in the universe. Matter consists of atoms, which are composed of electrons, protons, and neutrons. Different atoms combine together to give rise to molecules that act as a foundation for all kinds of substances. There are five states of matter based on their energies of attraction: solid, liquid, gases, plasma, and BEC (Bose-Einstein condensates).

Chapter 5, Problem 5.1P

(a)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is transferred from one container to a large one.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(a)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. Due to high kinetic energy, the particles can move randomly so they occupy the volume of the container. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

(b)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is heated in an expandable container without any change in the state of matter.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(b)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the container will increase whereas the volume of a sample with liquid does not change on heating.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the gas will increase whereas the volume of a sample with liquid does not change on heating.

(c)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is placed in a cylinder with a piston and external force is applied.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(c)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant whereas the volume of the gas is reduced.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces and lesser intermolecular space between particles compared to gases. When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant as liquids are not compressible whereas the volume of the gas is reduced because gases are highly compressible due to large intermolecular distance.

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Answer 3

Question

Definition Definition Substance that constitutes everything in the universe. Matter consists of atoms, which are composed of electrons, protons, and neutrons. Different atoms combine together to give rise to molecules that act as a foundation for all kinds of substances. There are five states of matter based on their energies of attraction: solid, liquid, gases, plasma, and BEC (Bose-Einstein condensates).

Chapter 5, Problem 5.1P

(a)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is transferred from one container to a large one.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(a)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. Due to high kinetic energy, the particles can move randomly so they occupy the volume of the container. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

(b)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is heated in an expandable container without any change in the state of matter.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(b)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the container will increase whereas the volume of a sample with liquid does not change on heating.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the gas will increase whereas the volume of a sample with liquid does not change on heating.

(c)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is placed in a cylinder with a piston and external force is applied.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(c)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant whereas the volume of the gas is reduced.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces and lesser intermolecular space between particles compared to gases. When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant as liquids are not compressible whereas the volume of the gas is reduced because gases are highly compressible due to large intermolecular distance.

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Answer 4

Question

Definition Definition Substance that constitutes everything in the universe. Matter consists of atoms, which are composed of electrons, protons, and neutrons. Different atoms combine together to give rise to molecules that act as a foundation for all kinds of substances. There are five states of matter based on their energies of attraction: solid, liquid, gases, plasma, and BEC (Bose-Einstein condensates).

Chapter 5, Problem 5.1P

(a)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is transferred from one container to a large one.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(a)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. Due to high kinetic energy, the particles can move randomly so they occupy the volume of the container. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

(b)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is heated in an expandable container without any change in the state of matter.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(b)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the container will increase whereas the volume of a sample with liquid does not change on heating.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the gas will increase whereas the volume of a sample with liquid does not change on heating.

(c)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is placed in a cylinder with a piston and external force is applied.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(c)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant whereas the volume of the gas is reduced.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces and lesser intermolecular space between particles compared to gases. When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant as liquids are not compressible whereas the volume of the gas is reduced because gases are highly compressible due to large intermolecular distance.

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Answer 5

Chapter 5, Problem 5.1P

(a)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is transferred from one container to a large one.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(a)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. Due to high kinetic energy, the particles can move randomly so they occupy the volume of the container. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

(b)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is heated in an expandable container without any change in the state of matter.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(b)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the container will increase whereas the volume of a sample with liquid does not change on heating.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the gas will increase whereas the volume of a sample with liquid does not change on heating.

(c)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is placed in a cylinder with a piston and external force is applied.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(c)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant whereas the volume of the gas is reduced.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces and lesser intermolecular space between particles compared to gases. When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant as liquids are not compressible whereas the volume of the gas is reduced because gases are highly compressible due to large intermolecular distance.

Answer 6

Chapter 5, Problem 5.1P

(a)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is transferred from one container to a large one.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(a)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. Due to high kinetic energy, the particles can move randomly so they occupy the volume of the container. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

Answer 7

Chapter 5, Problem 5.1P

(a)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is transferred from one container to a large one.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

Answer 8

(a)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

Answer 9

(a)

Expert Solution

Answer 10

(a)

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. Due to high kinetic energy, the particles can move randomly so they occupy the volume of the container. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is transferred from one container to a large one, the volume of the gas increases to the volume of the larger container whereas the volume of the liquid remains constant.

Answer 13

(b)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is heated in an expandable container without any change in the state of matter.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(b)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the container will increase whereas the volume of a sample with liquid does not change on heating.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the gas will increase whereas the volume of a sample with liquid does not change on heating.

Answer 14

(b)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is heated in an expandable container without any change in the state of matter.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

Answer 15

(b)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the container will increase whereas the volume of a sample with liquid does not change on heating.

Answer 16

(b)

Expert Solution

Answer 17

(b)

Expert Solution

Answer 18

Expert Solution

Answer 19

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces between particles compared to gases. When a sample of gas is heated in an expandable container without a change of physical state, then the volume of the gas will increase whereas the volume of a sample with liquid does not change on heating.

Answer 20

(c)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is placed in a cylinder with a piston and external force is applied.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

(c)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant whereas the volume of the gas is reduced.

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces and lesser intermolecular space between particles compared to gases. When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant as liquids are not compressible whereas the volume of the gas is reduced because gases are highly compressible due to large intermolecular distance.

Answer 21

(c)

Interpretation Introduction

Interpretation: The difference in the behavior of the sample of gas and liquid should be determined if the sample is placed in a cylinder with a piston and external force is applied.

Concept introduction:

Interconversion of physical states of matter refers to the application of temperature and pressure to change one physical state of matter into another.

For example, at high temperatures and at a certain pressure, solid changes to a liquid, and liquid changes to a gas.

Answer 22

(c)

Expert Solution

Answer to Problem 5.1P

When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant whereas the volume of the gas is reduced.

Answer 23

(c)

Expert Solution

Answer 24

(c)

Expert Solution

Answer 25

Expert Solution

Answer 26

Explanation of Solution

The gaseous state of matter has a large intermolecular distance between particles with the weakest intermolecular force between them. On the contrary, liquids have fixed volume due to stronger intermolecular forces and lesser intermolecular space between particles compared to gases. When a sample of gas is placed in a cylinder with a piston and external force is applied, the volume of the liquid remains constant as liquids are not compressible whereas the volume of the gas is reduced because gases are highly compressible due to large intermolecular distance.