Organic Chemistry, 12e Study Guide/Student Solutions Manual
Organic Chemistry, 12e Study Guide/Student Solutions Manual
12th Edition
ISBN: 9781119077329
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 5, Problem 2LGP
Interpretation Introduction

Interpretation:

The three-dimensional structure, the mirror image and Fisher projection formula of mirror image of d-galactitol are to be drawn. The stereochemical relationship between d-galactitol and its mirror image is to be explained.

Concept introduction:

Enantiomers are a type of stereoisomers whose molecules have nonsuperimposable mirror images of each other.

A chiral molecule is one that has a non-superimposable mirror image and an achiral molecule is one that has a superimposable mirror image.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?

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Organic Chemistry, 12e Study Guide/Student Solutions Manual

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