EBK CHEMISTRY: ATOMS FIRST
3rd Edition
ISBN: 8220103675505
Author: Burdge
Publisher: YUZU
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Textbook Question
Chapter 5, Problem 5.128QP
The compound 2,3-dimercaptopropanol (HSCH2CHSHCH2OH), commonly known as British Anti-Lewisite (BAL), was developed during World War I as an antidote to arsenic-containing poison gas. (a) If each BAL molecule binds one arsenic (As) atom, how many As atoms can be removed by 1.0 g of BAL? (b) BAL can also be used to remove poisonous heavy metals like mercury (Hg) and lead (Pb). If each BAL binds one Hg atom, calculate the mass percent of Hg in a BAL-Hg complex. (An H atom is removed when a BAL molecule binds an Hg atom.)
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Decide whether these proposed Lewis structures are reasonable.
proposed Lewis structure
Yes.
Is the proposed Lewis structure reasonable?
Cl-
: 2:
:Z:
:Z:
N—N
: 0:
C C1:
O CO
No, it has the wrong number of valence electrons.
The correct number is: ☐
No, it has the right number of valence electrons but doesn't satisfy the
octet rule.
The symbols of the problem atoms are:* ☐
Yes.
No, it has the wrong number of valence electrons.
The correct number is: ☐
No, it has the right number of valence electrons but doesn't satisfy the
octet rule.
The symbols of the problem atoms are:* |
Yes.
No, it has the wrong number of valence electrons.
The correct number is:
No, it has the right number of valence electrons but doesn't satisfy the
octet rule.
The symbols of the problem atoms are:* |
If two or more atoms of the same element don't satisfy the octet rule, just enter the chemical symbol as many
times as necessary. For example, if two oxygen atoms don't satisfy the octet rule, enter "0,0".
☑
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.
reaction
observations
conclusions
ΔΗ is
(pick one)
A
This reaction is faster above 103. °C than
below.
AS is
(pick one)
ΔΗ is
(pick one)
B
This reaction is spontaneous only above
-9. °C.
AS is
(pick one)
ΔΗ is
(pick one)
C
The reverse of this reaction is always
spontaneous.
AS is
(pick one)
18
Ar
Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy
AS.
Note: if you have not been given enough information to decide a sign, select the "unknown" option.
reaction
observations
conclusions
A
The reverse of this reaction is always
spontaneous but proceeds slower at
temperatures below 41. °C.
ΔΗ is
(pick one)
AS is
(pick one)
ΔΗ is
(pick one)
B
This reaction is spontaneous except above
94. °C.
AS is
(pick one)
This reaction is always spontaneous, but
ΔΗ is
(pick one)
C
proceeds slower at temperatures below
−14. °C.
AS is
(pick one)
Х
00.
18
Ar
무ㅎ
B
1
1
Chapter 5 Solutions
EBK CHEMISTRY: ATOMS FIRST
Ch. 5.2 - Write Lewis dot symbols for (a) fluoride ion (F),...Ch. 5.2 - Write Lewis dot symbols for (a) Ca2+, (b) N3 and...Ch. 5.2 - Indicate the charge on each of the ions...Ch. 5.2 - Prob. 1PPCCh. 5.2 - Using only a periodic table, determine the correct...Ch. 5.2 - Using only a periodic table, determine the correct...Ch. 5.2 - Prob. 5.2.3SRCh. 5.2 - To which group does the element Y belong if the...Ch. 5.3 - Arrange MgO, CaO, and SrO in order of increasing...Ch. 5.3 - Prob. 2PPA
Ch. 5.3 - Arrange the compounds NaF, MgO, and AlN in order...Ch. 5.3 - Prob. 2PPCCh. 5.3 - Will the lattice energy of KF be larger or smaller...Ch. 5.3 - Lattice energies are graphed for three series of...Ch. 5.4 - Prob. 5.3WECh. 5.4 - Prob. 3PPACh. 5.4 - Prob. 3PPBCh. 5.4 - Prob. 3PPCCh. 5.4 - Prob. 5.4WECh. 5.4 - Prob. 4PPACh. 5.4 - Prob. 4PPBCh. 5.4 - Prob. 4PPCCh. 5.4 - Prob. 5.4.1SRCh. 5.4 - Prob. 5.4.2SRCh. 5.4 - Prob. 5.4.3SRCh. 5.4 - Prob. 5.4.4SRCh. 5.5 - Prob. 5.5WECh. 5.5 - Prob. 5PPACh. 5.5 - Draw (a) a space-filling molecular model of carbon...Ch. 5.5 - Prob. 5PPCCh. 5.5 - Prob. 5.6WECh. 5.5 - Prob. 6PPACh. 5.5 - Prob. 6PPBCh. 5.5 - Prob. 6PPCCh. 5.5 - Prob. 5.5.1SRCh. 5.5 - Prob. 5.5.2SRCh. 5.6 - Name the following binary molecular compounds: (a)...Ch. 5.6 - Prob. 7PPACh. 5.6 - Prob. 7PPBCh. 5.6 - Prob. 7PPCCh. 5.6 - Prob. 5.8WECh. 5.6 - Give the molecular formula for each of the...Ch. 5.6 - Prob. 8PPBCh. 5.6 - Draw a molecular model of sulfur trioxide.Ch. 5.6 - Prob. 5.6.1SRCh. 5.6 - Prob. 5.6.2SRCh. 5.6 - Prob. 5.6.3SRCh. 5.6 - What is the name of the compound shown? (a)...Ch. 5.7 - Prob. 5.9WECh. 5.7 - Name the following ionic compounds: (a) Na2SO4,...Ch. 5.7 - Prob. 9PPBCh. 5.7 - Prob. 9PPCCh. 5.7 - Name the following species: (a) BrO4, (b) HCO3,...Ch. 5.7 - Prob. 10PPACh. 5.7 - Prob. 10PPBCh. 5.7 - Prob. 10PPCCh. 5.7 - Prob. 5.11WECh. 5.7 - Prob. 11PPACh. 5.7 - Prob. 11PPBCh. 5.7 - Prob. 11PPCCh. 5.7 - Prob. 5.7.1SRCh. 5.7 - Prob. 5.7.2SRCh. 5.7 - What is the correct name of the compound Hg2CrO4?...Ch. 5.7 - What is the formula of the compound iron(III)...Ch. 5.8 - Calculate the molecular mass or the formula mass,...Ch. 5.8 - Calculate the molecular or formula mass of each of...Ch. 5.8 - Prob. 12PPBCh. 5.8 - Prob. 12PPCCh. 5.8 - Prob. 5.8.1SRCh. 5.8 - Determine the formula mass of calcium citrate...Ch. 5.8 - Prob. 5.8.3SRCh. 5.8 - Prob. 5.8.4SRCh. 5.8 - Prob. 5.8.5SRCh. 5.9 - Prob. 5.13WECh. 5.9 - Prob. 13PPACh. 5.9 - Prob. 13PPBCh. 5.9 - Prob. 13PPCCh. 5.9 - Prob. 5.9.1SRCh. 5.9 - Prob. 5.9.2SRCh. 5.10 - Prob. 5.14WECh. 5.10 - Prob. 14PPACh. 5.10 - Prob. 14PPBCh. 5.10 - Prob. 5.15WECh. 5.10 - Prob. 15PPACh. 5.10 - Prob. 15PPBCh. 5.10 - Prob. 15PPCCh. 5.10 - Prob. 5.16WECh. 5.10 - Prob. 16PPACh. 5.10 - Prob. 16PPBCh. 5.10 - Prob. 16PPCCh. 5.10 - Prob. 5.10.1SRCh. 5.10 - How many moles of hydrogen are there m 6.50 g of...Ch. 5.10 - Prob. 5.10.3SRCh. 5.10 - Prob. 5.10.4SRCh. 5 - Define the term compound and explain how a...Ch. 5 - Prob. 5.2QPCh. 5 - Prob. 5.3QPCh. 5 - Prob. 5.4QPCh. 5 - Use the second member of each group from Group 1A...Ch. 5 - Without referring to Figure 5.1, write Lewis dot...Ch. 5 - Prob. 5.7QPCh. 5 - Indicate the charge on each of the ions...Ch. 5 - To what group of the periodic table does element X...Ch. 5 - Explain what ionic bonding is.Ch. 5 - Prob. 5.11QPCh. 5 - Prob. 5.12QPCh. 5 - Prob. 5.13QPCh. 5 - Prob. 5.14QPCh. 5 - Prob. 5.15QPCh. 5 - Prob. 5.16QPCh. 5 - Prob. 5.17QPCh. 5 - Prob. 5.18QPCh. 5 - Prob. 5.19QPCh. 5 - Explain why the chemical formulas of ionic...Ch. 5 - Prob. 5.21QPCh. 5 - Give the formulas and names of the compounds...Ch. 5 - Give the formulas and names of the compounds...Ch. 5 - Prob. 5.24QPCh. 5 - Prob. 5.25QPCh. 5 - Name the following compounds: (a) CdCl2, (b) FeI3,...Ch. 5 - Prob. 5.27QPCh. 5 - Prob. 5.28QPCh. 5 - Prob. 5.29QPCh. 5 - Prob. 5.30QPCh. 5 - Prob. 5.31QPCh. 5 - Prob. 5.32QPCh. 5 - Prob. 5.33QPCh. 5 - Sulfur reacts with fluorine to produce three...Ch. 5 - Prob. 5.35QPCh. 5 - Prob. 5.36QPCh. 5 - Prob. 5.37QPCh. 5 - Prob. 5.38QPCh. 5 - Give an example of a case in which two molecules...Ch. 5 - Prob. 5.40QPCh. 5 - Prob. 5.41QPCh. 5 - Prob. 5.42QPCh. 5 - Identify the following as elements or compounds:...Ch. 5 - Prob. 5.44QPCh. 5 - Prob. 5.45QPCh. 5 - Prob. 5.46QPCh. 5 - Write the empirical formulas of the following...Ch. 5 - Prob. 5.48QPCh. 5 - Prob. 5.49QPCh. 5 - Describe how the naming of molecular binary...Ch. 5 - Define the term acid.Ch. 5 - Prob. 5.52QPCh. 5 - Prob. 5.53QPCh. 5 - Prob. 5.54QPCh. 5 - Prob. 5.55QPCh. 5 - Prob. 5.56QPCh. 5 - Prob. 5.57QPCh. 5 - Prob. 5.58QPCh. 5 - Prob. 5.59QPCh. 5 - Prob. 5.60QPCh. 5 - Prob. 5.61QPCh. 5 - Prob. 5.62QPCh. 5 - Prob. 5.63QPCh. 5 - Prob. 5.64QPCh. 5 - Prob. 5.65QPCh. 5 - Prob. 5.66QPCh. 5 - Prob. 5.67QPCh. 5 - Prob. 5.68QPCh. 5 - Prob. 5.69QPCh. 5 - Prob. 5.70QPCh. 5 - Prob. 5.71QPCh. 5 - Prob. 5.72QPCh. 5 - Prob. 5.73QPCh. 5 - Prob. 5.74QPCh. 5 - Prob. 5.75QPCh. 5 - Prob. 5.76QPCh. 5 - Prob. 5.77QPCh. 5 - Prob. 5.78QPCh. 5 - All the substances listed here are fertilizers...Ch. 5 - Prob. 5.80QPCh. 5 - Molar mass is numerically equivalent to molecular...Ch. 5 - Prob. 5.82QPCh. 5 - Prob. 5.83QPCh. 5 - Prob. 5.84QPCh. 5 - Prob. 5.85QPCh. 5 - Prob. 5.86QPCh. 5 - Prob. 5.87QPCh. 5 - The density of water is 1.00 g/mL at 4C. How many...Ch. 5 - Cinnamic alcohol is used to add a pleasant scent...Ch. 5 - The chemical formula for rust can be represented...Ch. 5 - Prob. 5.91QPCh. 5 - Prob. 5.92QPCh. 5 - Prob. 5.93QPCh. 5 - Prob. 5.94QPCh. 5 - Equilin is an estrogen isolated from the urine of...Ch. 5 - Prob. 5.96QPCh. 5 - Prob. 5.97QPCh. 5 - Prob. 5.98QPCh. 5 - Prob. 5.99QPCh. 5 - Prob. 5.100QPCh. 5 - What is wrong with or ambiguous about the phrase...Ch. 5 - Prob. 5.102QPCh. 5 - Prob. 5.103QPCh. 5 - Prob. 5.104QPCh. 5 - Ethane and acetylene are two gaseous hydrocarbons....Ch. 5 - Prob. 5.106QPCh. 5 - Prob. 5.107QPCh. 5 - Prob. 5.108QPCh. 5 - Prob. 5.109QPCh. 5 - Prob. 5.110QPCh. 5 - Prob. 5.111QPCh. 5 - Determine the molecular and empirical formulas of...Ch. 5 - Prob. 5.113QPCh. 5 - Prob. 5.114QPCh. 5 - Prob. 5.115QPCh. 5 - Prob. 5.116QPCh. 5 - Prob. 5.117QPCh. 5 - Prob. 5.118QPCh. 5 - Prob. 5.119QPCh. 5 - Prob. 5.120QPCh. 5 - Prob. 5.121QPCh. 5 - Prob. 5.122QPCh. 5 - Prob. 5.123QPCh. 5 - Prob. 5.124QPCh. 5 - Prob. 5.125QPCh. 5 - Prob. 5.126QPCh. 5 - Prob. 5.127QPCh. 5 - The compound 2,3-dimercaptopropanol...Ch. 5 - Prob. 5.129QPCh. 5 - Prob. 5.130QPCh. 5 - Prob. 5.131QPCh. 5 - Prob. 5.132QPCh. 5 - Calculate the number of cations and anions in each...Ch. 5 - Calculate the percent composition by mass of all...Ch. 5 - Prob. 5.135QPCh. 5 - Prob. 5.136QPCh. 5 - Prob. 5.137QPCh. 5 - Prob. 5.138QP
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