From the given plots, a plot that doesn’t correctly represent Boyle’s law should be identified. Concept introduction: Boyle’s law can defined as, At constant temperature and number of moles, volume of a gaseous container is inversely proportional to the pressure excreted on the container. Mathematically, P ∝ 1 V Or PV=K Where, P = pressure in atmospheres V= volumes in liters K= a constant for a particular gas at given temperature By comparing two systems at different conditions P 1 V 1 =P 2 V 2
From the given plots, a plot that doesn’t correctly represent Boyle’s law should be identified. Concept introduction: Boyle’s law can defined as, At constant temperature and number of moles, volume of a gaseous container is inversely proportional to the pressure excreted on the container. Mathematically, P ∝ 1 V Or PV=K Where, P = pressure in atmospheres V= volumes in liters K= a constant for a particular gas at given temperature By comparing two systems at different conditions P 1 V 1 =P 2 V 2
Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 5 Solutions
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