Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card
3rd Edition
ISBN: 9781305367388
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 5, Problem 5.111PAE
111 Consider a room that is
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 5 Solutions
Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card
Ch. 5 - Prob. 1COCh. 5 - Prob. 2COCh. 5 - Prob. 3COCh. 5 - Prob. 4COCh. 5 - perform stoichiometric ca1cu1uions for reactions...Ch. 5 - Prob. 6COCh. 5 - Prob. 7COCh. 5 - Prob. 8COCh. 5 - Prob. 9COCh. 5 - Prob. 10CO
Ch. 5 - Prob. 11COCh. 5 - List two types of chemical compounds that must be...Ch. 5 - When ozone levels in urban areas reach unhealthy...Ch. 5 - Prob. 5.3PAECh. 5 - Prob. 5.4PAECh. 5 - Asphalt is composed of a mixture of organic...Ch. 5 - Prob. 5.6PAECh. 5 - Prob. 5.7PAECh. 5 - Prob. 5.8PAECh. 5 - Prob. 5.9PAECh. 5 - Prob. 5.10PAECh. 5 - Prob. 5.11PAECh. 5 - 5.12 Water has a density that is 13.6 times less...Ch. 5 - 5.13 Water has a density that is 13.6 times less...Ch. 5 - Prob. 5.14PAECh. 5 - 5.15 Gas pressure can be expressed in units of mm...Ch. 5 - 5.16 If the atmospheric pressure is 97.4 kPa, how...Ch. 5 - Prob. 5.17PAECh. 5 - 5.18 When helium escapes from a balloon, the...Ch. 5 - 5.19 A sample of CO2 gas has a pressure of 56.5 mm...Ch. 5 - Prob. 5.20PAECh. 5 - Prob. 5.21PAECh. 5 - Prob. 5.22PAECh. 5 - Prob. 5.23PAECh. 5 - Prob. 5.24PAECh. 5 - Prob. 5.25PAECh. 5 - Prob. 5.26PAECh. 5 - 5.23 A gas bubble forms inside a vat containing a...Ch. 5 - 5.24 A bicycle tire is inflated to a pressure of...Ch. 5 - 5.25 A balloon filled with helium has a volume of...Ch. 5 - 5.26 How many moles of an ideal gas are there if...Ch. 5 - 5.27 A newly discovered gas has a density of 2.39...Ch. 5 - 5.28 Calculate the mass of each of the following...Ch. 5 - 5.29 What are the densities of the following gases...Ch. 5 - Prob. 5.34PAECh. 5 - 5.31 A cylinder is filled with toxic COS gas to a...Ch. 5 - 5.32 Cylinders of compressed gases are often...Ch. 5 - Prob. 5.37PAECh. 5 - 5.34 Define the term mole fractionCh. 5 - Prob. 5.39PAECh. 5 - 36 What is the total pressure exerted by a mixture...Ch. 5 - Prob. 5.41PAECh. 5 - 38 For a gas sample whose total pressure is 740...Ch. 5 - 39 A sample containing only NO2 and SO2, has a...Ch. 5 - Prob. 5.44PAECh. 5 - 41 A sample of a smokestack emission was collected...Ch. 5 - 42 Air is often dry air, ignoring the water mole...Ch. 5 - 43 In an experiment, a mixture of gases occupies a...Ch. 5 - Prob. 5.48PAECh. 5 - Prob. 5.49PAECh. 5 - Prob. 5.50PAECh. 5 - 47 HCl(g) reacts with ammonia gas, NH3(g), to form...Ch. 5 - 48 Hydrogen gas is generated when acids come into...Ch. 5 - Prob. 5.53PAECh. 5 - 50 The first step in processing zinc metal from...Ch. 5 - 51 What volume of oxygen at 24 C and 0.88 atm is...Ch. 5 - 52 If tetraborane, B4H10, is treated with pure...Ch. 5 - 53 N2O5is an unstable gas that decomposes...Ch. 5 - 54 One way to generate oxygen is to heat potassium...Ch. 5 - 55 Ammonia is not the only possible fertilizer....Ch. 5 - 56 Consider the following reaction:...Ch. 5 - 57 What volume of hydrogen gas, in liters, is...Ch. 5 - 58 Magnesium will burn in air to form both Mg3N2...Ch. 5 - 59 During a collision, automobile air bags are...Ch. 5 - 60 Automakers are always investigating reactions...Ch. 5 - 61 As one step in its purification, nickel metal...Ch. 5 - 62 Ammonium dinitramide (ADN), NH4N(NO2)2, was...Ch. 5 - Prob. 5.67PAECh. 5 - Prob. 5.68PAECh. 5 - Prob. 5.69PAECh. 5 - Prob. 5.70PAECh. 5 - Prob. 5.71PAECh. 5 - Prob. 5.72PAECh. 5 - Prob. 5.73PAECh. 5 - Prob. 5.74PAECh. 5 - Prob. 5.75PAECh. 5 - Prob. 5.76PAECh. 5 - Prob. 5.77PAECh. 5 - Prob. 5.78PAECh. 5 - Prob. 5.79PAECh. 5 - Prob. 5.80PAECh. 5 - Prob. 5.81PAECh. 5 - Prob. 5.82PAECh. 5 - Prob. 5.83PAECh. 5 - Prob. 5.84PAECh. 5 - Prob. 5.85PAECh. 5 - 88 Liquid oxygen for use as a rocket fuel can be...Ch. 5 - 89 A number of compounds containing the heavier...Ch. 5 - Prob. 5.88PAECh. 5 - 91 A 0.2500-g sample of an Al-Zn alloy reacts with...Ch. 5 - Prob. 5.90PAECh. 5 - 93 The complete combustion of octane can be used...Ch. 5 - 94 Mining engineers often have to deal with gases...Ch. 5 - 95 Some engineering designs call for the use of...Ch. 5 - Prob. 5.94PAECh. 5 - 97 Homes in rural areas where natural gas service...Ch. 5 - Prob. 5.96PAECh. 5 - 99 Pure gaseous nitrogen dioxide (NO2) cannot be...Ch. 5 - Prob. 5.98PAECh. 5 - Prob. 5.99PAECh. 5 - 102 A mixture of helium and neon gases has a...Ch. 5 - Prob. 5.101PAECh. 5 - Prob. 5.102PAECh. 5 - 105 The decomposition of mercury(II) thiocyanate...Ch. 5 - Prob. 5.104PAECh. 5 - 107 A soft drink can’s label indicates that the...Ch. 5 - Prob. 5.106PAECh. 5 - 109 An ore sample with a mass of 670 kg contains...Ch. 5 - Prob. 5.108PAECh. 5 - Prob. 5.109PAECh. 5 - Prob. 5.110PAECh. 5 - 111 Consider a room that is 14ft20ft wih an 8-ft...Ch. 5 - Prob. 5.112PAECh. 5 - 113 A 0.0125-g sample of a gas with an empirical...Ch. 5 - Prob. 5.114PAE
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