Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357119303
Author: Bettelheim, Frederick A., Brown, William H., Campbell, Mary K., FARRELL, Shawn O., Torres, Omar
Publisher: Cengage Learning
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Chapter 4.6, Problem 4.8QC
Problem 4-8 We wish to weigh 2.84 mol of sodium sulfide, Na2S. How many grams is this?
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 4 Solutions
Introduction to General, Organic and Biochemistry
Ch. 4.2 - Problem 4-1 Following is an unbalanced equation...Ch. 4.2 - Problem 4-2 Balance this equation:Ch. 4.2 - Prob. 4.3QCCh. 4.3 - Problem 4-4 When a solution of copper(II)...Ch. 4.4 - Problem 4-5 In each equation, identify the...Ch. 4.5 - Problem 4-6 What is (a) the molecular weight of...Ch. 4.6 - Prob. 4.7QCCh. 4.6 - Problem 4-8 We wish to weigh 2.84 mol of sodium...Ch. 4.6 - Problem 4-9 How many moles of C atoms, H atoms,...Ch. 4.6 - Problem 4-10 How many moles of copper(I) ions,...
Ch. 4.6 - Prob. 4.11QCCh. 4.7 - Prob. 4.12QCCh. 4.7 - Prob. 4.13QCCh. 4.7 - Problem 4-14 Ethanol is produced industrially by...Ch. 4.7 - Prob. 4.15QCCh. 4.7 - Prob. 4.16QCCh. 4.8 - How many calories are required to heat 731g of...Ch. 4.8 - A 100g piece of iron at 25C is heated by adding...Ch. 4.8 - It required 88.2 cal to heat 13.4g of an unknown...Ch. 4.9 - Solid iron and oxygen gas react to form solid...Ch. 4 - 4-17 Balance each equation.Ch. 4 - 4-18 Balance each equation.Ch. 4 - Prob. 3PCh. 4 - 4-20 Calcium oxide is prepared by heating...Ch. 4 - 4-21 The brilliant white light in some firework...Ch. 4 - Prob. 6PCh. 4 - 4-23 When solid carbon burns in a limited supply...Ch. 4 - Prob. 8PCh. 4 - 4-25 In the chemical test for arsenic, the gas...Ch. 4 - Prob. 10PCh. 4 - Prob. 11PCh. 4 - 4-28 Answer true or false. (a) A net ionic...Ch. 4 - 4-29 Balance these net ionic equations. (a)...Ch. 4 - 4-30 In the equation (a) Identify the spectator...Ch. 4 - 4-31 Predict whether a precipitate will form when...Ch. 4 - 4-32 When a solution of ammonium chloride is added...Ch. 4 - 4-33 When a solution of hydrochloric acid, HCl, is...Ch. 4 - Prob. 18PCh. 4 - Prob. 19PCh. 4 - 4-36 Using the solubility generalizations given in...Ch. 4 - 4-37 Answer true or false. (a) When a substance is...Ch. 4 - Prob. 22PCh. 4 - Prob. 23PCh. 4 - Prob. 24PCh. 4 - Prob. 25PCh. 4 - 4-42 Calculate the formula weight of: (a) KCl (b)...Ch. 4 - 4-43 Calculate the molecular weight of: (a)...Ch. 4 - 4-44 Answer true or false. (a) The mole is a...Ch. 4 - 4-45 Calculate the number of moles in: (a) 32 g of...Ch. 4 - 4-46 Calculate the number of grams in: (a) 1.77...Ch. 4 - 4-47 Calculate the number of moles of: (a) O atoms...Ch. 4 - 4-48 Calculate the number of moles of: (a) S2-...Ch. 4 - 4-49 Calculate the number of: (a) nitrogen atoms...Ch. 4 - 4-50 How many molecules are in each of the...Ch. 4 - 4-51 What is the mass in grams of each number of...Ch. 4 - 4-52 The molecular weight of hemoglobin is about...Ch. 4 - 4-53 A typical deposit of cholesterol, C27H46O, in...Ch. 4 - 4-54 Answer true or false. (a) Stoichiometry is...Ch. 4 - 4-55 For the reaction: (a) How many moles of N2...Ch. 4 - 4-56 Magnesium reacts with sulfuric acid according...Ch. 4 - 4-57 Chloroform, CHCl3, is prepared industrially...Ch. 4 - 4-58 At one time, acetaldehyde was prepared...Ch. 4 - 4-59 Chlorine dioxide, ClO2, is used for bleaching...Ch. 4 - 4-60 Ethanol, C2H6O, is added to gasoline to...Ch. 4 - 4-61 In photosynthesis, green plants convert CO2...Ch. 4 - 4-62 Iron ore is converted to iron by heating it...Ch. 4 - Prob. 47PCh. 4 - 4-64 Aspirin is made by the reaction of salicylic...Ch. 4 - 4-65 Suppose the preparation of aspirin from...Ch. 4 - 4-66 Benzene reacts with bromine to produce...Ch. 4 - 4-67 Ethyl chloride is prepared by the reaction of...Ch. 4 - 4-68 Diethyl ether is made from ethanol according...Ch. 4 - Prob. 53PCh. 4 - How many calories are required to heat the...Ch. 4 - Prob. 55PCh. 4 - Prob. 56PCh. 4 - Prob. 57PCh. 4 - Prob. 58PCh. 4 - 4-71 Which of these reactions are exothermic, and...Ch. 4 - Prob. 60PCh. 4 - Prob. 61PCh. 4 - Prob. 62PCh. 4 - Prob. 63PCh. 4 - Prob. 64PCh. 4 - 4-77 To convert 1 mol of iron(III) oxide to its...Ch. 4 - 4-78 (Chemical Connections 4A) How does fluoride...Ch. 4 - Prob. 67PCh. 4 - Prob. 68PCh. 4 - 4-81 (Chemical Connections 4C) Balance the lithium...Ch. 4 - 4-82 When gaseous dinitrogen pentoxide, N2O5, is...Ch. 4 - Prob. 71PCh. 4 - Prob. 72PCh. 4 - Prob. 73PCh. 4 - 4-86 When an aqueous solution of Na3PO4 is added...Ch. 4 - Prob. 75PCh. 4 - 4-88 Chlorophyll, the compound responsible for the...Ch. 4 - 4-89 If 7.0 kg of is added to 11.0 kg of to form...Ch. 4 - 4-90 Lead(lI) nitrate and aluminum chloride react...Ch. 4 - 4-91 Assume that the average red blood cell has a...Ch. 4 - 4-92 Reaction of pentane, C5H12, with oxygen, O2,...Ch. 4 - 4-93 Ammonia is prepared industrially by the...Ch. 4 - 4-94 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) is...Ch. 4 - Prob. 83PCh. 4 - Prob. 84PCh. 4 - Prob. 85PCh. 4 - Prob. 86PCh. 4 - Prob. 87PCh. 4 - Prob. 88PCh. 4 - Prob. 89PCh. 4 - Prob. 90PCh. 4 - Prob. 91PCh. 4 - 4-102 Aspartame, an artificial sweetener used as a...Ch. 4 - 4-103 Caffeine, a central nervous system...Ch. 4 - Prob. 94P
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